The growing adoption of electric vehicles, known for their quieter operation compared to internal combustion engine vehicles, raises concerns about their detectability, particularly for vulnerable road users. To address this, regulations mandate the inclusion of exterior sound signals for electric vehicles, specifying minimum sound pressure levels at low speeds. These synthetic exterior sounds are often used in noisy urban environments, creating the challenge of enhancing detectability without introducing excessive noise annoyance. This study investigates the design of synthetic exterior sound signals that balance high noticeability with low annoyance. An audiovisual experiment with 14 participants was conducted using 15 virtual reality scenarios featuring a passing car. The scenarios included various sound signals, such as pure, intermittent, and complex tones at different frequencies. Two baseline cases, a diesel engine and only tyre noise, were also tested. Participants rated sounds for annoyance, noticeability, and informativeness using 11-point ICBEN scales. The findings highlight how psychoacoustic sound quality metrics predict annoyance ratings better than conventional sound metrics, providing insight into optimising sound design for electric vehicles. By improving pedestrian safety while minimising noise pollution, this research supports the development of effective and user-friendly exterior sound standards for electric vehicles.