A prospective life cycle assessment of global ammonia decarbonisation scenarios

A prospective life cycle assessment was performed for global ammonia production across 26 regions from 2020 to 2050. The analysis was based on the IEA Ammonia Roadmap and IMAGE electricity scenarios model for three climate scenarios related to a mean surface temperature increase of 3.5 °C, 2.0 °C, and 1.5 °C by 2100. Combining these models...

Hot air recirculation enlarges efficient operating window of reversible solid oxide cell systems: A thermodynamic study of energy storage using ammonia

Energy storage is vital for the energy transition, enabling reliable power grids based on intermittent renewables. Reversible solid oxide cell (rSOC) technology is promising for seasonal energy storage. The novel finding from this work is that optimised air recirculation for rSOC in endothermic electrolyser mode leads to efficiency being...

CommodipHy: The commodification of ammonia and the role of Rotterdam as a global pricing centre

Electrochemical Ammonia Synthesis: Hydrogen Permeable Electrodes as Alternative Pathway for Nitrogen Reduction

In the last century, the indiscriminate use of fossil energy to power the industrial revolution and technological progress of humankind, has led to the depletion of limited natural resources and, most importantly, the emission and accumulation of alarming levels of pollutants and greenhouse gases (GHG) in the atmosphere. One of the major...

Hazard Identification of Hydrogen-Based Alternative Fuels Onboard Ships

It is essential to use alternative fuels if we are to reach the emission reduction targets set by the IMO. Hydrogen carriers are classified as zero-emission, while having a higher energy density (including packing factor) than pure hydrogen. They are often considered as safe alternative fuels. The exact definition of what safety entails is often...

Optimization of multilayer graphene-based gas sensors by ultraviolet photoactivation

Nitrogen dioxide (NO₂) is a potential hazard to human health at low concentrations, below one part per million (ppm). NO₂ can be monitored using gas sensors based on multi-layered graphene operating at ambient temperature. However, reliable detection of concentrations on the order of parts per million and lower is...

The AmmoniaDrive Research Project

Several news items and short movies have appeared online recently, announcing that the AmmoniaDrive Consortium was awarded a prestigious NWO Perspectief grant. But what is the AmmoniaDrive research project? How does it contribute to combatting shipping-induced climate change? Who are in the consortium and why? And finally, what research...

Selectivity of vacuum ammonia stripping using porous gas-permeable and dense pervaporation membranes under various hydraulic conditions and feed water compositions

Recovery of ammonia (NH₃) from residual waters offers various reuse opportunities, such as the production of fertilisers and the generation of electricity and heat. However, simultaneous evaporation of water (H₂O) during NH₃ stripping under vacuum results in diluted recovered NH₃ gas with high H<sub...

Predicting major hazard accidents in the process industry based on organizational factors: A practical, qualitative approach

OCI Nitrogen seeks to gain knowledge of (leading) indicators regarding the process safety performance of their ammonia production process. The current sub-study raises the question whether major hazard accidents in the ammonia production process can be predicted from organizational factors, also called management delivery systems. This paper...

Determining a realistic ranking of the most dangerous process equipment of the ammonia production process: A practical approach

OCI Nitrogen seeks to gain knowledge of (leading) indicators regarding the process safety performance of their ammonia production process. The current research determines the most dangerous process equipment by calculating their effects resulting from a loss of containment using DNV GL's Phast™ dispersion model. In this paper, flammable and...

Predicting major accidents in the process industry based on the barrier status at scenario level: A practical approach

OCI Nitrogen wants to gain knowledge of (leading) indicators regarding the process safety performance of their ammonia production process. This paper answers the question whether indicators can be derived from the barrier system status to provide information about the development and likelihood of the major accident processes in the ammonia...

Thermodynamics of Industrially Relevant Systems: Method Development and Applications

Improving and developing simulation techniques are key to obtaining higher efficiency and accuracy in molecular simulations of dense liquid systems. The methodology development introduced in this thesis is relevant both for academia and industrial applications. In this thesis, the methods developments/improvements for molecular simulations are...

Mechanical integrity of process installations: Barrier alarm management based on bowties

A Safety Research project was carried out in an ammonia plant of OCI Nitrogen, located at the Chemelot site in Geleen, The Netherlands. This research focused on the development of a method to monitor accident processes in the chemical industry mainly caused by mechanical integrity of static equipment like vessels, tanks and heat exchangers. A...

Highly efficient absorption heat pump and refrigeration systems based on ionic liquids: Fundamentals & Applications

Improving efficiencies of thermal energy conversion systems is an important way to slow down global warming and mitigate climate change. Vapor absorption heat pump and refrigeration cycles are highly efficient ways of heating and cooling. These thermally activated systems also provide opportunities for the integration with a wide spectrum of low...

Ammonia absorption in ionic liquids-based mixtures in plate heat exchangers studied by a semi-empirical heat and mass transfer framework

Unfavorable transport properties have always been pointed out as the key factors that hinder the application of ammonia/ionic liquids (NH ₃ /ILs) in absorption cycles, while heat and mass transfer of these new fluids in components have been rarely reported. In this study, a corrugated plate heat exchanger is selected as the...

Ammonia/ionic liquid based double-effect vapor absorption refrigeration cycles driven by waste heat for cooling in fishing vessels

To use high-temperature waste heat generated by diesel engines for onboard refrigeration of fishing vessels, an ammonia-based double-effect vapor absorption refrigeration cycle is proposed. Non-volatile ionic liquids are applied as absorbents in the double-effect absorption system. In comparison to systems using ammonia/water fluid, the...

CVD transfer-free graphene for sensing applications

The sp² carbon-based allotropes have been extensively exploited for the realization of gas sensors in the recent years because of their high conductivity and large specific surface area. A study on graphene that was synthetized by means of a novel transfer-free fabrication approach and is employed as sensing material is herein...