Enhanced Interface Adhesion by Novel Eco-Epoxy Adhesives Based on the Modified Tannic Acid on Al and CFRP Adherends
Nataša Z. Tomić (University of Belgrade)
M. N. Saleh (TU Delft - Structural Integrity & Composites)
Sofia Teixeira de Freitas (TU Delft - Structural Integrity & Composites)
Andreja Živković (University of Belgrade)
Marija M. Vuksanović (University of Belgrade)
Hans Poulis (TU Delft - Adhesion Institute)
Aleksandar Marinković (University of Belgrade)
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Abstract
This paper presents a new process for obtaining eco-epoxide adhesives synthesized from bio-renewable raw material (tannic acid-TA) and used for bonding lightweight materials (aluminum (Al) and carbon fiber reinforced polymer (CFRP). Two synthesized bio-epoxy components based on TA, (A) glycidyl ether and (B) glycidyl phosphate ester of TA, were used as a replacement for the toxic epoxy component based on Bisphenol A. The effect of eco-epoxy components on the interface adhesion was measured by the determination of adhesion parameter b, which was compared to the reference epoxy (REF). The increase of adhesion parameter b was 77.5% for A and 151.5% for B. The adhesion of both eco-adhesives was tested using the bell peel test (BPT) with the Al and CFRP adherends. When compared to REF, the average peel load for B was 17.6% (39.3%) and 58.3% (176.9%) higher for the Al and CFRP adherends, respectively. Complete adhesion failure of REF reflected the weak adhesion to both Al and CFRP, which was improved by the addition of eco-epoxy components A and B showing the presence of cohesive failure. The microhardness testing method of interface adhesion was proven to be a fast and reliable testing method, providing a qualitative indication in adhesive selection.
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