Three-phase composites, especially those composed of high performance thermoplastics, have not been properly investigated with respect to their interlaminar fracture toughness. Therefore, this study investigates effect on the interlaminar fracture toughness by adding carbon nanotube buckypaper (BP), tested under cyclic loading in mode I and II. BP weakened the interlaminar fracture toughness in mode I, creating an easy path for crack growth and reducing the strain energy release (SERR) values in the Paris curves. Conversely, under mode II BPs presented no significant influence to the interlaminar fracture toughness and fatigue life; however, a slight improvement was observed due to the bridging effect. The energy balance principle model for opening delamination showed that BP composites require less energy per unit of area to crack growth, resulting in a smoother fracture surface with fewer failure mechanisms. In contrast, BP slightly increased the energy per unit of area for crack growth, leading to a rougher fracture surface with a higher prevalence of failure mechanisms under mode II. This work underscores the importance of examining the individual effects of mode I and II loadings on BP laminates since these interleaves affect the interlaminar toughness and fatigue life differently.

Carbon fiber reinforced polymer (CFRP) composites are widely used to produce structural components. However, their low interlaminar strength makes them susceptible to delamination, limiting structural applications. Aiming to solve this problem, this work proposes adding carbon nanotubes buckypaper (BP) into CFR thermoplastic composites as an interlayer to enhance the interlaminar strength through the BP bridging effect. Despite this objective, the carbon nanotube BP changed the delamination behavior in mode-I, creating an easy pathway for crack growth (smooth fracture surface) and reducing the interlaminar strength. An opposite behavior was observed for mode-II, in which BP acted as an obstacle for crack growth through the shear direction due BP bridging effect, which slightly improved interlaminar strength, resulting in a rougher surface. The experiments demonstrated through the energy involved in crack growth, the roughness of the fracture surface, and the amount of fracture mechanisms when BP was incorporated that in mode-I the delamination strength decreased, while it increased under the shear mode. This evidences that the BP bridging effect is influenced by the loading mode. Finally, this work highlights the need to study individual modes I and II in composites with buckypaper as an interlayer, since it influences the interlaminar toughness differently.