The corrosion mechanism of microporous nickel-chromium multilayer coatings was studied at localised scale by Scanning Electrochemical Microscopy (SECM) after exposure to an aggressive electrolyte (chloride-based one at pH 3.1 containing cupric ions). The open circuit potential was initially monitored during 22 h, followed by a detailed characterisation using Glow Discharge-Optical Emission Spectroscopy and Field Emission Scanning Electron Microscope. Interestingly, Cu deposition occurs over the surface of the microporous nickel layer, and it is located on spots where micro-discontinuities (i.e., cracks and pores) of the outermost Cr layer are present. The application of different operation modes of the SECM (i.e., redox competition and surface generation/tip collection) not only reveals such copper deposits (which were identified after monitoring their catalytic capabilities for oxygen reduction reaction) but also confirms the stepwise reduction of Cu2+ to Cu (via intermediate species of Cu+) during the corrosion process. The impact of metallic copper particles in the local pH due to their catalytic activity could also explain why the microporous nickel layer is not corroded after exposure to such electrolyte.@en

The impact of the pH on the corrosion of microporous nickel-chromium coatings has been explored at localised scale by Scanning Electrochemical Microscopy and validated by potentiodynamic polarisation measurements. Results not only reveal the correlation between both techniques but also enables to identify the different corrosion rate after increasing the electrolyte aggressiveness varying the pH. However, independently of the pH, a similar corrosion mechanism was determined: the cross-section micrographs (by Field Emission-Scanning Electron Microscope) have revealed an isotropic growth of the actives sites at early-stage corrosion as well as the attack of different nickel layers during the corrosion propagation.@en