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Gao, Ziyao (author), Zhao, C. (author), Zhou, Kai (author), Wu, Junru (author), Tian, Yao (author), Deng, Xianming (author), Zhang, Lihan (author), Lin, Kui (author), Wagemaker, M. (author)Nickel-rich layered oxide cathodes promise ultrahigh energy density but is plagued by the mechanical failure of the secondary particle upon (de)lithiation. Existing approaches for alleviating the structural degradation could retard pulverization, yet fail to tune the stress distribution and root out the formation of cracks. Herein, we report...journal article 2024
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Wang, Zaifa (author), Wang, Zhenyu (author), Xue, Dingchuan (author), Zhao, Jun (author), Zhang, Xuedong (author), Geng, Lin (author), Li, Yanshuai (author), Du, Congcong (author), Wagemaker, M. (author)The rock-salt phase (RSP) formed on the surface of Ni-rich layered cathodes in liquid-electrolyte lithium-ion batteries is conceived to be electrochemically "dead". Here we show massive RSP forms in the interior of LiNi<sub>x</sub>Mn<sub>y</sub>Co<sub>(1−x-y)</sub>O<sub>2</sub> (NMC) crystals in sulfide based all solid state batteries (ASSBs)...journal article 2023
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Liang, Jianwen (author), van der Maas, E.L. (author), Luo, Jing (author), Li, Xiaona (author), Chen, Ning (author), Adair, Keegan R. (author), Li, Weihan (author), Li, Junjie (author), Hu, Yongfeng (author), Liu, Jue (author), Zhang, Li (author), Zhao, W. (author), Parnell, S.R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Understanding the relationship between structure, ionic conductivity, and synthesis is the key to the development of superionic conductors. Here, a series of Li<sub>3-3</sub><sub>x</sub>M<sub>1+</sub><sub>x</sub>Cl<sub>6</sub> (−0.14 < x ≤ 0.5, M = Tb, Dy, Ho, Y, Er, Tm) solid electrolytes with orthorhombic and trigonal structures are...journal article 2022