Design and implementation of artificial neuromorphic systems able to provide brain akin computation and/or bio-compatible interfacing ability are crucial for understanding the human brain's complex functionality and unleashing brain-inspired computation's full potential. To this end, the realization of energy-efficient, low-area, and bio-compatible artificial synapses, which sustain the signal transmission between neurons, is of particular interest for any large-scale neuromorphic system. Graphene is a prime candidate material with excellent electronic properties, atomic dimensions, and low-energy envelope perspectives, which was already proven effective for logic gates implementations. Furthermore, distinct from any other materials used in current artificial synapse implementations, graphene is biocompatible, which offers perspectives for neural interfaces. In view of this, we investigate the feasibility of graphene-based synapses to emulate various synaptic plasticity behaviors and look into their potential area and energy consumption for large-scale implementations. In this article, we propose a generic graphene-based synapse structure, which can emulate the fundamental synaptic functionalities, i.e., Spike-Timing-Dependent Plasticity (STDP) and Long-Term Plasticity. Additionally, the graphene synapse is programable by means of back-gate bias voltage and can exhibit both excitatory or inhibitory behavior. We investigate its capability to obtain different potentiation/depression time scale for STDP with identical synaptic weight change amplitude when the input spike duration varies. Our simulation results, for various synaptic plasticities, indicate that a maximum 30% synaptic weight change and potentiation/depression time scale range from [-1.5 ms, 1.1 ms to [-32.2 ms, 24.1 ms] are achievable. We further explore the effect of our proposal at the Spiking Neural Network (SNN) level by performing NEST-based simulations of a small SNN implemented with 5 leaky-integrate-and-fire neurons connected via graphene-based synapses. Our experiments indicate that the number of SNN firing events exhibits a strong connection with the synaptic plasticity type, and monotonously varies with respect to the input spike frequency. Moreover, for graphene-based Hebbian STDP and spike duration of 20ms we obtain an SNN behavior relatively similar with the one provided by the same SNN with biological STDP. The proposed graphene-based synapse requires a small area (max. 30 nm2), operates at low voltage (200 mV), and can emulate various plasticity types, which makes it an outstanding candidate for implementing large-scale brain-inspired computation systems.

Designing and implementing artificial systems that can be interfaced with the human brain or that can provide computational ability akin to brain's processing information efficient style is crucial for understanding human brain fundamental operating principles and to unleashing the full potential of brain-inspired computing. As basic neural network components, responsible for information transfer between neurons, artificial synapses able to emulate analog biological synaptic behaviour are of particular interest. State of the art CMOS and memristor-based synapses suffer from scalability drawbacks (large energy consumption and area footprint), variability-induced instability, and are not bio-compatible. In this paper, we propose a generic Graphene Nanoribbon (GNR) based synapse structure and demonstrate that by changing GNR geometry and external bias voltages it can emulate different synaptic plasticity behaviours, i.e., Spike Timing Dependent Plasticity and LongTerm Depression and Potentiation, and that both excitatory and inhibitory synaptic behavior can be obtained with the same GNR geometry. To demonstrate biologically plausible operation, we make use of low voltage bias, i.e., 0.1V, 0.2 V, and consider inputs consistent with measured brain synapses data, i.e.,-50 mV to 50 mV pre-and post-synaptic spikes voltage range, and-60ms to 60 ms time range. The simulations indicate that by changing the GNR shape we can enrich the plasticity behaviour (potentially beyond the considered cases) and the plasticity change of 100% provided by natural synapses can be achieved. Our investigation clearly suggests that the proposed GNR synapse structure is a promising candidate for large-scale neuromorphic systems integration, which might potentially bring novel insight on brain neurophysiology, as it requires a small footprint, is energy effective, biocompatible, and versatile from the synaptic behaviour point of view.

As CMOS scaling is reaching its limits, high power density and leakage, low reliability, and increasing IC production costs are prompting for developing new materials, devices, architectures, and computation paradigms. Additionally, temperature variations have a significant impact on devices and circuits reliability and performance. Graphene's remarkable properties make it a promising post Silicon frontrunner for carbon-based nanoelectronics. While for CMOS gates temperature effects have been largely investigated, for gates implemented with atomic-level Graphene Nanoribbons (GNRs), such effects have not been explored. This paper presents the results of such an analysis performed on a set of GNR-based Boolean gates by varying the operation temperature within the military range, i.e., -55°C to 125°C, and evaluating by means of SPICE simulations gate output signal integrity, propagation delay, and power consumption. Our simulation results reveal that GNR-based gates are robust with respect to temperature variation, e.g., 5.2% and 5.3% maximum variations of NAND output logic '1' (VOH) and logic '0' ($V$OL) voltage levels, respectively. Moreover, even in the worst condition GNR-based gates outperform CMOS FinFET 7nm counterparts, e.g., 1.6× smaller delay and 185× less power consumption for the INV case, which is strengthening their great potential as basic building blocks for future reliable, low-power, nanoscale carbon-based electronics.

As CMOS feature size is reaching atomic dimensions, unjustifiable static power, reliability, and economic implications are exacerbating, thereby prompting for conducting research on new materials, devices, and/or computation paradigms. Within this context, graphene nanoribbons (GNRs), owing to graphene's excellent electronic properties, may serve as basic structures for carbon-based nanoelectronics. In this paper, we make use of the fact that GNR behavior can be modulated via top/back gate contacts to mimic a given functionality and combine complementary GNRs for constructing Boolean gates. We first introduce a generic gate structure composed of a pull-up GNR performing the gate Boolean function and a pull-down GNR performing its complement. Then, we seek GNR dimensions and gate topologies required for the design of 1-, 2-, and 3-input graphene-based Boolean gates, validate the proposed gates by means of SPICE simulation, which makes use of a non-equilibrium Green's function Landauer formalism based Verilog-A model to calculate GNR conductance, and evaluate their performance with respect to propagation delay, power consumption, and active area footprint. Simulation results indicate that, when compared with 7 nm FinFET CMOS counterparts, the proposed gates exhibit 6 × to 2 orders of magnitude smaller propagation delay, 2 to 3 orders of magnitude lower power consumption, and necessitate 2 orders of magnitude smaller active area footprint. We further present full adder (FA) and SRAM cell GNR designs, as they are currently fundamental components for the construction of any computation system. For an effective FA implementation, we introduce a 3-input MAJORITY gate, which apart of being able to directly compute FA's carry-out is an essential element in the implementation of error correcting codes codecs, which outperforms the CMOS equivalent carry-out calculation circuit by 2 and 3 orders of magnitude in terms of delay and power consumption, respectively, while requiring 2 orders of magnitude less area. The proposed FA exhibits 6.2 × smaller delay, 3 orders of magnitude less power consumption, while requiring 2 orders of magnitude less area, when compared with the 7 nm FinFET CMOS counterpart. However, because of the effective carry-out circuitry, a GNR-based n-bit ripple carry adder, whose performance is linear in the carry-out path, will be 108 × faster than an equivalent CMOS implementation. The GNR-based SRAM cell provides a slightly better resilience to dc-noise characteristics, while performance-wise has a 3.6 × smaller delay, consumes 2 orders of magnitude less power, and requires 1 order of magnitude less area than the CMOS equivalent. These results clearly indicate that the proposed GNR-based approach is opening a promising avenue toward future competitive carbon-based nanoelectronics.

Hysteretic behavior has been experimentally observed in graphene-based structures and has a major influence on graphene surface potential and gate field modulation ability. Thus, a graphene electronic transport modelling methodology, which incorporates hysteresis effects is crucial in order to properly assess gated-controlled graphene structures response and performance. To this end, we propose an atomistic-level electronic transport model, which is non restricted to rectangular graphene geometries and captures hysteretic effects caused by near-interfacial traps, provided that interface traps trapping/detrapping time constant and density are known. We apply the model on a rectangular graphene shape and validate our results against experimentally measured drain current vs. top gate voltage hysteresis curves. Moreover, to demonstrate model's versatility we consider two non-rectangular Graphene NanoRibbons (GNRs) and investigate their hysteresis behaviour. Our experiments indicate good agreement between simulated and measured results, which qualifies the model appropriate for traps-aware exploration of the conduction behaviour of graphene-based devices and circuits.