We report the preparation and electrocatalytic performance of silver-containing gas diffusion electrodes (GDEs) derived from a silver coordination polymer (Ag-CP). Layer-by-layer growth of the Ag-CP onto porous supports was applied to control Ag loading. Subsequent electro-decomposition of the Ag-CP resulted in highly selective and efficient CO₂-to-CO GDEs in aqueous CO₂ electroreduction. Afterward, the metal-organic framework (MOF)-mediated approach was transferred to a gas-fed flow electrolyzer for high current density tests. The in situ formed GDE, with a low silver loading of 0.2 mg cm^-2, showed a peak performance of j_CO ≈ 385 mA cm^-2 at around -1.0 V vs RHE and stable operation with high FE_CO (>96%) at j_Total = 300 mA cm^-2 over a 4 h run. These results demonstrate that the MOF-mediated approach offers a facile route for manufacturing uniformly dispersed Ag catalysts for CO₂ electrochemical reduction by eliminating ill-defined deposition steps (drop-casting, etc.) while allowing control of the catalyst structure through self-assembly.