Local shot noise spectroscopy with scanning tunneling microscopy (STM) has proven to be a powerful technique to investigate the electronic properties of quantum materials. It provides direct and non-invasive insight into the tunneling charge quanta or dynamics at the atomic scale. Due to the typically weak noise signal and the presence of low frequency spurious noise, local noise experiments require a high-resolution measurement amplifier. Here, we present a newly developed high-resolution noise amplifier that we implemented in three different STMs. Compared to our previous generation, we obtain more than a 20-fold improvement in the noise resolution, allowing us to resolve values of the effective charge as small as 0.01 e. Our amplifier opens new possibilities for studying electronic properties in novel materials such as d-wave superconductors. In addition to this, it can give direct information about the local electron temperature in STM experiments.

Bogoliubov quasiparticles play a crucial role in understanding the behavior of a superconductor and in achieving reliable operations of superconducting quantum circuits. Diagnosis of quasiparticle poisoning at the nanoscale provides invaluable benefits in designing superconducting qubits. Here, we use scanning tunneling noise microscopy to locally quantify quasiparticles by measuring the effective charge. Using the vortex lattice as a model system, we directly visualize the spatial variation of the quasiparticle concentration around superconducting vortices, which can be described within the Ginzburg-Landau framework. This shows a direct, noninvasive approach for the atomic-scale detection of relative quasiparticle concentration as small as 10⁻⁴ in various superconducting qubit systems. Our results alert of a quick increase in quasiparticle concentration with decreasing intervortex distance in vortex-based Majorana qubits.

Majorana bound states are putative collective excitations in solids that exhibit the self-conjugate property of Majorana fermions—they are their own antiparticles. In iron-based superconductors, zero-energy states in vortices have been reported as potential Majorana bound states, but the evidence remains controversial. Here, we use scanning tunneling noise spectroscopy to study the tunneling process into vortex bound states in the conventional superconductor NbSe₂, and in the putative Majorana platform FeTe_0.55Se_0.45. We find that tunneling into vortex bound states in both cases exhibits charge transfer of a single electron charge. Our data for the zero-energy bound states in FeTe_0.55Se_0.45 exclude the possibility of Yu–Shiba–Rusinov states and are consistent with both Majorana bound states and trivial vortex bound states. Our results open an avenue for investigating the exotic states in vortex cores and for future Majorana devices, although further theoretical investigations involving charge dynamics and superconducting tips are necessary.

By using scanning tunneling microscopy (STM) we find and characterize dispersive, energy-symmetric in-gap states in the iron-based superconductor FeTe_0.55Se_0.45, a material that exhibits signatures of topological superconductivity, and Majorana bound states at vortex cores or at impurity locations. We use a superconducting STM tip for enhanced energy resolution, which enables us to show that impurity states can be tuned through the Fermi level with varying tip-sample distance. We find that the impurity state is of the Yu-Shiba-Rusinov (YSR) type, and argue that the energy shift is caused by the low superfluid density in FeTe_0.55Se_0.45, which allows the electric field of the tip to slightly penetrate the sample. We model the newly introduced tip-gating scenario within the single-impurity Anderson model and find good agreement to the experimental data.

A reduction of the interprobe distance in multiprobe and double-tip scanning tunneling microscopy to the nanometer scale has been a longstanding and technically difficult challenge. Recent multiprobe systems have allowed for significant progress by achieving distances of ~30 nm using two individually driven, traditional metal wire tips. For situations where simple alignment and fixed separation can be advantageous, we present the fabrication of on-chip double-tip devices that incorporate two mechanically fixed gold tips with a tip separation of only 35 nm. We utilize the excellent mechanical, insulating and dielectric properties of high-quality SiN as a base material to realize easy-to-implement, lithographically defined and mechanically stable tips. With their large contact pads and adjustable footprint, these novel tips can be easily integrated with most existing commercial combined STM/AFM systems.

A double-tip scanning tunneling microscope with nanometer-scale tip separation has the ability to access the single-electron Green's function in real and momentum spaces based on second-order tunneling processes. Experimental realization of such measurements has been limited to quasi-one-dimensional systems due to the extremely small signal size. Here we propose an alternative approach to obtain such information by exploiting the current-current correlations from the individual tips and present a theoretical formalism to describe it. To assess the feasibility of our approach we make a numerical estimate for an ∼25-nm Pb nanoisland and show that the wave function in fact extends from tip to tip and the signal depends less strongly on increased tip separation in the diffusive regime than the one in alternative approaches relying on tip-to-tip conductance.

We report on the fabrication and performance of a new kind of tip for scanning tunneling microscopy. By fully incorporating a metallic tip on a silicon chip using modern micromachining and nanofabrication techniques, we realize so-called smart tips and show the possibility of device-based STM tips. Contrary to conventional etched metal wire tips, these can be integrated into lithographically defined electrical circuits. We describe a new fabrication method to create a defined apex on a silicon chip and experimentally demonstrate the high performance of the smart tips, both in stability and resolution. In situ tip preparation methods are possible and we verify that they can resolve the herringbone reconstruction and Friedel oscillations on Au(111) surfaces. We further present an overview of possible applications.

We have imaged the current noise with atomic resolution in a Josephson scanning tunneling microscope with a Pb-Pb junction. By measuring the current noise as a function of applied bias, we reveal the change from single-electron tunneling above the superconducting gap energy to double-electron charge transfer below the gap energy when Andreev processes become dominant. Our spatially resolved noise maps show that this doubling occurs homogeneously on the surface, and also on impurity locations, demonstrating that indeed the charge pairing is not influenced by disruptions in the superconductor smaller than the superconducting coherence length.