“Mg” Bone: Ink extrusion-based additive manufacturing of Mg implants

The treatment of largy bone defect remains challenging in clinics. All the clinically available bone grafts have their own limitations and are not ideal for the treatment. Therefore, developing a new generation of suitable bone substitutes is urgently needed. In the recent years, porous magnesium (Mg) has been extensively studied for orthopedic...

Biodegradable magnesium matrix composites for bone fixation devices

When a bone is fractured, it loses its structural integrity which makes it unable to bear any mechanical load. Therefore, a broken bone must be supported until it regains its strength to handle the body's movement and weight. A surgical procedure is needed to set a fractured bone. This procedure often involves repositioning the bone fragments...

Influence of HEPES buffer on the local pH and formation of surface layer during in vitro degradation tests of magnesium in DMEM

The human body is a buffered environment where pH is effectively maintained. HEPES is a biological buffer often used to mimic the buffering activity of the body in in vitro studies on the degradation behavior of magnesium. However, the influence of HEPES on the degradation behavior of magnesium in the DMEM pseudo-physiological solution has not...

Kinetic and thermodynamic aspects of Mg and Mg-Ti hydride nanomaterials

Reliable and affordable energy storage represents a bottleneck in a scenario where renewable energy sources become prominent on the energy market. With its high potential energy density and the natural abundance of the element, hydrogen gas is an attractive energy storage medium. But its gaseous nature, its high explosive potential and...

Destabilization of magnesium hydride through interface engineering

The aim of this thesis is to study the thermodynamics of hydrogenation of nanoconfined magnesium within a thin film multilayer model system. Magnesium hydride is a potential material for hydrogen storage, which is a key component in a renewable energy system based on hydrogen. In bulk form, magnesium hydride is very stable, which means that...

Self-healing corrosion protective coatings by TiO2 particles and a pH-sensitive organic agent on a magnesium alloy

A self-healing corrosion protective coating was developed using TiO2 particles and casein as pH-sensitive organic agents that is also environmentally friendly materials. A film structured of TiO2 particles was formed on a substrate (magnesium alloy) by dip-coating followed by immersion in a casein solution. Casein was inserted and fixed in the...

Polymer bonding and adhesion on aluminium and magnesium alloys

Experimental and Numerical Investigation of Metal Type and Thickness Effects on the Impact Resistance of Fiber Metal Laminates

The impact response of fiber metal laminates (FMLs), has been investigated with experiments and numerical simulations, which is reported in this article. Low-velocity impacts were carried out to study the effects of metal type and thickness within FMLs. Glare5-3/2 laminates with two aluminum layer thicknesses and a similar FML containing...

Fractal disperse hydrogen sorption kinetics in spark discharge generated Mg/NbOx and Mg/Pd nanocomposites

Isothermal hydrogen desorption of spark discharge generated Mg/NbOx and Mg/Pd metal hydride nanocomposites is consistently described by a kinetic model based on multiple reaction rates, in contrast to the Johnson-Mehl-Avrami-Kolmogorov [M. Avrami, J. Phys. Chem. 9, 177 (1941); W. A. Johnson and R. F. Mehl, Trans. Am. Inst. Min., Metal. Eng. 135,...

Divacancies and the hydrogenation of Mg-Ti films with short range chemical order

We obtained evidence for the partial chemical segregation of as-deposited and hydrogenated Mg1?yTiy films (0 ? y ? 0.30) into nanoscale Ti and Mg domains using positron Doppler-broadening. We exclusively monitor the hydrogenation of Mg domains, owing to the large difference in positron affinity for Mg and Ti. The electron momentum distribution...

Thermal stability of gas phase magnesium nanoparticles

In this work we present a unique transmission electron microscopy study of the thermal stability of gas phase synthesized Mg nanoparticles, which have attracted strong interest as high capacity hydrogen storage materials. Indeed, Mg nanoparticles with a MgO shell ( ? 3?nm thick) annealed at 300?°C show evaporation, void formation, and void...

Quasifree Mg–H thin films

The thermodynamics of hydrogen absorption in Pd-capped Mg films are strongly dependent on the magnesium thickness. In the present work, we suppress such dependency by inserting a thin Ti layer between Mg and Pd. By means of optical measurements, we show that the surface energy contribution to the destabilization of MgH2 is negligible. The...

Positron depth profiling of the structural and electronic structure transformations of hydrogenated Mg-based thin films

We report positron depth-profiling studies on the hydrogen sorption behavior and phase evolution of Mg-based thin films. We show that the main changes in the depth profiles resulting from the hydrogenation to the respective metal hydrides are related to a clear broadening in the observed electron momentum densities in both Mg and Mg2Ni films....

The role of magnesium in the electrochemical behaviour of 5XXX aluminium-magnesium alloys

An investigation concerning the effects of magnesium on the intergranular corrosion susceptibility of AA5XXX aluminium alloys was carried out. In the present work, magnesium is found to be highly mobile in the bulk metal as well as in the aluminium oxide. This mobility is also found to be dependent on the temperature and bulk magnesium...

Towards a hydrogen-driven society? Calculations and neutron scattering on potential hydrogen storage materials

For sustainable development, the resources of the earth need to be maintained and carbon dioxide emission should be avoided. In particular, we need to find an alternative for the use of fossil fuels in vehicles. Since long, hydrogen has been recognised as the fuel of the future because it exhausts only water when used in fuel cells and hardly...

Magnesium removal in the electrolytic zinc industry

Electrolytic zinc plants need to take measures to control the magnesium content in their process liquors, because the natural magnesium bleed does not balance the input from concentrates. Presently used methods are environmentally unfriendly (due to the production of large amounts of waste gypsum) or expensive. Therefore, an alternative process...

Design of a magnesium removal process for an electrolytic zinc plant

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