Based on a monthly field survey in 2011 of the Pearl River Estuary, the dynamics of polycyclic aromatic hydrocarbons (PAHs) in surface sediments (depth < 5 cm) were explored. The seasonal variations in PAH level and composition were investigated in this study, as well as their environmental behaviors, the role of particles, and source apportionment. The concentration of the sum of 16 priority PAHs (defined as ∑₁₆PAHs) ranged from 0.32 to 1.10 μg/g, while that of the sum of 62 PAHs (defined as ∑_tPAHs) varied from 0.83 to 2.75 μg/g. The levels of both the ∑₁₆PAHs and ∑_tPAHs peaked in February, although the minimum levels appeared in different months—December and August, respectively. The seasonal difference in the ∑_tPAHs was significant (flood season, 7.69 μg/g; dry season, 10.51 μg/g). The 5-ring PAH compound (e.g., perylene) was the most abundant and was responsible for 35% of the total, which implied a terrestrial input source via the Pearl River. Sediment particles were predominantly composed of clayed sand, and sediment PAHs showed a greater tendency to be adsorbed onto the large-sized particles rather than the fine fractions. Total organic carbon (TOC) could considerably facilitate the sediment PAHs. Principal component analysis revealed that vehicle emission sources, petroleum sources, and combustion sources were the major anthropogenic contamination sources. The diagnostic ratios of various individual PAHs were also explored. These findings are particularly useful for understanding the geochemistry of organic pollutants in the complex estuarine environment.

When different tidal constituents propagate along an estuary, they interact because of the presence of nonlinear terms in the hydrodynamic equations. In particular, due to the quadratic velocity in the friction term, the effective friction experienced by both the predominant and the minor tidal constituents is enhanced. We explore the underlying mechanism with a simple conceptual model by utilizing Chebyshev polynomials, enabling the effect of the velocities of the tidal constituents to be summed in the friction term and, hence, the linearized hydrodynamic equations to be solved analytically in a closed form. An analytical model is adopted for each single tidal constituent with a correction factor to adjust the linearized friction term, accounting for the mutual interactions between the different tidal constituents by means of an iterative procedure. The proposed method is applied to the Guadiana (southern Portugal-Spain border) and Guadalquivir (Spain) estuaries for different tidal constituents (M₂, S₂, N₂, O₁, K₁) imposed independently at the estuary mouth. The analytical results appear to agree very well with the observed tidal amplitudes and phases of the different tidal constituents. The proposed method could be applicable to other alluvial estuaries with a small tidal amplitude-to-depth ratio and negligible river discharge.

An analytical model is used to investigate the resonant behavior in a semi-closed channel. The main integral quantities of the tidal wave are obtained by means of a linearized one-dimensional model as a function of three dimensionless parameters, representing cross-section convergence, friction and distance to the closed boundary. Arbitrary along-channel variations of width and depth are accounted for by using a multi-reach approach, whereby the main tidal dynamics are reconstructed by solving a set of linear equations satisfying the continuity conditions of water level and discharge at the junctions of the sub-reaches. We highlight the importance of depth variation in the momentum equation, which is not considered in the classical tidal theory. The model allows for a direct characterization of the resonant response and for the understanding of the relative importance of the controlling parameters, highlighting the role of convergence and friction. Subsequently, the analytical model is applied to the Bristol Channel and the Guadalquivir estuary. The proposed analytical relations provide direct insights into the tidal resonance in terms of tidal forcing, geometry and friction, which will be useful for the study of semi-closed tidal channels that experience relatively large tidal ranges at the closed end.