Investigating the effect of artists’ paint formulation on degradation rates of TiO₂‑based oil paints

This study reports on the effect of artists’ paint formulation on degradation rates of TiO2-based oil paints. Titanium white oil paint exists in a multitude of different recipes, and the effect of the formulation on photocatalytic binder<br/>degradation kinetics is unknown. These formulations contain, among others, one or both titanium dioxide...

Determination of early warning signs for photocatalytic degradation of titanium white oil paints by means of surface analysis

Titanium white (TiO₂) has been widely used as a pigment in the 20th century. However, its most photocatalytic form (anatase) can cause severe degradation of the oil paint in which it is contained. UV light initiates TiO₂-photocatalyzed processes in the paint film, degrading the oil binder into volatile components...

Investigating the photocatalytic degradation of oil paint using ATR-IR and AFM-IR

As linseed oil has a longstanding and continuing history of use as a binder in artistic paints, developing an understanding of its degradation mechanism is critical to conservation efforts. At present, little can be done to detect the early stages of oil paint deterioration due to the complex chemical composition of degrading paints. In this...