Introduction: In this study we investigate the Suspended Particulate Matter (SPM) source and dynamics in terms of resuspension and advection in the mid field region of Rhine Region Of Freshwater Influence (Rhine-ROFI). In this area of the Rhine-ROFI, the sediment transport mechanisms are governed by the Rhine freshwater plume originating from the Rhine-Meuse estuary and propagating towards the coast in northward direction. Methods: The SPM near the bottom at a mooring located at 12m of water depth is analyzed in terms of concentration, particle size and shape in correlation with frontal dynamics and weather conditions for two seasons of winter 2013 (12 February - 07 March) and autumn 2014 (17 September - 06 October). Results and discussion: The freshwater front transports organic matter (such as microalgae strains and other organic matter) from the estuary into the coastal area. In calm weather conditions in autumn, most particles in suspension are of low density and high anisotropy. These particles are recognized as elongated algae strains with some organic matter-clay aggregates (flocs), giving trimodal Particle Size Distributions (PSD). During the neap tides strong salinity stratification and low turbulence result in SPM accumulation at the bed forming a fluff layer. At spring tides a fast switch between stratified and well mixed water column conditions caused by tidal mixing results in resuspension of SPM. During spring tides, the PSD’s are multimodal at low bed stress (predominance of microalgae) and monomodal at high bed stress (predominance of mineral sediment). At the storm initiation in autumn, the organic-matter rich fluff layer is depleted in a matter of hours, which is reflected in the change in modality of the PSD’s. Once the resuspended material is dominated by the mineral clay fraction, the PSD turns sharply monomodal. During winter monomodal PSD’s are recorded during calm weather conditions. The particles in suspension are then relatively spherical flocs of low density. During the winter storm, the fluff layer, which is much thinner than in autumn, is depleted very fast. This study shows the importance of organic matter in the transport of mineral sediment particles in coastal areas. The dynamic composition of the fluff layer of the bed should be accounted for in erosion models.

The authors regret that three typos remained in the original published article: in Eqs. (6), (10) and (11) a minus sign should be inserted in front of the variable t in all the exponentials. In particular, the full solution of the change in population, Eq. (10), reads [Formula presented] The authors would like to apologise for any inconvenience caused.

Despite recent advancement in the field of sediment transport, the integration of cohesive sediment properties in large-scale transport models remain a challenging task. In order to model adequately the change in particle size that occurs in different environmental conditions, flocculation models based on the so-called Population Balance Equations (PBE) are often used. These models have to be efficient enough to be implemented in numerical transport models, and as full PBE's are time-expensive to run and depend on a huge amount of a-priori unknown parameters, simplifications have to be made. These simplifications comes unavoidably at the cost of properly accounting for the complex particle-particle and particle-fluid interactions. In order to stay as close as possible to the physical processes, we propose a different approach based on a logistic growth model that mimics the Particle Size Distribution (PSD) measured over time for all size classes. The parameters of the model can easily be found from laboratory measurements. In contrast to most models, the particle classes we propose are not defined by particle size, but in terms of mineral sediment composition. One class is composed of (unflocculated) mineral sediment particles, another of flocculated sediment particles and a third one of organic particles. The mass balance between classes and the way to obtain their corresponding average settling velocity are given. Mass balance and settling velocities are the required input parameters for all sediment transport models. The simplicity of the derived expressions, and their link with measurable variables, makes them good candidates for future implementation in such models.

The characteristics of clayey suspensions, majorly composed of quartz microparticles, in the presence of anionic and cationic polyelectrolytes were investigated using different techniques. A wide range of clay concentrations was used, i.e., from 0.07 to 1000 g/L for different experimental techniques, based on the fact that the clay concentration possible to analyze with selected experimental methods was significantly different. The optimum flocculant to clay ratio was defined as the ratio that gives the fastest initial floc growth by static light scattering or fastest initial settling velocity by settling column experiments. In case of anionic polyelectrolyte, it was observed that the optimum flocculant dose depends on the amount of cations present in the system. For suspensions made with demi-water, a lower optimum flocculant dose (<1 mg/g) than for suspensions prepared in tap water (2.28 mg/g) was observed. At these lower salinities, the supernatant remained turbid in all the experiments and was, therefore, not a good measure for optimal anionic based flocculation. The equilibrium floc size at a given shear rate was found to be independent on the shear history of the floc and only dependent on the current applied shear. This was confirmed by both light scattering and rheological analysis. In case of cationic polyelectrolyte, the optimum flocculant ratio (5–6 mg/g) corresponded to the ratio that gives the lowest electrophoretic mobility for each clay concentration and to the ratio that gives the fastest settling velocity for the highest clay concentrations (12–15 g/L), where static light scattering measurements were not possible. All investigation techniques, therefore, proved to be good indicators for predicting the optimum flocculant to clay ratio. For the lowest concentrations (1.75–8.7 g/L) studied by settling column measurements, the optimum flocculant ratio was observed to increase with decreasing clay concentration, for fixed mixing conditions. The optimum flocculant to clay ratio was not always corresponding to the clearest supernatant and the size of flocs at optimum dosage was dependent on the mixing efficiency. The equilibrium floc size at a given shear rate was found to be dependent on the shear history of the floc and the current applied shear. This was confirmed by both light scattering and rheological analysis.