In the field of solid-state luminescence, Cu²⁺ has long been widely acknowledged for its capacity to emit infrared light. However, the occurrence of visible emission from Cu²⁺ ions had been infrequently observed and reported. In this study, we made an intriguing discovery by examining the behavior of Cu²⁺ within an irregular coordination environment of Ba in BaGa₂O₄. When excited by UV light, Cu²⁺ unexpectedly gave a vibrant yellow–red emission, covering a wavelength range spanning from 500 to 750 nm. More noteworthy, by simply manipulating the excitation wavelength or adjusting the temperature, the peak wavelength of the emission could be effectively tuned from approximately 600 to 660 nm, which could be attributed to the luminescence nature of the charge transfer (CT) between O²⁻ and Cu²⁺. Moreover, the phosphor material displayed a remarkable persistent luminescence (PerL) lasting up to 12 h after UV light excitation. Through thermoluminescence (TL) measurements and first-principle calculations, we found that the intrinsic defects, such as vacancies of oxygen and gallium (V_O and V_Ga^″), played important roles for the PerL phenomena. These findings highlighted the exceptional tunability and PerL properties of BaGa₂O₄:Cu²⁺. Our study provided a new potential guideline for the design of Cu²⁺-activated phosphors in visible region, and opened up new avenues for the research in related functional luminescence materials.

De-reclamation is a common strategy used for the restoration of tidal flats. In this study, we investigate the morphodynamic response of tidal channel networks and tidal flats after de-reclamation initiatives using the Delft3D numerical model. We find that tidal channel networks that have undergone reclamation and retreat projects have a lower drainage density (8.95 km⁻¹) than that of channel networks that formed naturally (11.33 km⁻¹), and the drainage efficiency of natural formed channel networks is almost three times greater than restored channel networks. These findings indicate that de-reclamation alone cannot fully erase the imprinting of the previous reclamation. We also find that the ultimate effectiveness of de-reclamation is affected by the geographical layout and unchanneled path length of the inchoate main creek system. In addition, following the implementation of de-reclamation, the immediate opening of previously enclosed areas amplifies the tidal prism, thereby intensifying tidal scouring and resulting in significant erosion, with erosion rate reaching hundreds of millimeters per day. Such losses can be remediated under sufficient sediment supply and prevented through the construction of artificial channels. However, this severe erosion may escalate under an insufficient sediment supply or a heightened tidal prism, potentially leading to permanent loss. These findings constitute an important reference for future engineering practices that support the safety and sustainability of coastal resources.

The sediment load in the Yangtze River downstream of the Three Gorges Dam (TGD) has substantially declined in recent decades. The decrease is more profound below the TGD, e.g., a 97% decrease at Yichang, compared with that at the delta apex, 1200 km downstream, e.g., a 75% decrease, implying along-river sediment recovery. Two large river-connected lakes, i.e., Dongting and Poyang Lakes, may play a role in the re-establishment of the river’s morphodynamic equilibrium, but a quantitative data-based understanding of this interaction is not yet available. In this work, we collected a series of field data to quantify the sediment gain and loss in the river-lake system in the middle-lower Yangtze River, and evaluate the lake’s response to the reduction in riverine sediment supply. We find that Dongting Lake and Poyang Lake shifted from net sedimentation to erosion in 2006 and 2000, and back to a sedimentation regime again after 2017 and 2018, respectively. Natural morphodynamic adaptation and sand mining play an important role in the regime changes in the Dongting Lake whereas sand mining dominates the abrupt changes in the Poyang Lake. The Dongting and Poyang Lake contributed maximum by 38% (2015) and 17% (2006) (respectively) to the sediment recovery in the erosion regime, whereas the riverbed erosion dominates the main sediment source. These changes in the relative contribution of sediment sources also indicates a response time of ~ 20 years in the lakes towards a new equilibrium state. It is noteworthy that the lakes’ buffer effects may be overestimated as the supplied sediment from the lakes is rather small compared to the significant dam trapping in the upstream basin and sediment source from downstream degradation. The results imply that river management and restoration should take into account of the river-lake interactions and feedback impact at decadal time scales.

River discharge is known to enhance tidal damping and tidal wave deformation in estuaries. While the damping effect on astronomical tides has been well documented, river impact on tidal wave deformation and associated overtide generation (shallow water harmonics of one or more astronomical constituents, such as M₄) remains insufficiently understood. Overtides affect tidal asymmetry, extreme water levels, and subsequent sediment transport and flooding management, thus meriting in-depth examination. Being inspired by unusual overtide changes in the landward and seaward parts of the Changjiang Estuary under low and high river discharges, in this work, we use a schematized tidal estuary model to systematically explore overtide variations under different river discharges. Model results show enhanced overtide generation in the case with river discharge compared with that without river impact. The M₄ amplitude decreases in the landward parts of the estuary, but increases in the seaward parts under increasing river discharges. The potential energy of M₄ integrated throughout the estuary shows nonlinear variations and reaches a transitional maximum when the river discharge to tidal mean discharge (R2T) ratio at the mouth is close to unity. Similar nonlinear behaviors are observed for compound tides like MS₄ when more astronomical constituents are prescribed and triad tidal interactions are enabled. The space-dependent overtide variability is more profound in large estuaries with high river discharges like the Amazon and Changjiang estuaries. It is ascribed to the inherently nonlinear river-tide interactions, specifically the twofold effects of river discharge in enhancing bottom stress, which simultaneously enhances dissipation of astronomical constituents and reinforces the energy transfer to overtides. These findings highlight the profound nonlinear impact of river discharge on overtides, and inform the study of tidal asymmetry and compound flood risk in large estuaries and deltas.