The preparation of thermal equilibrium states is important for the simulation of condensed matter and cosmology systems using a quantum computer. We present a method to prepare such mixed states with unitary operators and demonstrate this technique experimentally using a gate-based quantum processor. Our method targets the generation of thermofield double states using a hybrid quantum-classical variational approach motivated by quantum-approximate optimization algorithms, without prior calculation of optimal variational parameters by numerical simulation. The fidelity of generated states to the thermal-equilibrium state smoothly varies from 99 to 75% between infinite and near-zero simulated temperature, in quantitative agreement with numerical simulations of the noisy quantum processor with error parameters drawn from experiment.

Protecting quantum information from errors is essential for large-scale quantum computation. Quantum error correction (QEC) encodes information in entangled states of many qubits and performs parity measurements to identify errors without destroying the encoded information. However, traditional QEC cannot handle leakage from the qubit computational space. Leakage affects leading experimental platforms, based on trapped ions and superconducting circuits, which use effective qubits within many-level physical systems. We investigate how two-transmon entangled states evolve under repeated parity measurements and demonstrate the use of hidden Markov models to detect leakage using only the record of parity measurement outcomes required for QEC. We show the stabilization of Bell states over up to 26 parity measurements by mitigating leakage using postselection and correcting qubit errors using Pauli-frame transformations. Our leakage identification method is computationally efficient and thus compatible with real-time leakage tracking and correction in larger quantum processors.

Leakage outside of the qubit computational subspace, present in many leading experimental platforms, constitutes a threatening error for quantum error correction (QEC) for qubits. We develop a leakage-detection scheme via Hidden Markov models (HMMs) for transmon-based implementations of the surface code. By performing realistic density-matrix simulations of the distance-3 surface code (Surface-17), we observe that leakage is sharply projected and leads to an increase in the surface-code defect probability of neighboring stabilizers. Together with the analog readout of the ancilla qubits, this increase enables the accurate detection of the time and location of leakage. We restore the logical error rate below the memory break-even point by post-selecting out leakage, discarding less than half of the data for the given noise parameters. Leakage detection via HMMs opens the prospect for near-term QEC demonstrations, targeted leakage reduction and leakage-aware decoding and is applicable to other experimental platforms.

Variational quantum eigensolvers offer a small-scale testbed to demonstrate the performance of error mitigation techniques with low experimental overhead. We present successful error mitigation by applying the recently proposed symmetry verification technique to the experimental estimation of the ground-state energy and ground state of the hydrogen molecule. A finely adjustable exchange interaction between two qubits in a circuit QED processor efficiently prepares variational ansatz states in the single-excitation subspace respecting the parity symmetry of the qubit-mapped Hamiltonian. Symmetry verification improves the energy and state estimates by mitigating the effects of qubit relaxation and residual qubit excitation, which violate the symmetry. A full-density-matrix simulation matching the experiment dissects the contribution of these mechanisms from other calibrated error sources. Enforcing positivity of the measured density matrix via scalable convex optimization correlates the energy and state estimate improvements when using symmetry verification, with interesting implications for determining system properties beyond the ground-state energy.