Impact of Spin-Entropy on the Thermoelectric Properties of a 2D Magnet

Journal Article (2024)
Author(s)

Alessandra Canetta (Université Catholique de Louvain)

Serhii Volosheniuk (Kavli institute of nanoscience Delft, TU Delft - QN/van der Zant Lab)

Sayooj Satheesh (Max Planck Institute for Solid State Research)

José Pedro Alvarinhas Batista (Université de Liège)

Aloïs Castellano (Université de Liège)

Riccardo Conte (TU Delft - QN/van der Zant Lab, Kavli institute of nanoscience Delft)

Daniel George Chica (Columbia University)

Herre S.J. van der Zant (TU Delft - QN/van der Zant Lab, Kavli institute of nanoscience Delft)

Pascal Gehring (Université Catholique de Louvain)

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Research Group
QN/van der Zant Lab
DOI related publication
https://doi.org/10.1021/acs.nanolett.4c00809 Final published version
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Publication Year
2024
Language
English
Research Group
QN/van der Zant Lab
Bibliographical Note
Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.
Journal title
Nano Letters
Issue number
22
Volume number
24
Pages (from-to)
6513-6520
Downloads counter
177
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Abstract

Heat-to-charge conversion efficiency of thermoelectric materials is closely linked to the entropy per charge carrier. Thus, magnetic materials are promising building blocks for highly efficient energy harvesters as their carrier entropy is boosted by a spin degree of freedom. In this work, we investigate how this spin-entropy impacts heat-to-charge conversion in the A-type antiferromagnet CrSBr. We perform simultaneous measurements of electrical conductance and thermocurrent while changing magnetic order using the temperature and magnetic field as tuning parameters. We find a strong enhancement of the thermoelectric power factor at around the Néel temperature. We further reveal that the power factor at low temperatures can be increased by up to 600% upon applying a magnetic field. Our results demonstrate that the thermoelectric properties of 2D magnets can be optimized by exploiting the sizable impact of spin-entropy and confirm thermoelectric measurements as a sensitive tool to investigate subtle magnetic phase transitions in low-dimensional magnets.

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