SnSe2 결함 도입으로 인한 SnSe의 고온 열전성능 증대 메커니즘

SnSe2 결함 도입으로 인한 SnSe의 고온 열전성능 증대 메커니즘

JunSu, Kim (The University of Seoul)
Seong-Mee, Hwang (The University of Seoul)
Hyunjin, Park (The University of Seoul)
Tang, Y. (TU Delft Aerospace Structures & Computational Mechanics)
Won-Seon, Seo (Yonsei University)
Chae Woo, Ryu (Hongik University)
Heesun, Yang (Hongik University)
Weon Ho, Shin (Kwangwoon University)
Hyun-Sik, Kim (The University of Seoul)

2023

SnSe is a promising thermoelectric material due to its low toxicity, low thermal conductivity, and multiple valence band structures, which are ideal for high electronic transport properties. The multiple valence band structure has attracted many attempts to engineer the carrier concentration of the SnSe via doping, to place its fermi level at a position where the maximum number of valence bands can participate in the electronic transport. Up until now, ~5 × 10¹⁹ cm^-3 was the highest carrier concentration achieved in SnSe via doping. Recently, introducing SnSe₂ into SnSe was found to effectively increase the carrier concentration as high as ~6.5 × 10¹⁹ cm^-3 (at 300 K) due to the generated Sn vacancies. This high carrier concentration at 300 K, combined with the reduction in lattice thermal conductivity due to SnSe₂ micro-domains formed within the SnSe lattice, improved the thermoelectric performance (zT) of SnSe – xSnSe₂ as high as ~2.2 at 773 K. Here, we analyzed the changes in the electronic band parameters of SnSe as a function of temperature with varying SnSe₂ content using the Single Parabolic Band (SPB) model. According to the SPB model, the calculated density-of-states effective mass and the fermi level are changed with temperature in such a way that the Hall carrier concentration (n_H) of the SnSe – xSnSe₂ samples at 773 K coincides with the optimum n_H where the theoretically maximum zT is predicted. To optimize the n_H at high temperatures for the highest zT, it is essential to tune the 300 K n_H and the rate of n_H change with increasing temperature via doping.

Carrier concentration
High-temperature zT
Power factor
Single Parabolic Band model
SnSe

http://resolver.tudelft.nl/uuid:7467a69b-b18d-47c0-81e7-2061a943128e

https://doi.org/10.3365/KJMM.2023.61.11.857

2024-03-11

1738-8228

Journal of Korean Institute of Metals and Materials, 61 (11), 857-866

Institutional Repository

journal article

© 2023 Kim JunSu, Hwang Seong-Mee, Park Hyunjin, Y. Tang, Seo Won-Seon, Ryu Chae Woo, Yang Heesun, Shin Weon Ho, Kim Hyun-Sik