Mechanistic insight into the improved photocatalytic degradation of dyes for an ultrathin coating of SiO₂ on TiO₂ (P25) nanoparticles

The photocatalytic mechanism of TiO₂ (P25) nanoparticles coated with SiO₂ (SiO₂:TiO₂) by atomic layer deposition was investigated. The deposition of SiO₂ on TiO₂ not only gives a photocatalytic improvement for the degradation of both Rhodamine B (3.6–fold) and Acid Blue 9 (3...

Surface functionalized N-C-TiO₂/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H₂ generation

Surface-functionalized nitrogen/carbon co-doped polymorphic TiO₂ phase junction nanoparticles uniformly distributed in porous carbon matrix were synthesized by a simple one-step pyrolysis of titanium based metal–organic framework (MOF), NH₂-MIL-125(Ti) at 700 °C under water vapour atmosphere. Introducing water vapour...

Tuning electron transfer by crystal facet engineering of BiVO₄ for boosting visible-light driven photocatalytic reduction of bromate

Removal of bromate (BrO₃⁻) has gained increasing attention in drinking water treatment process. Photocatalysis technology is an effective strategy for bromate removal. During the photocatalytic reduction of bromate process, the photo-generated electrons are reductive species toward bromate reduction and photo-generated...

Multitarget evaluation of the photocatalytic activity of P25-SiO₂ prepared by atomic layer deposition

This work presents the evaluation of the photocatalytic activity of P25 TiO₂ particles, coated with SiO₂, using atomic layer deposition (ALD) for the photocatalytic removal of methylene blue, oxidation of methanol and inactivation of Escherichia coli bacteria in water and its comparative evaluation with bare P25 TiO<sub...

Synthesis of a rationally designed multi-component photocatalyst pt:Sio₂:Tio₂ (p25) with improved activity for dye degradation by atomic layer deposition

Photocatalysts for water purification typically lack efficiency for practical applications. Here we present a multi-component (Pt:SiO₂:TiO₂ (P25)) material that was designed using knowledge of reaction mechanisms of mono-modified catalysts (SiO₂:TiO₂, and Pt:TiO₂ ) combined with the...

Water purification in a solar reactor incorporating TiO₂ coated mesh structures

The rate of photocatalytic oxidation of contaminants in drinking water using an immobilized catalyst can be increased by properly designing the catalyst structure. By creating a solar reactor in which meshes coated with TiO₂ were stacked, we demonstrated that degradation of humic acids with four superimposed stainless steel meshes...

Combining Photo-Organo Redox- and Enzyme Catalysis Facilitates Asymmetric C-H Bond Functionalization

In this study, we combined photo-organo redox catalysis and biocatalysis to achieve asymmetric C–H bond functionalization of simple alkane starting materials. The photo-organo catalyst anthraquinone sulfate (SAS) was employed to oxyfunctionalise alkanes to aldehydes and ketones. We coupled this light-driven reaction with asymmetric enzymatic...

Photocatalytic activity of functionalized nanodiamond-TiO₂ composites towards water pollutants degradation under UV/Vis irradiation

Pristine nanodiamonds (NDs) obtained by detonation, or functionalized by different treatments, namely oxidation, hydrogenation and amination, were used to synthesize composites by insertion in TiO₂ matrixes. The different treatments of the NDs lead to materials containing diverse texture properties and surface chemistry...

Determination of early warning signs for photocatalytic degradation of titanium white oil paints by means of surface analysis

Titanium white (TiO₂) has been widely used as a pigment in the 20th century. However, its most photocatalytic form (anatase) can cause severe degradation of the oil paint in which it is contained. UV light initiates TiO₂-photocatalyzed processes in the paint film, degrading the oil binder into volatile components...

How Gold Deposition Affects Anatase Performance in the Photo-catalytic Oxidation of Cyclohexane

Gold deposition on Hombikat UV100 was found to negatively affect the activity of this Anatase catalyst in selective photo-oxidation of cyclohexane. By ammonia TPD and DRIFT spectroscopy it was determined that the Au deposition procedure leads to a significant decrease in OH-group density (mol m?2 BET) on Hombikat, suggesting that the amount of...