This paper introduces new oil recovery mechanisms for oil recovery by polymer injection in heavy oil reservoirs with strong bottom aquifers. Due to unfavorable mobility ratio between aquifer water and oil and the development of the sharp cones significant amount of oil remains unswept. To overcome these issues, for the case demonstrated in this paper, a polymer injection pilot was executed with three horizontal injectors, located a few meters above the oil/water contact. The injectivity issues resulted in frequent shutdowns of the injectors. Interestingly, the water cut reversal and oil gain continued during the shut-in periods. This observation has led to the development of a new cyclic polymer injection strategy, in which the injection of polymer is alternated with intentional well shut-ins. The strategy is referred to as Nothing-Alternating-Polymer (NAP). It was found that during polymer injection, the oil is recovered by conventional mobility and sweep enhancement mechanisms ahead of the polymer front. Additionally, during this stage the injected polymer squeezes the existing cones and creates a barrier between the aquifer and the oil column, suppressing the aquifer flux and hence the negative effect of the cones or water channels (blanketing mechanism). Moreover, injection of polymer pushes the oil to the depleted water cones, which is then produced by the water coming from the aquifer during shut-in period (recharge mechanism). During the shut-in or NAP period, the aquifer water also pushes the existing polymer bank and hence leads to extra oil production. The resistance caused by polymer adsorption reduces the extent of fingering of water into polymer bank. The NAP strategy reduces polymer loss into aquifer and improves the polymer utilization factor expressed in kg-polymer/bbl of oil, resulting in a favorable economic outcome.

Surfactant losses by adsorption to rock surfaces make surfactant-based enhanced oil recovery economically less feasible. We investigated polyacrylate (PA) as a sacrificial agent in the reduction of anionic surfactant adsorption with focus on calcite surfaces by using quartz crystal microbalance with dissipation monitoring. It was found that the adsorption of the anionic surfactant alcohol alkoxy sulfate (AAS) followed a Langmuir adsorption isotherm, and the adsorbed amount reached saturation above its critical micellar concentration. Adsorption of PA was a much slower process compared to AAS adsorption. Increasing the calcium ion concentration also increased the amount of AAS adsorbed as well as the mass increase rate of PA adsorption. Experimental results combined with density functional theory calculations indicated that calcium cation bridging was important for anionic surfactant AAS and PA adsorption to calcite surfaces. To effectively reduce the amount of surfactant adsorption, it was needed to preflush with PA, rather than by a simultaneous injection. Preflushing with 30 ppm of PA gave a reduction of AAS adsorption of 30% under high salinity (HS, 31,800 ppm) conditions, compared to 8% reduction under low salinity (LS, 3180 ppm) conditions. In the absence of PA, the amount of adsorbed AAS was reduced by already 50% upon changing from HS to LS conditions. Lower calcium ion concentrations, as under LS conditions, contributed to this observation. On different mineral surfaces, PA reduced the AAS adsorption in the order of alumina > calcite > silica. These results offer important insights into mitigating surfactant adsorption using PA polyelectrolyte as sacrificial agent and contribute to improved flooding strategies with reduced surfactant loss.