FP

F. Pargar

18 records found

Determination of chloride content in cement-based materials

Comparison of results derived by conventional methods and chloride sensor readings

In this paper the potentiometric response of a Ag/AgCl electrode as a chloride sensor in cementitious materials of different mix design was studied. The chloride sensor’s response was discussed with respect to the presence of hydration products around the sensor. The free chlorid ...
In this work, the different techniques for non-destructive in situ measurement of chloride ion concentration are presented. Non-destructive (ND) in situ measurement is crucial for reliable and continuous determination of chloride ion concentration in concrete. Over the last 20 ye ...
The stability and reproducibility of an Ag/AgCl sensors’ response in an alkaline medium are important for the application of these sensors in cementitious materials. The sensors’ response, or their open circuit potential (OCP), reflects a dynamic equilibrium at the sensor/environ ...
Determination of the chloride content in a reinforced concrete structure is important for evaluation of the risk of chloride-induced corrosion of reinforcement. The traditional techniques for chloride determination in concrete are laborious, time-consuming and cannot be used for ...
Characterization of the Ag/AgCl electrode is a necessary step toward its
application as a chloride sensor in a highly alkaline medium, such as concrete.
The nucleation and growth of AgCl on Ag in 0.1 M HCl was verified through
cyclic voltammetry. Ag anodization was pe ...
Determination of the free chloride content in a concrete structure is important for evaluation of the risk of corrosion of reinforcing steel. The Ag/AgCl sensor is sensitive to chloride ions and exhibits an open circuit potential (OCP) that depends on the chloride ions activity i ...
When studying chloride-induced corrosion in reinforced concrete structures, essential information of interest is the concentration of chloride ions in the system. The absence of a reliable method for monitoring the free chloride ions justifies the attempts towards establishing a ...
The need for an accurate determination of the chloride threshold value for corrosion initiation in reinforced concrete has long been recognized. Numerous investigations and reports on this subject are available. However, the obtained chloride threshold values have always been, an ...

Determination of Chloride Content in Cementitious Materials

From Fundamental Aspects to Application of Ag/AgCl Chloride Sensors

This paper reports on the advantages and drawbacks of available test methods for the determination of chloride content in cementitious materials in general, and the application of Ag/AgCl chloride sensors in particular. The main factors that affect the reliability of a chloride s ...
Free chloride ions are the main cause of steel corrosion in reinforced concrete structures. Ag/AgCl electrodes, as chloride sensors, are predominantly sensitive to chloride ions and respond electrochemically to the chloride ion activity in the environment. This is reflected by ch ...
The stability of chloride ion selective electrodes in highly alkaline solutions is an important aspect when reliability and feasibility within reinforced concrete applications are concerned. The sensitivity of these electrodes largely depends on the properties of the AgCl layer, ...
The half-cell potential of the Activated carbon (AC), due to its high double layer capacitance (EDL), remains stable in high ionic electrolyte. The open circuit potential (OCV) of the AC, with EDL of 40 – 50 F, shows a stable potential (10 mV variation) over two weeks in the ceme ...

Non-destructive evaluation of chloride-induced corrosion in reinforced concrete

Electrochemical impedance spectroscopy sheds new light on generally applied sensors performance

Service life of reinforced concrete structures exposed to chloride enriched environment is well known to be mainly determined by steel passivity breakdown in the event of chloride-induced corrosion initiation and propagation. Since Cl- induced (localized) corrosion is caused by t ...