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Strategy to mitigate the dipole interfacial states in (i)a-Si:H/MoOxpassivating contacts solar cells

Mazzarella, L. (author), Alcañiz Moya, A. (author), Kawa, Eliora (author), Procel Moya, P.A. (author), Zhao, Y. (author), Han, C. (author), Yang, G. (author), Zeman, M. (author), Isabella, O. (author)

Electrical simulations show that the dipole formed at (i)a-Si:H/MoOx interface can explain electrical performance degradation. We experimentally manipulate this interface by a plasma treatment (PT) to mitigate the dipole strength without harming the optical response. The optimal PT + MoOx stack results in strongly improved electrical...

conference paper 2020

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Analysis of Transition Metal Oxides based Heterojunction Solar Cells with S-shaped J-V curves

Scire, D. (author), Bonadonna, Marco (author), Zhao, Y. (author), Procel Moya, P.A. (author), Isabella, O. (author), Zeman, M. (author), Macaluso, Robert (author), Mosca, Mauro (author), Crupi, Isodiana (author)

The use of transition metal oxides for the selective carrier contact in the crystalline silicon solar cells technology is rising to interest for the excellent optoelectrical properties of these materials whose implementation, however, can result in lousy performing cells due to an S-shaped electrical characteristic. In this paper, we fabricated...

conference paper 2020

document

Room-temperature sputtered tungsten-doped indium oxide for improved current in silicon heterojunction solar cells

Han, C. (author), Zhao, Y. (author), Mazzarella, L. (author), Santbergen, R. (author), Bento Montes, A.R. (author), Procel Moya, P.A. (author), Yang, G. (author), Zhang, Xiaodan (author), Zeman, M. (author), Isabella, O. (author)

The window layers limit the performance of silicon heterojunction (SHJ) solar cells with front and back contacts. Here, we optimized tungsten-doped indium oxide (IWO) film deposited by radio frequency magnetron sputtering at room temperature. The opto-electrical properties of the IWO were manipulated when deposited on top of thin-film silicon...

journal article 2021

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Oxygen-alloyed poly-Si passivating contacts for high-thermal budget c-Si heterojunction solar cells

Yang, G. (author), Han, C. (author), Procel Moya, P.A. (author), Zhao, Y. (author), Singh, M. (author), Mazzarella, L. (author), Zeman, M. (author), Isabella, O. (author)

Crystalline silicon solar cells with passivating contacts based on doped poly-Si exhibit high optical parasitic losses. Aiming at minimizing these losses, we developed the oxygen-alloyed poly-Si (poly-SiOx) as suitable material for passivating contacts. From passivation point of view, poly-SiOx layers show excellent passivation quality and...

journal article 2022

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Colored optic filters on c-Si IBC solar cells for building integrated photovoltaic applications

Ortiz Lizcano, J.C. (author), Procel Moya, P.A. (author), Calcabrini, A. (author), Yang, G. (author), Ingenito, Andrea (author), Santbergen, R. (author), Zeman, M. (author), Isabella, O. (author)

Building Integrated Photovoltaic systems can produce a significant portion of the energy demand of urban areas. Despite their potential, they remain a niche technology that architects and project engineers still find esthetically limited. The dark blue or black color of standard photovoltaic panels is considered inappropriate for restoration...

journal article 2021

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Will SiOx-pinholes for SiOx/poly-Si passivating contact enhance the passivation quality?

Yang, G. (author), Gram, Remon (author), Procel Moya, P.A. (author), Han, C. (author), Yao, Z. (author), Singh, M. (author), Zhao, Y. (author), Mazzarella, L. (author), Zeman, M. (author), Isabella, O. (author)

Passivating contacts based on poly-Si have enabled record-high c-Si solar cell efficiencies due to their excellent surface passivation quality and carrier selectivity. The eventual existence of pinholes within the ultra-thin SiOx layer is one of the key factors for carrier collection, beside the tunneling mechanism. However, pinholes are usually...

journal article 2023

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Design and optimization of hole collectors based on nc-SiO_x:H for high-efficiency silicon heterojunction solar cells

Zhao, Y. (author), Procel Moya, P.A. (author), Han, C. (author), Mazzarella, L. (author), Yang, G. (author), Weeber, A.W. (author), Zeman, M. (author), Isabella, O. (author)

Low activation energy (E_a) and wide bandgap (E_g) are essential for (p)-contacts to achieve effective hole collection in silicon heterojunction (SHJ) solar cells. In this work, we study Plasma-Enhanced Chemical Vapor Deposition p-type hydrogenated nanocrystalline silicon oxide, (p)nc-SiO_x:H, combined with (p)nc...

journal article 2021

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Strategy to mitigate the dipole interfacial states in (i)a-Si:H/MoO_x passivating contacts solar cells

Mazzarella, L. (author), Alcañiz Moya, A. (author), Procel Moya, P.A. (author), Kawa, Eliora (author), Zhao, Y. (author), Tiringer, U. (author), Han, C. (author), Yang, G. (author), Taheri, P. (author), Zeman, M. (author), Isabella, O. (author)

Molybdenum oxide (MoO_x) is attractive for applications as hole-selective contact in silicon heterojunction solar cells for its transparency and relatively high work function. However, the integration of MoO_x stacked on intrinsic amorphous silicon (i)a-Si:H layer usually exhibits some issues that are still not fully...

journal article 2020

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Ultra-thin electron collectors based on nc-Si:H for high-efficiency silicon heterojunction solar cells

Zhao, Y. (author), Mazzarella, L. (author), Procel Moya, P.A. (author), Han, C. (author), Tichelaar, F.D. (author), Yang, G. (author), Weeber, A.W. (author), Zeman, M. (author), Isabella, O. (author)

Low parasitic absorption and high conductivity enable (n)-type hydrogenated nanocrystalline silicon [(n)nc-Si:H], eventually alloyed with oxygen [(n)nc-SiO_x:H], to be deployed as window layer in high-efficiency silicon heterojunction (SHJ) solar cells. Besides the appropriate opto-electrical properties of these nanocrystalline...

journal article 2021

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A silicon carbide-based highly transparent passivating contact for crystalline silicon solar cells approaching efficiencies of 24%

Köhler, Malte (author), Pomaska, Manuel (author), Procel Moya, P.A. (author), Santbergen, R. (author), Lambertz, Andreas (author), Duan, Weiyuan (author), Eberst, Alexander (author), Luysberg, Martina (author), Isabella, O. (author)

A highly transparent passivating contact (TPC) as front contact for crystalline silicon (c-Si) solar cells could in principle combine high conductivity, excellent surface passivation and high optical transparency. However, the simultaneous optimization of these features remains challenging. Here, we present a TPC consisting of a silicon-oxide...

journal article 2021

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Towards bifacial silicon heterojunction solar cells with reduced TCO use

Han, C. (author), Santbergen, R. (author), van Duffelen, Max (author), Procel Moya, P.A. (author), Zhao, Y. (author), Yang, G. (author), Zhang, Xiaodan (author), Zeman, M. (author), Mazzarella, L. (author), Isabella, O. (author)

Reducing indium consumption, which is related to the transparent conductive oxide (TCO) use, is a key challenge for scaling up silicon heterojunction (SHJ) solar cell technology to terawatt level. In this work, we developed bifacial SHJ solar cells with reduced TCO thickness. We present three types of In₂O₃-based TCOs,...

journal article 2022

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Raman spectroscopy of silicon with nanostructured surface

Kadlečíková, Magdaléna (author), Vančo, Ľubomír (author), Breza, Juraj (author), Mikolášek, Miroslav (author), Hušeková, Kristína (author), Fröhlich, Karol (author), Procel Moya, P.A. (author), Zeman, M. (author), Isabella, O. (author)

We compared the morphology and Raman response of nanoscale shaped surfaces of Si substrates versus monocrystalline Si. Samples were structured by reactive ion etching, and four of them were covered by a RuO₂-IrO₂ layer. Raman bands, centred at approx. 520 cm^–1, belonging to samples processed by etching the Si...

journal article 2022

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Introducing a comprehensive physics-based modelling framework for tandem and other PV systems

Vogt, M.R. (author), Ruiz Tobon, C.M. (author), Alcañiz Moya, A. (author), Procel Moya, P.A. (author), Blom, Y. (author), Nour El Din, A. (author), Stark, T. (author), Wang, Z. (author), Goma, E. Garcia (author), Etxebarria, J. G. (author), Ziar, H. (author), Zeman, M. (author), Santbergen, R. (author), Isabella, O. (author)

We introduce a novel simulation tool capable of calculating the energy yield of a PV system based on its fundamental material properties and using self-consistent models. Thus, our simulation model can operate without measurements of a PV device. It combines wave and ray optics and a dedicated semiconductor simulation to model the...

journal article 2022

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Achieving 23.83% conversion efficiency in silicon heterojunction solar cell with ultra-thin MoO_x hole collector layer via tailoring (i)a-Si:H/MoO_x interface

Cao, L. (author), Procel Moya, P.A. (author), Alcañiz Moya, A. (author), Yan, J. (author), Tichelaar, F.D. (author), Özkol, E. (author), Zhao, Y. (author), Han, C. (author), Yang, G. (author), Yao, Z. (author), Zeman, M. (author), Santbergen, R. (author), Mazzarella, L. (author), Isabella, O. (author)

Thin films of transition metal oxides such as molybdenum oxide (MoO_x) are attractive for application in silicon heterojunction solar cells for their potential to yield large short-circuit current density. However, full control of electrical properties of thin MoO_x layers must be mastered to obtain an efficient hole...

journal article 2022

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Erratum to: Sub-gap defect density characterization of molybdenum oxide: An annealing study for solar cell applications (Nano Research, (2020), 13, 12, (3416-3424), 10.1007/s12274-020-3029-9)

Scire, D. (author), Procel Moya, P.A. (author), Gulino, Antonino (author), Isabella, O. (author), Zeman, M. (author), Crupi, Isodiana (author)

Ref. [56] was unfortunately wrong, Instead of [56] Corless, R. M.; Gonnet, G. H.; Hare, D. E. G.; Jeffrey, D. J.; Knuth, D. E. On the Lambert W function. Adv. Comput. Math. 1996, 5, 329–359. It should be changed to Biswas, R. K.; Khan, P.; Mukherjee, S.; Mukhopadhyay, A. K.; Ghosh, J.; Muraleedharan, K. Study of short range structure of...

journal article 2022

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Strategies for realizing high-efficiency silicon heterojunction solar cells

Zhao, Y. (author), Procel Moya, P.A. (author), Han, C. (author), Cao, L. (author), Yang, G. (author), Özkol, E. (author), Alcañiz, Alba (author), Kovačević, K. (author), Limodio, G. (author), Santbergen, R. (author), Smets, A.H.M. (author), Weeber, A.W. (author), Zeman, M. (author), Mazzarella, L. (author), Isabella, O. (author)

Silicon heterojunction (SHJ) solar cells have achieved a record efficiency of 26.81% in a front/back-contacted (FBC) configuration. Moreover, thanks to their advantageous high V_OC and good infrared response, SHJ solar cells can be further combined with wide bandgap perovskite cells forming tandem devices to enable efficiencies well...

journal article 2023

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Effects of (i)a-Si: H deposition temperature on high-efficiency silicon heterojunction solar cells

Zhao, Y. (author), Procel Moya, P.A. (author), Smets, A.H.M. (author), Mazzarella, L. (author), Han, C. (author), Yang, G. (author), Cao, L. (author), Yao, Z. (author), Weeber, A.W. (author), Zeman, M. (author), Isabella, O. (author)

Excellent surface passivation induced by (i)a-Si:H is critical to achieve high-efficiency silicon heterojunction (SHJ) solar cells. This is key for conventional single-junction cell applications but also for bottom cell application in tandem devices. In this study, we investigated the effects of (i)a-Si:H deposition temperature on passivation...

journal article 2022

document

Poly-crystalline silicon-oxide films as carrier-selective passivating contacts for c-Si solar cells

Yang, G. (author), Guo, Peiqing (author), Procel Moya, P.A. (author), Weeber, A.W. (author), Isabella, O. (author), Zeman, M. (author)

The poly-Si carrier-selective passivating contacts (CSPCs) parasitically absorb a substantial amount of light, especially in the form of free carrier absorption. To minimize these losses, we developed CSPCs based on oxygen-alloyed poly-Si (poly-SiO_x) and deployed them in c-Si solar cells. Transmission electron microscopy analysis...

journal article 2018

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Poly-Si(O)x passivating contacts for high-efficiency c-Si IBC solar cells

Yang, G. (author), Zhang, Y. (author), Procel Moya, P.A. (author), Weeber, A.W. (author), Isabella, O. (author), Zeman, M. (author)

Highest conversion efficiency in crystalline silicon (c-Si) solar cells can be enabled by quenching minority carriers' recombination at c-Si/contact interface owing to carrier-selective passivating contacts. With the semi-insulating poly-crystalline silicon (SIPOS, poly-Si) a very good passivation of c-Si surfaces was obtained. We have...

journal article 2017

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Improving the Back Surface Field on an Amorphous Silicon Carbide Thin Film Photocathode for Solar Water Splitting

Perez Rodriguez, P. (author), Cardenas-Morcoso, Drialys (author), Digdaya, I.A. (author), Mangel Raventos, A. (author), Procel Moya, P.A. (author), Isabella, O. (author), Gimenez, Sixto (author), Zeman, M. (author), Smith, W.A. (author), Smets, A.H.M. (author)

Amorphous silicon carbide (a-SiC:H) is a promising material for photoelectrochemical water splitting owing to its relatively small band-gap energy and high chemical and optoelectrical stability. This work studies the interplay between charge-carrier separation and collection, and their injection into the electrolyte, when modifying the...

journal article 2018