In this work, a glass/epoxy material system applied in wind turbine blades was used to evaluate degradation processes induced by water ingression. Composite and neat epoxy specimens were conditioned in demineralised water at 50 °C for 4800 h and tested quasi-statically and in fatigue. Comparing results from mechanical tests in composite specimens, significant degradation was found, with up to 36% lower static shear strength and three orders of magnitude shorter fatigue life. For neat epoxy specimens, a lower degree of degradation was observed, with up to 17% lower tensile and bending moduli and strength. Specimens dried after having been immersed were also tested. For composite samples, recovery of shear stiffness and strength was incomplete. For neat resin, stiffness and bending strength were completely recovered but a decrease in the strain at failure was observed. It is hypothesised from differences in magnitude and reversibility of degradation between composite and neat resin that matrix degradation is accompanied by high differential swelling stresses and damage to the fibre/matrix interface in composites. The damage due to moisture ingression and the subsequent changes in failure behaviour are further investigated through thermal analysis (DSC, DMA) and optical microscopy.

Mechanical properties of glass fibre reinforced polymers are dependent on the manufacturing curing cycles. During the laminate manufacturing process, each thickness position experiences a different local curing cycle. Therefore, it can be expected that mechanical properties vary through the thickness, particularly for thick laminates. To study the through-thickness variation of static and fatigue mechanical properties, thick laminates were divided into sub-laminates and these sub-laminates were separately tested. The present work reports temperature profiles through the thickness recorded during the manufacturing of thick laminates, as well as experimental data from static and fatigue tests (S-N curves) of sub-laminates obtained at different thickness positions. The variation of the mechanical properties through the thickness is discussed and related to the local curing temperatures experienced by each sub-laminate.

In this work, a numerical framework for modelling of hygrothermal ageing in laminated composites is proposed. The model consists of a macroscopic diffusion analysis based on Fick's second law coupled with a multiscale FE² stress analysis in order to take microscopic degradation mechanisms into account. Macroscopic material points are modelled with a representative volume element with random fibre distribution. The resin is modelled as elasto-plastic with damage, and cohesive elements are included at the fibre/matrix interfaces. The model formulations and the calibration of the epoxy model using experimental results are presented in detail. A study into the representative volume element size is conducted, and the framework is demonstrated by simulating the ageing process of a unidirectional specimen immersed in water. The influence of transient swelling stresses on microscopic failure is investigated, and failure envelopes of dry and saturated micromodels are compared.