Microbially mediated kinetic sulfur isotope fractionation: reactive transport modeling benchmark

Microbially mediated sulfate reduction is a ubiquitous process in many subsurface systems. Isotopic fractionation is characteristic of this anaerobic process, since sulfate-reducing bacteria (SRB) favor the reduction of the lighter sulfate isotopologue (S³²O₄²⁻) over the heavier isotopologue (S³⁴O...

Applying aluminum-organic matter precipitates to reduce soil permeability in-situ: A field and modeling study

Using naturally occurring processes to modify the engineering properties of the subsurface has received increasing attention from industry and research communities as they aid in the development of cost-effective, robust and sustainable engineering technologies. In line with this trend, we propose to use precipitates of aluminum (Al) and organic...

Analysis and Remediation of the Salinized, Damour Coastal (Dolomitic) Limestone Aquifer in Lebanon

Coastal aquifer management has recently emerged as a main scope in groundwater hydrology, especially in arid and semi-arid zones. About two thirds of the human population are currently gathered close to shorelines relying on coastal groundwater resources. Worldwide, these systems are subject to quality deterioration due to a multitude of...

Field Experiments and Reactive Transport Modeling of Subsurface Arsenic Removal in Bangladesh

The principle of Subsurface Arsenic (As) Removal (SAR) is to extract anoxic groundwater, aerate it and reinject it. Oxygen in the injected water reacts with iron in the resident groundwater to form hydrous ferric oxide (HFO). Dissolved As sorbs onto the HFO, which allows for the extraction of groundwater with lower As concentrations.

Modeling 3D-CSIA data: Carbon, chlorine, and hydrogen isotope fractionation during reductive dechlorination of TCE to ethene

Reactive transport modeling of multi-element, compound-specific isotope analysis (CSIA) data has great potential to quantify sequential microbial reductive dechlorination (SRD) and alternative pathways such as oxidation, in support of remediation of chlorinated solvents in groundwater. As a key step towards this goal, a model was developed...

Modeling biogeochemical processes and isotope fractionation of enhanced in situ biodenitrification in a fractured aquifer

Enhanced in situ biodenitrification (EIB) is a feasible technology to clean nitrate-polluted groundwater and reach<br/>drinking water standards. Aimed at enabling a better monitoring and management of the technology at the field<br/>scale, we developed a two-dimensional reactive transport model (RTM) of a cross section (26.5 × 4 m) of a...