Energy system optimization models (ESOMs) can be used to guide long-term energy transitions but often overlook environmental impacts and the diversity of solutions close to the cost-optimal one. Here, we combine an ESOM using Modelling to Generate Alternatives (MGA) with Life Cycle Assessment (LCA) to evaluate 260 near-optimal and technologically diverse carbon-neutral energy system designs for Portugal in 2050 across five environmental indicators: climate change, land use, water use, ecotoxicity, and materials. Using the Calliope energy modelling framework and ENBIOS for environmental assessment, we find that system designs whose cost is within 10 % of the minimum feasible cost provide up to 50 % lower environmental impacts. Our results reveal a trade-off between technological diversity and environmental performance, showing that while diversity enhances resilience, this may come with a significant increase in environmental drawbacks. Solar photovoltaic and battery technologies dominate the environmental impacts, particularly in water consumption and critical material use. This study shows that traditional cost-optimal energy system designs may not be environmentally optimal. Exploring near-optimal alternatives reveals lower-impact solutions and supports more inclusive planning for energy transitions.

Due to elevated potential associated with the extremely vast compositional space of high-entropy alloys (HEAs), there is a significant drive to explore these alloys in high-performance contexts such as intensive wear and oxidative environments. In this regard, this review article comprehensively explores the utilization of HEAs in cemented carbides, focusing on their role as binders in cermets. The wear resistance and oxidation behavior of HEA-containing cermets depends on the ceramic-binder thermodynamic compatibility, phase transformations during sintering, microstructure, and mechanical properties. Hence, much high quality research has been focused into exploring the combination of several HEAs with tungsten carbide, titanium carbides, nitrides, carbonitrides and diborides along with other ceramic compounds. As there are many HEA-ceramic combinations, this review aims to provide a landscape of the developments in this field, providing detailed information about the chemical compositions, sintering techniques, mechanical properties and wear and oxidation resistance obtained. Finally, the need for further research to fully understand the complex interactions between composition, microstructure, and wear and oxidation resistance is highlighted, aiming to tailor HEA compositions for optimized performance. The findings presented in this review contribute valuable insights into the promising applications of HEAs in cemented carbides.

Energy transition policies can be translated into narratives about how energy systems should change (e.g., towards a centralised or decentralised system). These narratives tend to reflect expectations, priorities, and perceptions on feasibility and the social acceptability of different policy options, as well as long-term goals and trade-offs, all of which influence policy criteria. Taking as its case study Portugal and the implementation of European directives there, this study aims to characterise energy transition narratives (e.g. a swift transformation to renewables) and interrelated policy criteria (e.g., participation of local communities), focusing on expectations for a socially engaging and democratic energy transition. The analysis builds on the results of a Delphi survey with 10 expert stakeholders, a citizens’ survey (n=500), and a workshop with 19 participants. It identifies the most relevant criteria to stakeholders, as well as the importance of different underlying expectations, meanings, and attitudes shaping narratives about energy system futures. The findings indicate that criteria interrelated to narratives which highlight a promise of democratic energy governance may be less important for energy transition policies, and therefore undermine energy democracy goals. The conclusion highlights suggestions for policy and future research more likely to foster sociopolitical acceptance.