Nowadays, the application of glass-fibre composites in light-weight structures is growing. Although mechanical characterizations of those structures are commonly performed in testing, chemical changes of materials under stresses have not yet been well documented. In the present work coupon tests and Hyperspectral Imaging (HSI) have been used to categorise possible chemical changes of glass-fibre reinforced polymers (GFRP) which are currently used in the aircraft industry. HSI is a hybrid technique that combines spectroscopy with imaging. It is able to detect chemical degradation of surfaces and has already been successfully applied in a wide range of fields including astronomy, remote sensing, cultural heritage and medical sciences. GFRP specimens were exposed to two different thermal loading conditions. One thermal loading condition was a continuous thermal exposure at 120°C for 24h, 48 h and 96h, i.e. ageing at a constant temperature. The other thermal loading condition was thermal cycling with three different numbers of cycles (4000, 8000, 12000) and two temperature ranges (0°C to 120°C and -25°C to 95°C). The effects of both conditions were measured using both HSI and interlaminar shear (ILSS) tests. No significant changes of the physical properties of the thermally cycled GFRP specimens were detected using interlaminar shear strength tests and optical microscopy. However, when using HIS, differences of the surface conditions were detected. The results showed that the different thermal loading conditions could be successfully clustered in different colours, using the HSI linear unmixing technique. Each different thermal loading condition showed a different chemical degradation level on its surface which was indicated using different colours. @en

Background Hyperspectral imaging is a technique that enables the mapping of spectral signatures across a surface. It is most commonly used for surface chemical mapping in fields as diverse as satellite remote sensing, biomedical imaging and heritage science. Existing models, such as the Kubelka-Munk theory and the Lambert-Beer law also relate layer thickness with absorption, and in the case of the Kubelka-Munk theory scattering, however they are not able to fully describe the complex behavior of the light-layer interaction. Methods This paper describes a new approach for hyperspectral imaging, the mapping of coating surface thickness using a coefficient-independent scattering model. The approach taken in this paper is to model the absorption and scattering behavior using a developed coefficient-independent model, calibrated using reference sample thickness measurements performed with optical coherence tomography. Results The results show that this new model, by considering the spectral variation that can be recorded by the hyperspectral imaging camera, is able to measure coatings of 250 μm thickness with an accuracy of 11 μm in a fast and repeatable way. Conclusions The new coefficient-independent scattering model presented can successfully measure the thickness of coatings from hyperspectral imaging data. @en

The adhesion process of bonded structures is a very sensitive manufacturing process, namely to surface contaminations. Nowadays, the adhesion quality of bonded joints can only be detected by destructive testing such as peel tests. But, for actual structures destructive testing of every bonded part is obviously not an option and industry is lacking a non-destructive test to quantify adhesion strength. In this work a methodology is described that could lead to a successful detection of possible contamination agents during the manufacturing process of bonded structures. Hyperspectral imaging is an optical non-destructive technique that allows mapping of specific chemical characteristics of a surface in high contrast. It is a well-recognized technique that has already been successfully applied in a wide range of fields including astronomy, remote sensing, cultural heritage and medical sciences. Multiple sets of aged and non-aged peel tests were destructively tested under different conditions. One type of adhesively bonded specimens was studied: aluminium-to-aluminium using standard floating roller peel test (ASTM D3167). Five sets of samples with different aging conditions were tested. After destructive testing, the contamination level of the fracture surfaces of the bonded specimens were studied using hyperspectral imaging. The hyperspectral imaging system used was a line-scan spectral imaging device (Imspector V10E spectrograph, SPECIM, Finland) capable of acquiring data in the range of 400 nm – 1000 nm with a bandwidth of 2.8 nm. Three tungsten halogen light sources (30W, Osram) were used for uniform illumination across all the sensitivity range of the sensor. The resulting images of each specimen had a resolution of 1312 * 300 pixels, with an exposure time of 200 msec. Following acquisition, all measurements were normalized with the use of a white diffuse reference target (WS1, Ocean Optics). Reference reflectance spectra were extracted from suspicious areas and a non-negative-least-square un-mixing algorithm was applied to check for chemical similarities. Two main signals were detected and mapped onto the surfaces. Statistical analysis was performed, based on the mapping results that described the surface percentage coverage of the contaminant signals and the related statistical errors. A correlation between the percentage of contamination and the adhesive failure was found. Results are promising and will be further studied with other techniques and chemical analyses to fully understand the level of contamination.@en

This work concerns the automatic registration of spectral images of paintings upon planar, or approximately planar, surfaces. An approach that capitalizes upon this planarity is proposed, which estimates homography transforms that register the spectral images into an aligned spectral cube. Homography estimation methods are comparatively evaluated for this purpose. A non-linear, robust estimation method that is based on keypoint features is adopted, as the most accurate. A marker-based, quantitative evaluation method is proposed for the measurement of multispectral image registration accuracy and, in turn, utilized for the comparison of the proposed registration method to the state of the art. For the same purpose, characteristic for this application domain, benchmark datasets that are annotated with correctly corresponding points have been compiled and are publicly availed.@en

This work concerns the automatic registration of spectral images of paintings upon planar, or approximately planar, surfaces. An approach that capitalizes upon this planarity is proposed, which estimates homography transforms that register the spectral images into an aligned spectral cube. Homography estimation methods are comparatively evaluated for this purpose. A non-linear, robust estimation method that is based on keypoint features is adopted, as the most accurate. A marker-based, quantitative evaluation method is proposed for the measurement of multispectral image registration accuracy and, in turn, utilized for the comparison of the proposed registration method to the state of the art. For the same purpose, characteristic for this application domain, benchmark datasets that are annotated with correctly corresponding points have been compiled and are publicly availed.@en

Gilt leather was one of the most fashionable and costly types of wall hangings in the Western world in the 16th to 18th centuries. Despite its appearance, it is not real gold that creates the golden shine, but typically a silver leaf which is coated with an orange-brown lacquer to obtain a golden lustre. Gilt leather has its origins in North-Africa, and the technique was widely practiced in Southern Europe through the middle ages and Renaissance. By the mid-17th century Dutch gilt leather had a similar fame to Delftware and Dutch paintings. Despite this only a small fraction of the large amounts of gilt leather wall hangings produced in Europe has been preserved. Gilt leather is a layered composite of organic and inorganic materials, including leather, animal glue, silver leaf, varnish, oil paint – materials which fall within different conservation disciplines. The aging of gilt leather is characterized by the specific degradations of each of the applied materials, and the possible interactions between them. Some common conservation treatments practiced in the past, such as oiling the leather, have negative side effects, such as gloss and colour change (darkening) and stiffening of the support. Furthermore, most of the surviving gilt leather decorative sections show traces of surface cleaning, such as abrasion, re-varnishing or the application of other protective coatings. Hyperspectral imaging has a wide range of applications in astronomy, biology, chemistry, medicine and quality control. Within the domain of art history, archaeology and conservation, hyperspectral imaging has been used since the 1990’s, mostly for the examination of paintings and manuscripts. It has proved a successful tool for revealing things that are invisible to the naked eye, for example varnish layers, overpaints or underdrawings. In this study the research team investigated a collection of gilt leather objects at SRAL (Stichting Restauratie Atelier Limburg, Maastricht) using an imaging monochromator IMSPECTOR V10E (Specim©, spatial resolution 1300 pixels, wavelength range 400-1000 nm, bandwidth 2.8nm). Scanning of selected case study objects was performed with an automated 3D scanning platform, developed at TU Delft. The objective lens enabled imaging of an approximately 100 mm of field of view. The sample was illuminated by 3 tungsten lamps (30W Halogen) at a 45° angle to avoid specular reflections and to ensure that only diffuse scattering caused by the surface roughness and scattering centres underneath the surface were recorded by the camera. The technique is non-invasive and non-destructive to the studied object. The data was recorded in February 2016 and is currently being analysed using the TIPP software platform, developed at TU Delft. This software platform includes algorithms to perform filtering and un-mixing of hyperspectral data cubes, along with memory management for large data sets and tools for data visualization. Data processing will be performed within the next months, with the objective of mapping areas of surface chemical degradation or change in composition due to earlier conservation treatments. Results will be included in the full paper.@en