The iron and steel industry is considered as one of the hard-to-abate heavy sectors due to the massive demand for metallurgical coke in the energy-intensive blast furnace (BF) ironmaking process. In this work, an electrochemical conversion of two major metallurgical exhaust gases, namely, blast furnace (BFG) and coke oven gas (COG) into renewable methanol (CH₃OH) is proposed for deeply decarbonizing steel production. An innovative low-carbon BF ironmaking process, which combines solid oxide cells (i.e., renewable-powered co-electrolysis and COG-fed solid oxide fuel cells) and oxyfuel combustion for CO₂ capture, is thermodynamically modeled to evaluate various performance metrics in terms of energy conversion efficiency, product yield, and carbon intensity of renewable methanol. To enhance the process conversion efficiency, four different recycling configurations are designed and compared for efficient tail gas utilization: Scenarios 1 and 4 (co-electrolysis and methanol synthesis via short-loop recirculation) and Scenarios 2 and 3 (co-electrolysis and methanol synthesis via long-loop recirculation). The results indicate that efficient tail gas utilization via long-loop recirculation into the co-electrolysis unit could generate a much higher methanol yield than the short-loop design. Up to 73 % carbon conversion efficiency can be achieved, while 30 % energy conversion efficiency can be attained using long-loop design at a recirculation ratio (RR) of 0.8. Nevertheless, a higher RR operation results in increased energy demand associated with the methanol synthesis process, which in turn leads to higher indirect carbon emissions. Overall, the carbon intensity of methanol ranges from approximately 1.05–1.48kg-CO₂/kg-CH₃OH across the four process configurations under the selected RRs. The long-loop design is likely to offer a reduction in CO₂ emissions of up to 57 % compared to the traditional blast furnace ironmaking process. In particular, a maximum energy conversion efficiency of 38 % can be achieved through heat integration, while net negative CO₂ emissions are achievable based on the evaluated system boundary. The developed process not only has great potential to close the carbon loop between steel makers and chemical producers but also efficiently stores energy in the form of renewable methanol.

This study is particularly aimed at investigating the influence of hydrogen chloride traces in biogas on direct internal reforming in solid oxide fuel cells (SOFCs). The experiments are performed with simulated biogas containing methane to carbon dioxide ratio of 3:2, the usual average proportion in biogas. To the best of our knowledge, there are no reported studies that investigated the effect of hydrogen chloride on direct internal reforming by clearly establishing the effect of reforming with outlet gas composition measurements. The experiments at SOFC operating temperature of 850 °C reveals no negative effect on reforming or cell performance, with 4, 8, and 12 ppm(v) of hydrogen chloride in biogas. At 800 °C, there is no visible performance degradation, but a negligible amount of methane (∼ 1%) is detected in the anode off gas. Both the reforming and electrochemical performance are marginally affected at 750 °C. Further, post-test analyses (FESEM-EDS, XRD) of the used SOFC reveals no damage to the cell at microstructure level or chlorine poisoning. All the experiments are performed in the context of utilizing the biogas generated from sewage treatment plants in an SOFC system. The reported level of chlorine traces in biogas generated from sewage sludge is < 10 ppm(v) and hence the limit set for experiments is at par with this value.

Waste-to-energy (WTE) conversion technologies for generating renewable energy and solving the environmental problems have an important role in the development of sustainable circular economy. This paper presents a novel high-efficiency WTE power plant using refuse-derived fuel (RDF) as feedstock by integrating torrefaction (T) pretreatment with plasma gasifier (PG), solid oxide fuel cell (SOFC), and combined heat and power (CHP) system. The combined impacts of torrefaction conditions (i.e. temperature and residence time) and steam-to-fuel (S/F) ratio on the energy and environmental performances of the proposed T-PG-SOFC-CHP power plant without CO₂ capture (System I) is first evaluated. Results show that torrefaction of RDF prior to plasma gasification provides better syngas quality and therefore the system electrical efficiency (SEE) and CHP efficiency (CHPE) of System I can be markedly boosted compared to that of untreated RDF. However, the integration of torrefaction unit shows a negative effect on the energy return on investment (EROI) due to high energy demands for torrefaction and plasma gasification. Overall, the values of CHPE of System I range from 47.25% to 55.39% when the torrefaction temperatures of 200 and 250 °C are adopted. In contrast, the torrefaction of RDF at 300 °C is not a recommended condition for operation in the T-PG-SOFC-CHP power plant because of noticeably negative energy and environmental impacts. Moreover, to prevent the risk of carbon deposition on the SOFC anode, a recirculation ratio (RR) of the anode off-gas of 30% is required. Finally, the introduction of oxy-fuel combustion technology into the T-PG-SOFC-CHP system for CO₂ capture (System II) allows to achieve a zero direct CO₂ emission WTE power plant. However, this results in an energy penalty of about 5.40–6.77% associated with the CO₂ capture and compression process.

In this study, an energy, exergy, and environmental (3E) analyses of a plasma-assisted hydrogen production process from microalgae is investigated. Four different microalgal biomass fuels, namely, raw microalgae (RM) and three torrefied microalgal fuels (TM200, TM250, and TM300), are used as the feedstock for steam plasma gasification to generate syngas and hydrogen. The effects of steam-to-biomass (S/B) ratio on the syngas and hydrogen yields, and energy and exergy efficiencies of plasma gasification (η_En,PG, η_Ex,PG) and hydrogen production (η_En,H2, η_Ex,H2) are taken into account. Results show that the optimal S/B ratios of RM, TM200, TM250, and TM300 are 0.354, 0.443, 0.593, and 0.760 respectively, occurring at the carbon boundary points (CBPs), where the maximum values of η_En,PG, η_Ex,PG, η_En,H2, and η_Ex,H2 are also achieved. At CBPs, torrefied microalgae as feedstock lower the η_En,PG, η_Ex,PG, η_En,H2, and η_Ex,H2 because of their improved calorific value after undergoing torrefaction, and the increased plasma energy demand compared to the RM. However, beyond CBPs the torrefied feedstock displays better performance. A comparative life cycle analysis indicates that TM300 exhibits the highest greenhouse gases (GHG) emissions and the lowest net energy ratio (NER), due to the indirect emissions associated with electricity consumption.

Internal dry reforming (IDR) of methane for biogas-fed solid oxide fuel cell (SOFC) applications has been experimentally investigated on planar Ni-GDC (cermet anode) electrolyte-supported cells. This study focuses on the effect of CO₂ concentration, current density, operating temperature, and residence time on internal methane dry reforming. A single cell is fed with different CH₄/CO₂ mixture ratios between 0.6 and 1.5. Extra CO₂ recovered from carbon capture plants can be utilized here as a reforming agent. The I-V characterization curves are recorded at different operating conditions in order to determine the best electrochemical performance while the power production is maximized, and carbon deposition is suppressed. The outlet gas from the anode is analyzed by a micro gas chromatograph to investigate methane conversion inside the anode fuel channel and to understand its influence on the cell performance. Relatively long-term experiments have been performed for all gas mixtures at 850°C under a current density of 2000 A m⁻². The results indicate that when the cell is fed with biogas with an equimolar amount of CH₄ and CO₂, carbon deposition is prevented, and maximum power density is obtained.

Internal dry reforming of methane is envisaged as a possibility to reduce on capital and operation costs of biogas fuelled solid oxide fuel cells (SOFCs) system by using the CO₂ present in the biogas. Due to envisaged internal dry reforming, the requirement for biogas upgrading becomes obsolete, thereby simplifying the system complexity and increasing its technology readiness level. However, impurities prevailing in biogas such as H₂S have been reported in literature as one of the parameters which affect the internal reforming process in SOFCs. This research has been carried out to investigate the effects of H₂S on internal dry reforming of methane on nickel-scandia-stabilised zirconia (Ni-ScSZ) electrolyte supported SOFCs. Results showed that at 800°C and a CH₄:CO₂ ratio of 2:3, H₂S at concentrations as low as 0.125 ppm affects both the catalytic and electric performance of a SOFC. At 0.125 ppm H₂S concentration, the CH₄ reforming process is affected and it is reduced from over 95% to below 10% in 10 h. Therefore, future biogas SOFC cost reduction seems to become a trade-off between biogas upgrading for CO₂ removal and biogas cleaning of impurities to facilitate efficient internal dry reforming.

Plasma gasification of raw and torrefied woody, non-woody, and algal biomass using three different gasifying agents (air, steam, and CO₂) is conducted through a thermodynamic analysis. The impacts of feedstock and reaction atmosphere on various performance indices such as syngas yield, pollutant emissions, plasma energy to syngas production ratio (PSR), and plasma gasification efficiency (PGE) are studied. Results show that CO₂ plasma gasification gives the lowest PSR, thereby leading to the highest PGE among the three reaction atmospheres. Torrefied biomass displays increased syngas yield and PGE, but is more likely to have a negative environmental impact of N/S pollutants in comparison with raw one, especially for rice straw. However, the exception is for torrefied grape marc and macroalgae which produce lower amounts of S-species under steam and CO₂ atmospheres. Overall, torrefied pine wood has the best performance for producing high quality syngas containing low impurities among the investigated feedstocks.