The lithium air, or Li–O2, battery system is a promising electrochemical energy storage system because of its very high theoretical specific energy, as required by automotive applications. Fundamental research has resulted in much progress in mitigating detrimental (electro)chemical processes; however, the detailed structural evolution of the crystalline Li2O2 and LiOH discharge products, held at least partially responsible for the limited reversibility and poor rate performance, is hard to measure operando under realistic electrochemical conditions. This study uses Rietveld refinement of operando X-ray diffraction data during a complete discharge–charge cycle to reveal the detailed structural evolution of Li2O2 and LiOH crystallites in 1,2-dimethoxyethane (DME) and DME/LiI electrolytes, respectively. The anisotropic broadened reflections confirm and quantify the platelet crystallite shape of Li2O2 and LiOH and show how the average crystallite shape evolves during discharge and charge. Li2O2 is shown to form via a nucleation and growth mechanism, whereas the decomposition appears to start at the smallest Li2O2 crystallite sizes because of their larger exposed surface. In the presence of LiI, platelet LiOH crystallites are formed by a particle-by-particle nucleation and growth process, and at the end of discharge, H2O depletion is suggested to result in substoichiometric Li(OH)1–x, which appears to be preferentially decomposed during charging. Operando X-ray diffraction proves the cyclic formation and decomposition of the LiOH crystallites in the presence of LiI over multiple cycles, and the structural evolution provides key information for understanding and improving these highly relevant electrochemical systems.

The radio sky at frequencies below ∼30 MHz is virtually unobservable from Earth due to ionospheric disturbances and the opaqueness of the ionosphere below ∼10MHz, and also due to strong terrestrial radio interference. Deploying a radio observatory in space would open up this largely unexplored frequency band for science in astronomy, cosmology, geophysics, and space science. A Chinese-European team is proposing an ultra long wavelength (ULW) radio interferometer mission DSL (Discovering the Sky at the Longest Wavelengths). The proposed radio interferometer will be deployed in low-altitude lunar orbit, exploiting the radio quietness of the lunar far side. DSL will consist of a mother-spacecraft for data transport and control, plus eight small micro-satellites each equipped with three orthogonal dipoles. These satellites form a virtual distributed observatory with adjustable baselines, allowing different scientific observation strategies. The satellites are configured in a flexible quasi-linear array in nearly identical orbits, guaranteeing low relative drift rates. Short orbital periods and orbit precession ensure quick filling of the interferometric spatial frequency (u, v, w) space, enabling high quality imaging. The science themes considered for the DSL mission include pioneering studies of the unknown and exploratory science such as the search for signatures of the cosmological Dark Ages, complementing current (e.g. LOFAR) and future SKA telescope searches; full-sky continuum survey of discrete sources, including ultra-steep spectrum extragalactic sources, pulsars, and transients (galactic and extragalactic); full-sky map of continuum diffuse emission; solar-terrestrial physics, planetary sciences, and cosmic ray physics. The main frequency band covered is 1-30 MHz extending down to 0.1 MHz, and up to about 50 MHz for cross-referencing with ground-based instruments. DSL will support a variety of observational modes, including broad-band spectral analysis for Dark Ages, radio interferometric cross-correlations for imaging, and flexible raw data downlink capability. Data processing will be performed at radio astronomy science data centres in Europe and China.