Electrochemical CO₂ reduction in membrane-electrode assemblies

Electrochemical conversion of gaseous CO₂ to value-added products and fuels is a promising approach to achieve net-zero CO₂ emission energy systems. Significant efforts have been achieved in the design and synthesis of highly active and selective electrocatalysts for this reaction and their reaction mechanism. To perform...

Hyperpolarised gas filling station for medical imaging using polarised ¹²⁹Xe and ³He

We report the design, construction, and initial tests of a hyperpolariser to produce polarised ¹²⁹Xe and ³He gas for medical imaging of the lung. The hyperpolariser uses the Spin-Exchange Optical Pumping method to polarise the nuclear spins of the isotopic gas. Batch mode operation was chosen for the design to produce...

Importance of Methane Chemical Potential for Its Conversion to Methanol on Cu-Exchanged Mordenite

Copper-oxo clusters exchanged in zeolite mordenite are active in the stoichiometric conversion of methane to methanol at low temperatures. Here, we show an unprecedented methanol yield per Cu of 0.6, with a 90–95 % selectivity, on a MOR solely containing [Cu₃(μ-O)₃]²⁺ active sites. DFT calculations,...