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Van Westen, T. (author), Oyarzun, B. (author), Vlugt, T.J.H. (author), Gross, J. (author)An extension of Onsager's second virial theory is developed to describe the isotropic-nematic phase transition of tangent hard-sphere chain fluids. Flexibility is introduced by the rod-coil model. The effect of chain-flexibility on the second virial coefficient is described using an accurate, analytical approximation for the orientation...journal article 2013
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Van 't Hof, A. (author), De Leeuw, S.W. (author), Peters, C.J. (author)Gibbs-Duhem integration implies the numerical integration of a Clapeyron equation. To start the numerical integration, an initial coexistence point and a corresponding initial slope of the Clapeyron equation are needed. In order to apply Gibbs-Duhem integration to all kinds of systems at diverse physical conditions, one has to investigate and...journal article 2006
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Kalikmanov, V.I. (author), De Leeuw, S.W. (author)We propose a self-consistent mean-field lattice-gas theory of intercalation compounds based on effective interactions between interstitials in the presence of the host atoms. In addition to short-range screened Coulomb repulsions, usually discussed in the lattice gas models, the present theory takes into account long-range effective attractions...journal article 2002