We present an investigation of the compact structure of the active galactic nucleus 2021+317 based on multiepoch very long baseline interferometry (VLBI) observations at 15, 22, and 43 GHz in the period from 2013 through 2024. The VLBI images show a core-jet structure extended to the south, with two stationary components in the northern region, one of which is likely to be the core of the source. We also detected two new moving jet components (S4 and S5) in the observations of 2021. Based on these observational findings, we analyzed two distinctive jet models involving one or another stationary component mentioned above as the jet core. One model assumes a moderate bulk motion velocity, a wider viewing angle, and a lower Doppler factor, with the magnetic field energy density significantly dominating over the nonthermal particle energy density. The other model involves a higher bulk motion velocity, a narrower viewing angle, and a higher Doppler factor, with an even greater dominance of magnetic field energy in the core. The position angle of the jet ridgeline rotates counterclockwise over the observed period. The apparent kinematics of the jet components is more consistent with a model of the precessing jet, which has recently completed the first half of the precession cycle. Our results provide constraints on the dynamic evolution of the jet and its interaction with the surrounding medium.

The transesterification of propylene carbonate (PC) or ethylene carbonate (EC) to dimethyl carbonate (DMC) by using catalytic reactive distillation (RD) is a promising approach for carbon dioxide utilization. However, there is still scarcity of comprehensive comparison between the two RD processes. Hence, using the UNIQUAC model and kinetics calibrated by literature and our experiments, we conduct an extensive comparison of the two RD processes. Based on the kinetic insights, laboratory RD processes for both reactions are modeled, analyzed, and experimentally validated. Consequently, two RD processes designed to produce 60 ktpy of DMC are optimized and compared. The interplay and control factors between reaction and separation are elucidated and clarified via investigating variations of the actual chemical equilibrium constant profile compared with theoretical values along the reactive section at various pressures, liquid holdups, etc. The results reveal that the optimized EC RD process achieves almost 50 % reductions in both total annual cost and carbon dioxide emission compared to the PC RD process. This work facilitates the carbon neutrality and provides an essential guide for quantitatively assessing the two routes.

Steam-assisted gravity drainage (SAGD) is one efficient and mature technology for recovering heavy oil and bitumen resources. The key underlying mechanism is the growth of the steam chamber after injecting steam. However, due to the complex geological environment, the thief zones exist and have a prejudicial effect on the development of the steam chamber, thus impacting the ultimate heavy-oil recovery. In this work, our objective is to investigate the effect of a top-water thief zone (i.e., water zone overlies the oil sand) on SAGD performance and further to understand the crucial mechanisms that control the heat loss during steam injection. A large-scale three-dimensional experimental apparatus is used to carry out the SAGD process with a top aquifer. Based on the similarity criterion, the field-scale model is transformed into a laboratory elemental model. To evaluate the SAGD performance quantitatively, the dynamic growth of the steam chamber is measured using the thermal detectors and the production data is recorded. The results show that the steam chamber exhibits three distinguished stages, that is, upward spread, lateral extension, and downward development in the presence of top-water zone. The bottom-water zone has less impact on the steam-chamber growth. The existence of a confined top-water zone, however, significantly affects SAGD performance, especially the lateral expansion of the steam chamber. The lateral propagation of the steam front is hindered by the top thief zone due to the heat exchange with the top water. Once the steam chamber reaches the boundary, the accumulation of energy in the water thief zone, in turn, can reduce the remaining oil saturation along the topwater-oil interface. This study provides us some key insights into the development of heavy oil resources with top thief zones when implementing SAGD technology.