From Lab to Market: Evaluating Performance Metrics for Electrochemical Ammonia Synthesis versus Haber-Bosch

Master thesis (2023)

Authors

A.C.E. Vlierboom Electrical Engineering, Mathematics and Computer Science

Contributors

R. Kortlever Large Scale Energy Storage - Mechanical, Maritime and Materials Engineering (supervisor 1)
W. de Jong Large Scale Energy Storage - Mechanical, Maritime and Materials Engineering (supervisor 1)
B. Izelaar Large Scale Energy Storage - Mechanical, Maritime and Materials Engineering (supervisor 1)
M. Ramdin Engineering Thermodynamics - Mechanical, Maritime and Materials Engineering (supervisor 1)
Mar Pérez-Fortes Energy and Industry (supervisor 1)
Faculty
Electrical Engineering, Mathematics and Computer Science
Copyright: © 2023 Alexander Vlierboom
Conceptual process design Ammonia Electrochemical nitrogen reduction reaction , techno-economic analysis Energy analysis
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Published Date

15-05-2023

Language

English

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Faculty

Electrical Engineering, Mathematics and Computer Science

Abstract

Ammonia (NH3) is a bulk commodity chemical known for its large production volumes and application in the global fertiliser industry, and is more recently being explored for its role as a sustainable energy vector. The industry standard ammonia production method is the century-old Haber-Bosch (HB) process, which is power by fossil fuels, and is accompanied with high energy intensity and large carbon-dioxide emissions. In this research, conceptual processes for the electrochemical synthesis of ammonia via the direct electrochemical nitrogen reduction reaction (e-NRR) from air and water were developed to assess their technical and economic viability compared to the HB benchmark. Different scales (91, 544 and 2055 t d-1) and electrolyzer cell configurations (alkaline electrolyzer (AEL), gas-diffusion electrode flow cell (GDE) and solid oxide electrolyzer (SOEL)) were considered. The results showed that small-scale production is more feasible for e-NRR NH3 synthesis due to the economies of scale of the HB benchmark. Among different electrolyzer types, the gas-diffusion electrode flow cell was found to be the most practical and economical for e-NRR NH3 synthesis. A sensitivity analysis showed that the electricity price is the most important parameter for the feasibility of e-NRR, and should ideally be as low as possible. Performance parameters of the electrolyzer, such as stack cost, operational current density, and faradaic efficiency, were optimized for minimal NH3 production cost, but were challenging to estimate due to the early stage of e-NRR technology. An optimized case was presented that demonstrated e-NRR NH3 can reach HB-parity, but the validity of the optimised parameters was difficult. It is advised that reliable laboratory-scale demonstrations are needed for an accurate assessment of the commercial feasibility of electrochemical NH3 synthesis.