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Hybrid d0and d10electronic configurations promote photocatalytic activity of high-entropy oxides for CO2 conversion and water splitting (Journal of Materials Chemistry A (2024) 12 (31589-31602) DOI: 10.1039/D4TA04689G)
Journal article(2025)
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Jacqueline Hidalgo-Jimenez, Taner Akbay, Xavier Sauvage, Lambert van Eijck, Motonori Watanabe, Jacques Huot, Tatsumi Ishihara, Kaveh Edalati
The authors regret that in the original article, the scale bars in Fig. 4b and 5a were incorrect. The authors also regret errors in the orientation of the atomic planes in Fig. 6e. Additionally, the range of the X-axis in Fig. 9a was twice as large as the correct value, and two numbers in Table 3 were incorrectly shown as 12 and 2.95 instead of the correct values, 0.2 and 6.6. These unintentional errors do not affect any other data or the conclusions of the manuscript. The correct Fig. 4 6, 9 and Table 3 are as shown here. (Figure presented) (Table presented) (Figure presented). The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
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The authors regret that in the original article, the scale bars in Fig. 4b and 5a were incorrect. The authors also regret errors in the orientation of the atomic planes in Fig. 6e. Additionally, the range of the X-axis in Fig. 9a was twice as large as the correct value, and two numbers in Table 3 were incorrectly shown as 12 and 2.95 instead of the correct values, 0.2 and 6.6. These unintentional errors do not affect any other data or the conclusions of the manuscript. The correct Fig. 4 6, 9 and Table 3 are as shown here. (Figure presented) (Table presented) (Figure presented). The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
Journal article(2024)
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Jacqueline Hidalgo-Jimenez, Taner Akbay, Xavier Sauvage, L. van Eijck, Motonori Watanabe, Jacques Huot, Tatsumi Ishihara, Kaveh Edalati
Photocatalysis offers a sustainable solution for essential reactions such as CO2 conversion and water splitting, but constraints in catalyst properties like bandgap and active site availability often limit its efficiency. High-entropy oxides (HEOs), which incorporate five or more different cations, present significant potential for this application due to their elemental diversity. This study explores active HEO development for photocatalytic applications by integrating cations with d0 and d10 electronic configurations. A single-phase HEO with a monoclinic structure was successfully synthesized, comprising elements with d0 (titanium, zirconium, niobium and tantalum) and d10 (zinc) electronic configurations. Comprehensive analyses of its microstructure, chemical composition, optical properties and photocatalytic activity were conducted. The resulting TiZrNbTaZnO10 exhibited superior UV and visible light absorption, a low bandgap of 2.5 eV, minimal radiative electron–hole recombination and high stability under photocatalytic conditions. Remarkably, TiZrNbTaZnO10 outperformed the TiZrHfNbTaO11 photocatalyst which contains solely d0 electronic configuration. This enhanced performance is attributed to the mixed electronic configurations fostering heterogeneous chemical environments, which facilitate efficient charge carrier separation and transfer.
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Photocatalysis offers a sustainable solution for essential reactions such as CO2 conversion and water splitting, but constraints in catalyst properties like bandgap and active site availability often limit its efficiency. High-entropy oxides (HEOs), which incorporate five or more different cations, present significant potential for this application due to their elemental diversity. This study explores active HEO development for photocatalytic applications by integrating cations with d0 and d10 electronic configurations. A single-phase HEO with a monoclinic structure was successfully synthesized, comprising elements with d0 (titanium, zirconium, niobium and tantalum) and d10 (zinc) electronic configurations. Comprehensive analyses of its microstructure, chemical composition, optical properties and photocatalytic activity were conducted. The resulting TiZrNbTaZnO10 exhibited superior UV and visible light absorption, a low bandgap of 2.5 eV, minimal radiative electron–hole recombination and high stability under photocatalytic conditions. Remarkably, TiZrNbTaZnO10 outperformed the TiZrHfNbTaO11 photocatalyst which contains solely d0 electronic configuration. This enhanced performance is attributed to the mixed electronic configurations fostering heterogeneous chemical environments, which facilitate efficient charge carrier separation and transfer.
