S. Koorthedath Pullayikody
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A major challenge in multijunction devices is reduced light incoupling caused by interference fringes from optical microcavities. This paper reports a potential route to mitigate the interference effects with an effective front-window design. The concepts of interface scattering and grain scattering are implemented at the front side of superstrate tandem solar cells. A random texturing and periodic-hexagonal texturing approach on glass is used as interface scatterers. However, applying an interface scatterer alone is insufficient to eliminate the interference effects of optical cavities completely. Use of sputtered unintentionally doped zinc oxide (i-ZnO) or tin oxide (SnO) as grain scatterers stacked over random and periodic glass textures quenches the interference effects significantly. For a random textured glass substrate, a 1.5-μm thick i-ZnO layer could quench interference in the top cell, except for the effect of the optical cavity formed in the amorphous top cell. Hexagonal craters on glass, combined with a 0.9-μm thick i-ZnO layer, effectively mitigate fringes formed by all optical cavities in the device. This sample demonstrates the highest incoupled photon flux with 86% of photons entering the device. Use of a wide-bandgap grain scatterer, such as SnO, reduces parasitic absorption of high-energy photons while mitigating optical cavities. The design principles discussed in this work can be applied to any thin-film multijunction solar cells consisting of layers with contrasting refractive indices.
Photovoltaic (PV) panel installations in buildings and transportation hubs pose additional safety challenges as the glare from the panels can impose adverse impacts like flash blindness in human eyes. This study substantiates that polymer encapsulated thin film modules offer significantly low glare levels that are essential for building integrated and transport hub installations. In this work, the glare hazard potential associated with matt ethylene tetrafluoroethylene (ETFE)-based polymer sheet used as the frontsheet for the production of flexible thin amorphous silicon (a-Si) PV modules is studied and compared with standard PV glass used in crystalline silicon (c-Si) PV panels. The specular reflectance extracted from the measured total and diffuse reflectance for an angle of incidence (AOI) of 8° and the angular intensity distribution (AID) of specular reflectance measured for AOI ranging from 10° to 80° are utilized for glare assessment of the frontsheets. The mean value of specular reflectance extracted from the measured total and diffused reflectance is as low as 0.5% for the polymer frontsheet and is 4% for glass. The AID measurements suggest that the reflection from the polymer frontsheet is highly diffusive in nature in contrast to glass and the measured specular reflectance is always close to a magnitude lower than that from glass for all AOI. With the increase in AOI, the specular AID reflectance increases exponentially for glass to become as high as 40%, which is almost 20 times less than that from the polymer frontsheet for an AOI of 80°. Further, the c-Si test structure with glass and thin a-Si PV module with matt ETFE-based polymer as frontsheet showed similar specular reflectance trends as that of glass and the polymer frontsheet, respectively.