Zeolitic imidazolate frameworks (ZIFs) based electrocatalysts for CO2 reduction offer unique possibilities for developing advanced materials for this reaction due to their ordered nanoporosity and pore environments, tunable characteristics and high affinity for CO
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Zeolitic imidazolate frameworks (ZIFs) based electrocatalysts for CO2 reduction offer unique possibilities for developing advanced materials for this reaction due to their ordered nanoporosity and pore environments, tunable characteristics and high affinity for CO2. Still, they were not investigated sufficiently. In this study, we developed a Bismuth nanodots embedded Zeolitic Imidazolate Framework-8 (BND-ZIF-8) electrocatalyst via a one-pot synthesis method for the electrochemical CO₂ reduction reaction (eCO₂RR). Comprehensive spectroscopic and electrochemical characterization confirmed the successful integration of Bismuth into the ZIF-8 matrix. The electrocatalytic performance of the BND-ZIF-8 was assessed in multiple reactor typologies such as H-cell, flow cell, and membrane electrode assembly (MEA) setups. Remarkable differences in the performances in the three cell configurations are evidenced. Notably, the MEA configuration exhibited a marked enhancement in formate selectivity, achieving a Faradic efficiency (FE) of up to 91 % at a current density of −150 mA cm‒². This work underscores the potential of Bi-ZIF-8 in advancing eCO₂RR while remarking on the crucial importance of the appropriate type of electrocatalytic experiments in assessing the material performance.