Engineering of Hexagonal Microtextures on Glass

Journal Article (2025)
Author(s)

Govind Padmakumar (TU Delft - Electrical Engineering, Mathematics and Computer Science)

Aravind Balaji (TU Delft - Mechanical Engineering)

Matthias Criel (TU Delft - Electrical Engineering, Mathematics and Computer Science)

Federica Saitta (TU Delft - Electrical Engineering, Mathematics and Computer Science)

Gianluca Limodio (TU Delft - Electrical Engineering, Mathematics and Computer Science)

Paula Perez-Rodriguez (TU Delft - Electrical Engineering, Mathematics and Computer Science)

René A.C.M.M. van Swaaij (TU Delft - Electrical Engineering, Mathematics and Computer Science)

Arno H.M. Smets (TU Delft - Electrical Engineering, Mathematics and Computer Science)

Research Group
Photovoltaic Materials and Devices
DOI related publication
https://doi.org/10.1021/acsaom.5c00328 Final published version
More Info
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Publication Year
2025
Language
English
Research Group
Photovoltaic Materials and Devices
Journal title
ACS Applied Optical Materials
Issue number
10
Volume number
3
Pages (from-to)
2360-2372
Downloads counter
110
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Abstract

Textured glass is used in a wide range of applications to improve optoelectrical performances, such as photovoltaics, biosensing, microfluidics, and photonics. Honeycomb textures have demonstrated an excellent performance in optical devices using crystalline silicon wafers as opaque substrates. As a pathway to translate these advantages to configurations implementing glass, hexagonal-shaped microsized craters (honeycombs) are made on glass in this study. We use photolithography combined with wet etching for this process. The relationship between photoresist mask design, glass–photoresist adhesion, wet-etching steps, and the mechanism of honeycomb formation is studied. It is demonstrated that the higher the isotropic nature of etching achieved, the deeper the hexagonal craters will be. The potential of hexagonal textures on glass to significantly reduce reflection to <8% over the entire spectral range is observed. Finally, hexagonal microsized textures with 5 μm periodicity and 1.01 μm depth that effectively diffuse 50% of the total transmitted light at near-infrared (1100 nm) wavelengths are developed.