Although the Planchón-Peteroa Volcanic Complex (PPVC) has undergone many hazardous eruptions, only a small number of geological, geochemical, and geophysical studies have been performed to describe this active volcanic system. In order to characterize the subsurface structures present at the PPVC, we applied seismic interferometry to fracture seismicity originating in this volcanic complex and along active geologic faults located nearby. We utilized seismic data recorded by two arrays of stations deployed in Argentina and Chile. Nine of these stations (three in Chile and six in Argentina) recorded data simultaneously and were used for this application. Only seismic events with energy arriving (sub) vertically to the stations were chosen for processing. According to the magnitude and the location of the selected seismic events, relocated seismic sources were used for the Chilean stations while, for the Argentine stations, only seismic sources located near that array were used. We obtained seismic evidence of the location of the subsurface reflectors underneath each station using zero-offset reflection responses retrieved from seismic interferometry by autocorrelation of (time windows extracted from) the selected seismic events. Then, applying a comparative analysis between the seismic results and the available geological information, we imaged the shallow subsurface of the area enclosed by the Chilean stations, and also by the Argentine stations. The results are consistent with the available geological information, provide accurate depth values for several subsurface discontinuities, indicate areas of higher heterogeneity, and support the emplacement of a magma body at ∼4 km depth from the surface. This work shows the first application of a novel variation of seismic interferometry based on autocorrelations to local-earthquake data recorded in a volcanic area.