Luminescence of Ce3+ activated fluoro-apatites M5(PO4)3F (M = Ca, Sr, Ba) under VUV—UV and x-ray excitation

Luminescence and site occupancy of Ce3+ in Ba2Ca(BO3)2

Vacuum ultraviolet-ultraviolet and x-ray excited luminescence properties of Ba3Gd(BO3)3:Ce3+

The phosphors Ba3Gd(BO3)3:Ce3+ were prepared by a solid-state reaction technique at high temperature. The vacuum ultraviolet-ultraviolet and visible spectroscopic properties of the phosphors together with decay time curves are investigated and discussed. The spectroscopic properties are explained by occupancy of Ce3+ at two different Gd sites in...

Luminescence of Ce3+ at two different sites in ?-Sr2P2O7 under vacuum ultraviolet-UV and x-ray excitation

A series of Ce3+ doped ?-Sr2?2xCexNaxP2O7 phosphor compounds has been prepared using a high-temperature solid-state reaction technique. The luminescence properties under vacuum ultraviolet-UV and x-ray excitation were studied. Luminescence spectra reveal three UV-emitting peaks at about 310, 330, and 350 nm from which we conclude that Ce3+...

Ultraviolet-vacuum ultraviolet photoluminescence and x ray radioluminescence of Ce3+-doped Ba3MgSi2O8

Ce3+-doped Ba3MgSi2O8 phosphors were prepared by a solid-state reaction route. The photoluminescence properties in the vacuum ultraviolet-vis spectral range and the x ray excited radioluminescence were investigated. Ce3+ ions were found to enter three different sites in the host lattice. Five excitation bands and two emission bands of Ce(1)3+...

Insight into Eu redox and Pr³⁺ 5d emission in KSrPO₄ by VRBE scheme construction

A series of Ln-doped KSrPO₄ (Ln = Ce³⁺, Eu³⁺, Eu²⁺, Pr³⁺) phosphors are prepared through a high-temperature solid-state method. The KSrPO₄ compound is confirmed to possess a β-K₂SO₄ structure with the Pnma group by Rietveld refinement, and the temperature...

Impacts of 5d electron binding energy and electron-phonon coupling on luminescence of Ce ³⁺ in Li ₆ Y(BO ₃ ) ₃

In this work, the crystal structure and electronic structure as well as the synchrotron radiation vacuum ultraviolet-ultraviolet-visible (VUV-UV-vis) luminescence properties of Li ₆ Y(BO ₃ ) ₃ (LYBO):Ce ³⁺ phosphors were investigated in detail. The Rietveld refinement and DFT calculation reveal the...

Site Occupancies, VUV-UV-vis Photoluminescence, and X-ray Radioluminescence of Eu²⁺-Doped RbBaPO₄

RbBaPO4:Eu2+ phosphors have been prepared by a high-temperature solid-state reaction method, and the structure was determined by Rietveld refinement based on powder X-ray diffraction (P-XRD) data. Their VUV-UV-vis photoluminescence properties are systematically investigated with three objectives: (1) based on low-temperature spectra, we...

Experimental and Theoretical Studies of the Site Occupancy and Luminescence of Ce³⁺in LiSr₄(BO₃)₃for Potential X-ray Detecting Applications

Ce3+-doped LiSr4(BO3)3 phosphors have been prepared by a high-temperature solid-state reaction method, and structural refinement of the host compound has been performed. The excitation and emission spectra in the vacuum ultraviolet-ultraviolet-visible range at cryogenic temperatures reveal that Ce3+ ions preferentially occupy eight...

VUV-UV-vis photoluminescence, X-ray radioluminescence and energy transfer dynamics of Ce³⁺ and Eu²⁺ in Sr₂MgSi₂O₇

Ce³⁺ and Eu²⁺ doped and Ce³⁺-Eu²⁺ co-doped Sr₂MgSi₂O₇ phosphors are prepared via a high-temperature solid-state reaction technique. The synchrotron radiation vacuum ultraviolet-ultraviolet (VUV-UV) excitation and ultraviolet-visible (UV-vis) emission spectra of...

Cationic Effects on Photo- and X-ray Radioluminescence of K₃RE(PO₄)₂:Ce³⁺/Pr³⁺ (RE = La, Gd, and Y) Phosphors toward X-ray Detection

Cationic tuning for lanthanide (Ce³⁺/Pr³⁺)-activated inorganic phosphors with stable, efficient, and fast-decay 5d-4f emissions has emerged as an important strategy toward the continuing pursuit of superior scintillators. The in-depth understanding of the cationic effects on photo- and radioluminescence of lanthanides Ce...