This article is the first of a two-part series presenting the thermodynamic evaluation and techno-economics of developing negative-emission power plants. The aim of this research is to evaluate the potential of biochar co-production in negative-emission power plants based on biomass-fed integrated gasification solid oxide fuel cell systems with carbon capture and storage (BIGFC/CCS) units. The influence of two gasification agents, namely, air and steam-oxygen, on the proposed system is investigated. In Part I, we present the thermodynamic models. A sensitivity analysis is carried out to investigate the system response to stepwise increase in biochar co-production (up to 10% by weight). Providing a secondary oxy-combustor in the steam-oxygen gasification case has been shown to be a solution to meet the heat requirements of the allothermal gasification process. A comprehensive exergy analysis indicated significant efficiency improvement for the steam-oxygen gasification case. The results show that the biomass steam-oxygen gasification yields the higher electrical exergy efficiency (48.3%) and combined heat and power (CHP) exergy efficiency (54.6%) for the similar rates of biochar co-production. The specific power output per unit of CO₂ stored is 2.65 MW/(kg/s) and 3.58 MW/(kg/s) for the air and steam-oxygen gasification cases, respectively, when the biochar is co-produced at 10% by weight for the given biomass flow of 20 kg/s. Moreover, the total CO₂ stored due to the proposed system is calculated as 133.9 t/h, and it is estimated to remove 1.17 Mt of CO₂ from the atmosphere annually (when the biochar-based carbon storage is also considered). The models are used for the techno-economic analysis presented in Part II of the series.

This study is particularly aimed at investigating the influence of hydrogen chloride traces in biogas on direct internal reforming in solid oxide fuel cells (SOFCs). The experiments are performed with simulated biogas containing methane to carbon dioxide ratio of 3:2, the usual average proportion in biogas. To the best of our knowledge, there are no reported studies that investigated the effect of hydrogen chloride on direct internal reforming by clearly establishing the effect of reforming with outlet gas composition measurements. The experiments at SOFC operating temperature of 850 °C reveals no negative effect on reforming or cell performance, with 4, 8, and 12 ppm(v) of hydrogen chloride in biogas. At 800 °C, there is no visible performance degradation, but a negligible amount of methane (∼ 1%) is detected in the anode off gas. Both the reforming and electrochemical performance are marginally affected at 750 °C. Further, post-test analyses (FESEM-EDS, XRD) of the used SOFC reveals no damage to the cell at microstructure level or chlorine poisoning. All the experiments are performed in the context of utilizing the biogas generated from sewage treatment plants in an SOFC system. The reported level of chlorine traces in biogas generated from sewage sludge is < 10 ppm(v) and hence the limit set for experiments is at par with this value.

In this study, an energy, exergy, and environmental (3E) analyses of a plasma-assisted hydrogen production process from microalgae is investigated. Four different microalgal biomass fuels, namely, raw microalgae (RM) and three torrefied microalgal fuels (TM200, TM250, and TM300), are used as the feedstock for steam plasma gasification to generate syngas and hydrogen. The effects of steam-to-biomass (S/B) ratio on the syngas and hydrogen yields, and energy and exergy efficiencies of plasma gasification (η_En,PG, η_Ex,PG) and hydrogen production (η_En,H2, η_Ex,H2) are taken into account. Results show that the optimal S/B ratios of RM, TM200, TM250, and TM300 are 0.354, 0.443, 0.593, and 0.760 respectively, occurring at the carbon boundary points (CBPs), where the maximum values of η_En,PG, η_Ex,PG, η_En,H2, and η_Ex,H2 are also achieved. At CBPs, torrefied microalgae as feedstock lower the η_En,PG, η_Ex,PG, η_En,H2, and η_Ex,H2 because of their improved calorific value after undergoing torrefaction, and the increased plasma energy demand compared to the RM. However, beyond CBPs the torrefied feedstock displays better performance. A comparative life cycle analysis indicates that TM300 exhibits the highest greenhouse gases (GHG) emissions and the lowest net energy ratio (NER), due to the indirect emissions associated with electricity consumption.

Negative emission technologies have recently received increasing attention due to climate change and global warming. One among them is bioenergy with carbon capture and storage (BECCS), but the capture process is very energy intensive. Here, a novel pathway is introduced, based on second-generation biofuels followed by carbon circulation in an indefinitely closed chain, effectively resulting in a sink. Instead of using an energy-intensive conventional CCS process, the application of an on-board solid oxide fuel cell (SOFC) running on biofuels in an electric vehicle (FCEV) could result in negative emissions by capturing a concentrated stream of CO₂, which is readily stored in a second tank. A CO₂ recovery system at the fuel station then takes the CO₂ from the tank to be transported to storage locations or to be used for local applications such as CO₂-based concrete curing and synthesis of e-fuels. Incorporating CO₂ utilization technologies into the FCEVs-SOFC system can close the carbon loop, achieving carbon neutrality through feeding the CO₂ in a reverse-logistic to a methanol plant. The methanol produced is also used in SOFCs, leading to an infinite repetition of this carbon cycle till a saturation stage is reached. It is determined this pathway will reach typical Cradle-to-Grave negative emissions of 0.515 ton CO₂ per vehicle, and total negative CO₂ emission of 138 Mt for all passenger cars in the EU is potentially achievable. All steps comprise known technologies with medium to high technology readiness level (TRL) levels, so principally this system can readily be applied in the mid-term.

Since municipal solid waste (MSW) is a negatively priced, abundant, and essentially renewable feedstock, energy recovered from MSW is a useful technology to reduce the consumption of fossil fuels, and also reduces the expenses needed to dispose of MSW. Three configurations of MSW-based IGCC power system (Design 1), MSW-based IGCC polygeneration system (Design 2), and CaO-based IGCC polygeneration system (Design 3) are proposed. Design 1 uses a combination of an identified MSW gasifier, an integrated intermittent chemical-loop air separation (IICLAS), and Rankine and Brayton cycles to generate electricity and achieve the high concentration of CO₂ emissions around 93.3%~94.7%. The process for co-production of DME and MeOH in Design 2, which replaces the Rankine cycle in Design 1, could increase the net energy efficiency of Design 1 by 71.6%, but the total CO₂ emissions from Design 2 are merely 7.97% of Design 1. The calcium looping gasification (CaLG) process in Design 3, which replaces the MSW gasifier in Design 2, could increase the production rate of DME of Design 2 by 12.5%. The CO₂ concentration from the calcinator in Design 3 is higher than CO₂ concentration in flue gas from Designs 1 and 2 by 2.0%~3.5%. Through exergy analysis, the overall exergy efficiency of Design 3 is lower than Designs 1 and 2 by 3.2%~10.1% due to the exergy destruction rate and ratio in the gasification zone of Design 3 higher than other designs. The GaLG process could increase the DME yield as well as the outlet CO₂ concentration, but this approach design induces a higher exergy loss.

Waste-to-energy (WTE) conversion technologies for generating renewable energy and solving the environmental problems have an important role in the development of sustainable circular economy. This paper presents a novel high-efficiency WTE power plant using refuse-derived fuel (RDF) as feedstock by integrating torrefaction (T) pretreatment with plasma gasifier (PG), solid oxide fuel cell (SOFC), and combined heat and power (CHP) system. The combined impacts of torrefaction conditions (i.e. temperature and residence time) and steam-to-fuel (S/F) ratio on the energy and environmental performances of the proposed T-PG-SOFC-CHP power plant without CO₂ capture (System I) is first evaluated. Results show that torrefaction of RDF prior to plasma gasification provides better syngas quality and therefore the system electrical efficiency (SEE) and CHP efficiency (CHPE) of System I can be markedly boosted compared to that of untreated RDF. However, the integration of torrefaction unit shows a negative effect on the energy return on investment (EROI) due to high energy demands for torrefaction and plasma gasification. Overall, the values of CHPE of System I range from 47.25% to 55.39% when the torrefaction temperatures of 200 and 250 °C are adopted. In contrast, the torrefaction of RDF at 300 °C is not a recommended condition for operation in the T-PG-SOFC-CHP power plant because of noticeably negative energy and environmental impacts. Moreover, to prevent the risk of carbon deposition on the SOFC anode, a recirculation ratio (RR) of the anode off-gas of 30% is required. Finally, the introduction of oxy-fuel combustion technology into the T-PG-SOFC-CHP system for CO₂ capture (System II) allows to achieve a zero direct CO₂ emission WTE power plant. However, this results in an energy penalty of about 5.40–6.77% associated with the CO₂ capture and compression process.

Plasma gasification of raw and torrefied woody, non-woody, and algal biomass using three different gasifying agents (air, steam, and CO₂) is conducted through a thermodynamic analysis. The impacts of feedstock and reaction atmosphere on various performance indices such as syngas yield, pollutant emissions, plasma energy to syngas production ratio (PSR), and plasma gasification efficiency (PGE) are studied. Results show that CO₂ plasma gasification gives the lowest PSR, thereby leading to the highest PGE among the three reaction atmospheres. Torrefied biomass displays increased syngas yield and PGE, but is more likely to have a negative environmental impact of N/S pollutants in comparison with raw one, especially for rice straw. However, the exception is for torrefied grape marc and macroalgae which produce lower amounts of S-species under steam and CO₂ atmospheres. Overall, torrefied pine wood has the best performance for producing high quality syngas containing low impurities among the investigated feedstocks.