MAX phases are a family of ternary carbide or nitride ceramics possessing a layered crystal structure and, due to their chemical bonds having a mixed covalent-ionic-metallic nature, have unique properties combining those of metals and ceramics. In this review, the formation mechanisms of MAX phases from elemental and compound powders are reviewed in detail, as the formation mechanisms are closely related to the unique properties of well-synthesized MAX phases. The stability of MAX phases in some harsh external environments is significantly influenced by the defect population, allowing the mechanisms of defect formation and migration to strongly influence their self-healing performance and radiation tolerance. The properties of MAX phases can be tailored by creating solid solutions, which have lattice distortions, and texturing which results in the preferential orientation of plate-like grains.

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In this study, we demonstrate the importance of incorporating shippers’ preference heterogeneity into the optimization of the China Railway express network. In particular, a bilevel programming model is established to minimize the total construction cost for the government in the upper level and maximize the shippers’ satisfaction in the lower level. The proposed model considers price, time, reliability, frequency, safety, flexibility, traceability, and emission. Two designs are obtained by applying the model to two scenarios, in which one is of the aggregate shipper group and the other is of the three distinct clusters. Results show that explicitly including heterogeneity in network optimization pays off in terms of the dramatic increase in shippers’ satisfaction and the share of the sustainable railway without generating extra cost for the system. The results of this study could lead to insightful implication for proper network planning for the China Railway express and some useful suggestions on the subsidies of the government.@en