Concrete is an ageing viscoelastic material exhibiting both elastic (instantaneous) as well as viscous (time-dependent) deformation under loading conditions (either external or internal). There is a limited number of studies focused on the time-dependent response of alkali-activated concretes (AACs) under loading/unloading conditions. Creep of AAC is a complex phenomenon, which is influenced by exposure conditions of the material, including the loading magnitude, temperature, relative humidity, thermal and drying histories; as well as chemical composition and phase assemblages (e.g., type and amount of reaction products) present in the cementitious matrix. AAC has shown very vibrable creep behaviors, due to different raw materials and processes using during their production. Creep studies on room temperature cured slag-based AAC usually show high creep; however, creep studies of different AACs, including fly ash-based and fly ash-slag-blended, indicate that elevated temperature curing could be a suitable mitigation strategy for reducing creep. This is associated with the development of a more mature microstructure in the material, due to an accelerated reaction kinetics and a consequent increase in strength and lower creep. However, applying a curing temperature above 80 °C causes thermal defects and cracks which increases the creep. For most aluminosilicate-based AACs that produced with fly ash, metakaolin and their blends with a small amount of ground granulated blast furnace slag, the recommended curing method is to use thermal curing at about 60 °C. In addition, curing time and initial loading time are also important. It must be noted that because of the complexity of raw materials properties and mix proportions, there is no universal method for all types of AACs. The existing creep prediction models for Portland cement-based concretes cannot be transferred and adopted in AACs directly due to the distinct nature of hydration products. Therefore, more studies investigated the creep at both small size and full-scale of AACs are urgently needed.

In this paper, the atomic structures of sodium aluminosilicate hydrate (N–A–S–H) gels with different Si/Al ratios are studied by molecular dynamics simulation. An N–A–S–H gel model was obtained from the polymerization of Si(OH)₄ and Al(OH)₃ monomers with the use of a reactive force field (ReaxFF). The simulated atomic structural features, such as the bond length, bond angle, and simulated X-ray diffraction pattern of the gel structure are in good accordance with the experimental results in the literature. Si–O–Al is found to be preferred over Si–O–Si in the N–A–S–H gel structure according to the amount of T–O–T bond angles and distribution of Si⁴(mAl). Pentacoordinate Al is identified in all simulated N–A–S–H models. It provides strong support to current knowledge that pentacoordinate Al in geopolymer does not only come from raw material. Furthermore, the structural analysis results also show that N–A–S–H gel with lower Si/Al ratios has a more cross-linked and compacted structure.

This study aims to compare the developments of mechanical properties and autogenous shrinkage related properties of alkali-activated materials-based concrete (AC) and ordinary Portland cement-based concrete (OC) against curing age and degree of reaction. Temperature Stress Testing Machines are utilized to monitor the evolution of the internal tensile stress and the cracking occurrence in the restrained concrete. It is found that AC shows lower tensile strength-to-compressive strength ratios than OC. The mechanical properties of both OC and AC can be modelled by a power law against the degree of reaction. AC shows higher autogenous shrinkage, but later cracking than OC when under restrained condition. However, the degrees of reaction at which AC and OC cracked are very similar. From the autogenous shrinkage, the elastic modulus and the self-induced stress, the elastic and creep deformations of the concrete can be calculated. AC is found to show much higher creep coefficient than OC.

This paper aims to study the adhesion mechanism of polyvinyl alcohol (PVA) fiber within alkali-activated slag/fly ash (AASF) matrix using molecular dynamics (MD) simulation in combination with systematic experimental characterization. The adhesion of PVA to C-(N-)A-S-H gel with different Ca/(Si+Al) and Al/Si ratios was modeled using MD simulation, with the related adsorption enthalpy calculated and the adhesion mechanism explored. The experimentally attained chemical bonding energy of PVA fiber in AASF coincides well with the simulation results. In both cases, the adhesion enhances primarily with increasing Ca/(Si+Al) ratio of C-(N-)A-S-H gel. Additionally, MD simulation indicates preferential element distributions of Ca around PVA molecule, which was confirmed experimentally by the detection of the Ca-rich C-(N-)A-S-H gel in the interfacial transition zone (ITZ). This study provides further insights into the adhesion mechanism of PVA fiber to C-(N-)A-S-H gel formed in AASF, which is particularly valuable for the future development of PVA-based high-performance alkali-activated composites.

Alkali activated concrete (AAC) has not received broader industry acceptance, one reason of which lies in the uncertainties in the durability against shrinkage and potential cracking. Many studies reported that AAC exhibit larger autogenous shrinkage than OPC concrete. However, it is unable to deduce that AAC should show higher cracking potential than OPC concrete only based on the higher autogenous shrinkage of AAC. The cracking potential of concrete is determined by multiple factors including autogenous shrinkage, creep/relaxation, elastic modulus, and tensile properties of the concrete. However, very few studies have considered these parameters. Furthermore, the influence of precursors (e.g. slag or fly ash) on the cracking potential of AAC induced by autogenous shrinkage is also rarely studied. The aim of this study, therefore, is to investigate the autogenous shrinkage-induced cracking potential of slag and fly ash-based AAC. The free autogenous shrinkage of the specimens is measured by Autogenous Deformation Testing Machine (ADTM). The autogenous shrinkage-induced stress and cracking of the concrete under restraint condition is tracked by Thermal Stress Testing Machine (TSTM). Additionally, the influence of precursors on the autogenous shrinkage induced cracking potential is discussed.