WIND turbines play a crucial role in the global transition towards a sustainable energy future. Maximizing energy production and ensuring a reliable operation is essential to harnessing the full potential of wind energy. Among the critical components, the main shaft bearings have for several years been a focal point due to their significant downtime. In this context, a tribochemical treatment called case-carburization has gained notable attention for enhancing the microstructure of these bearings, to improve their reliability. Case-carburization is a surface treatment technique capable of modifying steel to exhibit a combination of properties such as high fatigue strength, toughness, and wear resistance, that are essential for these bearings as they operate in high-load-bearing environments. In a multi-stage heat treatment process involving case-carburization as the initial stage, the microstructure development at each stage is affected by the final microstructure of the preceding stage. Therefore, a comprehensive understanding of the microstructure at every stage is crucial for assessing its impact on the final microstructure and its properties. This Ph.D. research investigates the microstructure evolution throughout a four-stage heat treatment: carburization, sub-critical isothermal treatment, hardening, and tempering. The second stage is where the sole difference lies with regard to the heat treatment parameters, and is performed along two different routes, also in industrial practise, called the "bainitic route" and "pearlitic route". One of the primary goals of this research is to understand the microstructure development during the different stages of the two heat treatment routes and to provide an understanding of the microstructural features that can potentially affect the properties/performance of bearings. Additionally, this research also aims to identify the specific stage at which these features form and to provide insight into their formation mechanisms to explore strategies to rectify or mitigate the formation of detrimental features in the microstructure....@en

The influence of carbon concentration variations on pearlite formation (20 h at 600 °C) in a case-carburized steel is investigated. The resultant microstructure shows three distinct regions: carburized case, a transition region, and the original core. The microstructural transition from the case to the core regions is observed to be relatively sharp. The investigated region of the carburized case (0.9 wt.% C) contains two types of pearlite: ferrite + cementite and ferrite + M₂₃C₆, where the pearlitic aggregate with M₂₃C₆ shows faster formation kinetics. The kinetics of pearlite formation in the transition region (0.3 wt.% C) is very slow and is observed with only M₂₃C₆ carbide. Only around 40% austenite decomposes into pearlite in the transition region, which, in comparison to the carburized case region of 0.9 wt.% C is a fraction that is lower by a factor of two. Pearlite is absent in the investigated core region (0.16 wt.% C). The microstructure in this region is predominantly martensite and pro-eutectoid ferrite, with a fraction of ferrite well below the equilibrium fraction. Ferrite formation in this region is limited by the redistribution of mainly Ni, Mn, and Cr, and their resulting solute drag effect on the austenite/ferrite interface. A thermodynamic and kinetic argumentation of these observations is provided with the help of thermodynamic data, precipitation simulations, and a general mixed-mode Gibbs energy balance model.

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In many commercial steel processing routes, steel microstructures are reverted to an austenitic condition prior to the final processing steps. Understanding the microstructure development during austenitization is crucial for improving the performance and reliability of the microstructure that forms from austenite. In this work, austenite formation in a high-C steel (0.85 wt%) from a microstructure containing martensite/austenite and bainite bands is investigated. It is shown that austenite formation from bainite results in a refined austenite grain structure, and the martensite matrix thus obtained on quenching has a homogeneous distribution of carbides with a relatively low fraction of retained austenite (24%). On the other hand, a coarser austenite microstructure is obtained when austenite forms from a mixture of martensite and retained austenite. The reason for the coarse austenite grains is argued to be a memory effect, which is substantiated by in situ X-ray diffraction analysis. After quenching, an inhomogeneous carbide distribution and a higher retained austenite fraction (30%) are observed in the regions that were initially martensite/austenite. The global microstructure, hence, has a bimodal size distribution of prior austenite grains and carbide-dense bands. The causes for these heterogeneities are discussed with the help of interrupted quench experiments, equilibrium phase calculations, and DICTRA simulations.

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Bainite to austenite reversal is one of the grain refinement techniques employed in carburized steels. However, chemical segregation influences the homogeneity of the bainitic structure, which is seminal to exploit the advantages associated with austenite reversal. It is therefore important to understand the influence of chemical segregation on bainite formation, which is investigated in this work. Characterizations were performed on the microstructures obtained from the case and core regions of a carburized steel after 30 h of bainite treatment at 320 °C for two carbon compositions: 0.85 wt% C (z_case) and 0.16 wt% C (z_core). The microstructure of z_case is shown to contain bands with bainite in alloy-lean regions and martensite/austenite in alloy-rich regions. For z_core, although the chemical bands are not composed of different phases, the alloy-rich regions have a fraction of martensite-austenite (MA) islands that is twice the fraction in alloy-lean regions. Despite this difference, the austenite phase fractions in the chemical bands of z_core are low and almost similar, indicating that the MA islands are mostly martensite. From experimental results and thermodynamic and kinetic simulations, it is elucidated that a different rate of phase transformation in the chemical bands is the cause for the observed microstructural inhomogeneities.

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