Charge-sensing of a Ge/Si core/shell nanowire double quantum dot using a high-impedance superconducting resonator

Spin qubits in germanium are a promising contender for scalable quantum computers. Reading out of the spin and charge configuration of quantum dots formed in Ge/Si core/shell nanowires is typically performed by measuring the current through the nanowire. Here, we demonstrate a more versatile approach on investigating the charge configuration...

Biodegradation of Oxide Nanoparticles in Apoferritin Protein Media: A Systematic Electrochemical Approach

Functional oxide nanoparticles are extensively utilized in the last decades for biomedical purposes due to their unique functional properties. Nevertheless, their biodegradation mechanism by biological species, particularly by proteins at oxide/protein interfaces, still remains limited. Here, a systematic approaches is provided to investigate...

Understanding and Preventing Photoluminescence Quenching to Achieve Unity Photoluminescence Quantum Yield in Yb:YLF Nanocrystals

Ytterbium-doped LiYF4 (Yb:YLF) is a commonly used material for laser applications, as a photon upconversion medium, and for optical refrigeration. As nanocrystals (NCs), the material is also of interest for biological and physical applications. Unfortunately, as with most phosphors, with the reduction in size comes a large reduction of the...

Assembly of Core/Shell Nanospheres of Amorphous Hemin/Acetone-Derived Carbonized Polymer with Graphene Nanosheets for Room-Temperature NO Sensing

Implementing parts per billion-level nitric oxide (NO) sensing at room temperature (RT) is still in extreme demand for monitoring inflammatory respiratory diseases. Herein, we have prepared a kind of core-shell structural Hemin-based nanospheres (Abbr.: Hemin-nanospheres, defined as HNSs) with the core of amorphous Hemin and the shell of...

Nanostructuring Pt-Pd Bimetallic Electrocatalysts for CO₂ Reduction Using Atmospheric Pressure Atomic Layer Deposition

Preparing supported nanoparticles with a well-defined structure, uniform particle size, and composition using conventional catalyst synthesis methods, such as impregnation, precipitation, and deposition-precipitation is challenging. Furthermore, these liquid phase methods require significant solvent consumption, which has sustainable issues...

Self-assembly of colloidal superballs under spherical confinement of a drying droplet

Understanding the relationship between colloidal building block shape and self-assembled material structure is important for the development of novel materials by self-assembly. In this regard, colloidal superballs are unique building blocks because their shape can smoothly transition between spherical and cubic. Assembly of colloidal...

Position-Controlled Fabrication of Vertically Aligned Mo/MoS₂ Core–Shell Nanopillar Arrays

The fabrication of 2D materials, such as transition metal dichalcogenides (TMDs), in geometries beyond the standard platelet-like configuration exhibits significant challenges which severely limit the range of available morphologies. These challenges arise due to the anisotropic character of their bonding van der Waals out-of-plane while...

Lanthanopolyoxometalate-Silica Core/Shell Nanoparticles as Potential MRI Contrast Agents

The NMR relaxivities of the decatungstolanthanoate core-shell nanoparticles, prepared by encapsulating [Ln(W₅O₁₈)₂]⁹⁻ polyoxometalates (LnPOM) within amorphous silica shells (K₉[Ln(W₅O₁₈)₂]@SiO₂), were studied along the Ln series. The relaxivity...

Towards multi-functional SiO₂ @YAG: Ce core–shell optical nanoparticles for solid state lighting applications

This paper aims to investigate the synthesis, structure, and optical properties of SiO₂ @YAG:Ce core–shell optical nanoparticles for solid state lighting applications. YAG:Ce phosphor is a key part in white light emitting diodes (LEDs), with its main functionality being the generation of yellow light. Generated yellow light from...

Developing Lattice Matched ZnMgSe Shells on InZnP Quantum Dots for Phosphor Applications

Indium phosphide quantum dots (QDs) have drawn attention as alternatives to cadmium- and lead-based QDs that are currently used as phosphors in lamps and displays. The main drawbacks of InP QDs are, in general, a lower photoluminescence quantum yield (PLQY), a decreased color purity, and poor chemical stability. In this research, we attempted...

Low Noble Metal Content Catalysts for Hydrogen Fuel Technology

The increasing energy demand of the world population in combination with tangible climate change effects stemming from rising carbon dioxide emissions is currently characterizing a large portion of the political and societal debate. Despite huge technological advancement in the field of renewable energy resulting in energy prices lower than that...

Tuning roughness and gloss of powder coating paint by encapsulating the coating particles with thin Al₂O₃ films

In this work, we report a method to change the surface finish of a standard polyester-based powder coating paint, from gloss to matt, by depositing ultrathin films of Al₂O₃ on the powder coating particles. The coating experiments were performed in a fluidized bed reactor at 1 bar and 27 °C, using a gas-phase coating...

Core-Shell Plasmonic Nanohelices

We introduce core-shell plasmonic nanohelices, highly tunable structures that have a different response in the visible for circularly polarized light of opposite handedness. The glass core of the helices is fabricated using electron beam induced deposition and the pure gold shell is subsequently sputter coated. Optical measurements allow us...

Tuning the Lattice Parameter of In_xZn_yP for Highly Luminescent Lattice-Matched Core/Shell Quantum Dots

Colloidal quantum dots (QDs) show great promise as LED phosphors due to their tunable narrow-band emission and ability to produce high-quality white light. Currently, the most suitable QDs for lighting applications are based on cadmium, which presents a toxicity problem for consumer applications. The most promising cadmium-free candidate QDs...

Deposition of conductive TiN shells on SiO2 nanoparticles with a fluidized bed ALD reactor

Conductive TiN shells have been deposited on SiO2 nanoparticles (10–20 nm primary particle size) with fluidized bed atomic layer deposition using TDMAT and NH3 as precursors. Analysis of the powders confirms that shell growth saturates at approximately 0.4 nm/cycle at TDMAT doses of >1.2 mmol/g of powder. TEM and XPS analysis showed that all...

Towards the production of core-shell nanoparticles with fluidized bed ALD

Reducing particle size or material structure size to nanometer scale can make the material properties, such as light absorption and electronic structure, change compared to the same materials at normal scale. This gives them properties that can make them suitable for the development of highly efficient and improved micro-electronics, sensor...

The Influence of Particle Size Distribution and Shell Imperfections on the Plasmon Resonance of Au and Ag Nanoshells

Au and Ag nanoshells are of interest for a wide range of applications. The plasmon resonance of such nanoshells is the property of interest and can be tuned in a broad spectral regime, ranging from the ultraviolet to the mid-infrared. To date, a large number of manuscripts have been published on the optics of such nanoshells. Few of these,...

How to Determine the Core-Shell Nature in Bimetallic Catalyst Particles?

Nanometer-sized materials have significantly different chemical and physical properties compared to bulk material. However, these properties do not only depend on the elemental composition but also on the structure, shape, size and arrangement. Hence, it is not only of great importance to develop synthesis routes that enable control over the...