Three-phase composites, especially those composed of high performance thermoplastics, have not been properly investigated with respect to their interlaminar fracture toughness. Therefore, this study investigates effect on the interlaminar fracture toughness by adding carbon nanotube buckypaper (BP), tested under cyclic loading in mode I and II. BP weakened the interlaminar fracture toughness in mode I, creating an easy path for crack growth and reducing the strain energy release (SERR) values in the Paris curves. Conversely, under mode II BPs presented no significant influence to the interlaminar fracture toughness and fatigue life; however, a slight improvement was observed due to the bridging effect. The energy balance principle model for opening delamination showed that BP composites require less energy per unit of area to crack growth, resulting in a smoother fracture surface with fewer failure mechanisms. In contrast, BP slightly increased the energy per unit of area for crack growth, leading to a rougher fracture surface with a higher prevalence of failure mechanisms under mode II. This work underscores the importance of examining the individual effects of mode I and II loadings on BP laminates since these interleaves affect the interlaminar toughness and fatigue life differently.

@en

The present study aims to evaluate thin plate-injected polypropylene (PP) composites containing short aramid fibers (AF) and graphene nanoplatelets (GNPs). The aramid fibers were manually cut to a length of 10 mm and added to the polypropylene matrix at a concentration of 10 wt.%. Additionally, GNPs were incorporated at concentrations of 0.1, 0.25, and 0.5 wt.%. Maleic anhydride grafted polypropylene (MAPP) was used at a concentration of 2 wt.% to improve the adhesion and compatibility between the polymer matrix and the fillers. Thermal analyses, tensile and flexural tests, and dynamic mechanical thermal analysis were performed, followed by statistical analysis using ANOVA and Tukey’s test. The composites demonstrated significant improvements in storage and loss moduli compared to neat polypropylene. With the addition of AF and GNPs, tensile strength increased to 46.8 MPa, which represents a 265% enhancement compared to PP. Similarly, flexural strength reached 62.4 MPa, significantly higher than the 36.73 MPa for PP, particularly for the composite containing AF and 0.25 wt.% GNPs. The results presented in this study highlight the synergistic effect of aramid fibers and GNPs on PP. These improvements make the proposed composites highly promising for a range of applications, including ballistic interlayered aramid/thin-plate laminates.@en

Cellulose-derived battery separators have emerged as a viable sustainable alternative to conventional synthetic materials like polypropylene and polyethylene. Sourced from renewable and biodegradable materials, cellulose derivatives—such as nanofibers, nanocrystals, cellulose acetate, bacterial cellulose, and regenerated cellulose—exhibit a reduced environmental footprint while enhancing battery safety and performance. One of the key advantages of cellulose is its ability to act as a hybrid separator, using its unique properties to improve the performance and durability of battery systems. These separators can consist of cellulose particles combined with supporting polymers, or even a pure cellulose membrane enhanced by the incorporation of additives. Nevertheless, the manufacturing of cellulose separators encounters obstacles due to the constraints of existing production techniques, including electrospinning, vacuum filtration, and phase inversion. Although these methods are effective, they pose challenges for large-scale industrial application. This review examines the characteristics of cellulose and its derivatives, alongside various processing techniques for fabricating separators and assessing their efficacy in battery applications. Additionally, it will consider the environmental implications and the primary challenges and opportunities associated with the use of cellulose separators in energy storage systems. Ultimately, the review underscores the significance of cellulose-based battery separators as a promising approach that aligns with the increasing demand for sustainable technologies in the energy storage domain.@en

Fibre bridging is an important phenomenon influencing the mode I delamination growth behaviour in composite materials. Accurate modelling of this phenomenon is required in order to be able to account for its effects in damage tolerance evaluation of composite structures. Therefore, this study introduces a novel physical model to isolate and quantify the contribution of fibre bridging to Mode I fatigue delamination. The model distinguishes between monotonic and cyclic components of fibre bridging stress, capturing their individual effects on the strain energy release rate (SERR) in the Paris curve. The monotonic component, based on the Sørensen model, accounts for pre-cracking effects, while the cyclic component is derived by integrating a bridging stress function over the end-opening displacement, with both components modelled by empirical exponential relationships. The model has been validated against established methods such as the Yao model and specific extrapolation techniques, demonstrating improved accuracy in fitting the Paris curve, particularly in accounting for the monotonic influence in the shift of the SERR and the cyclic contribution to the curve slope. Importantly, the model requires only one quasi-static and one fatigue test, reducing the experimental workload. In conclusion, this method provides a more accurate characterisation of fibre bridging effects, making it a robust tool for fatigue delamination analysis.@en

This paper investigates the fatigue-induced delamination growth in carbon fibre-reinforced polymer (CFRP), considering different fibre orientation combinations. The study explores the application of Artificial Neural Networks (ANN) in the simulation of fatigue delamination behaviour to reduce the number of experimental tests required for fatigue evaluation and eventual certification. The research aims to evaluate the effectiveness of ANN at different stages of data processing, including raw data simulation and final curve estimation. The results show that applying ANN at the raw data stage provides flexibility in modelling, with error < 10%. In addition, when ANN is applied directly to the final Paris curve, it minimises errors and increases reliability, allowing for a more cost-effective fatigue evaluation process. The study highlights the importance of the data processing stages in determining the accuracy of fatigue delamination predictions with AI modelling, thus informing strategies for efficient fatigue evaluation of CFRP components in structural applications.  @en

Wood is a versatile material extensively utilized across industries due to its low density, favorable mechanical properties, and environmental benefits. However, despite considerable research, the diversity in species with varying compositions and properties remains insufficiently explored, particularly for native woods. A deeper understanding of these differences is crucial for optimizing their industrial applications. This study investigated the composition, tensile strength, flexural strength, Young’s modulus, bending stiffness and elongation at break, thermal behavior, and viscoelastic properties of three Brazilian native wood species: Araucaria angustifolia (ARA), Dipterix odorata (DOD), and Tabeuia ochracea (TOC). The density of these woods showed a linear correlation with mechanical properties such as Young’s modulus (0.9) and flexural modulus (0.9). The research revealed a linear correlation between the woods’ density and mechanical properties, with lignin content emerging as a key determinant of thermal stability. This study highlights the importance of understanding wood species’ composition and physical properties, and provides valuable insights into their behavior.@en

Laminated pultruded composite plates are gaining interest for use in wind turbine blades due to their excellent structural performance with affordable cost. However, there is limited understanding of their fracture properties. The present work explores the interlaminar fracture behaviour of pultruded composite plates, bonded through resin infusion, to form thick CFRP structures. Mode-I, −II, and mixed-mode (I/II) tests were performed to obtain fracture properties at different mixed-mode ratios. Mode I crack propagation exhibits stick–slip behaviour, resulting in brittle failure in a few steps, while mode II provides more stable crack propagation along with cohesive failure. The mixed-mode fracture patterns follow the trend of the mode-mix ratios, in which higher mode-mix ratios (more mode II) induce more stable crack propagation. Benzeggagh-Kenane and power law criteria were compared regarding their prediction of crack initiation toughness given a mode mix ratio, and a linear relation between the mixed mode I/II fracture toughness components could exist at interfaces of laminated pultruded plates. Meanwhile, applicability of testing standards and the effect of manufacturing-induced defects on fracture properties are thoroughly discussed. The results show that existing standards provide sufficient support for characterising fracture properties of bonded pultruded plates; and that manufacturing-induced defects can be detrimental to crack propagation and cause more brittle behaviour in mode I dominant cases, while beneficial effect of defects by toughening the interface was exhibited in mode II dominant cases.@en

Driven by the energy transition and the reduction of carbon emissions, pultruded CFRP plates have emerged as an affordable high performance material for designing wind turbines with larger rotors. To enable the creation of thicker laminates, pre-cured plates are bonded together using an epoxy resin. The present study focuses on characterizing the fracture behaviours of these laminated bonded plates under different modes, and to generate fracture criteria for numerical simulations establishing design allowables and service life. Double cantilever beam tests, end-loaded split tests, and mixed-mode bending tests were conducted under quasi static loading for such plates. Mode I crack propagation showed brittle failure while mode II fracture tests on the other hand, presented a more stable crack growth. Finally, power law and Benzeggagh-Kenane law criteria were established to numerically describe the fracture behaviours. Overall, the results show that the available standards for fracture toughness testing are also suitable for these laminated-pultruded composite plate structures, enabling the material characterization needed for design.@en

The demand to capture translaminar crack growth under fatigue loading scenarios led this work contribution to carry out the Finite Fracture Mechanics (FFM) method in fatigue damage growth and the application of the Paris model to generate the translaminar damage propagation prediction. The purpose of this study is to analyse the effect of fibre orientation on translaminar crack propagation rate using the FFM model, which includes cycle damage increment estimation and fractographic analysis. The results confirm the feasibility of FFM in predicting crack growth and estimating life under cyclic loading. However, C-scan analysis and the revised crack propagation direction are critical in determining the realistic crack length, considering adhesive failure along the fibre direction. Additionally, this work contribution is also related to the application of the Paris model (based on dL/dN vs ΔK) to generate the translaminar damage propagation prediction model. The most dominant damage mechanism was the splitting pattern, which changed the aspect of failure for each laminate architecture as a function of fibre orientation. The laminate with multidirectional fibre orientation exhibited higher resistance to translaminar crack propagation due to the growth of splitting and delamination in multiple directions. The fibre orientation changed the propagation path, which influenced the fracture toughness and crack propagation rate behaviour.

@en

n the past decades, there has been a significant increase in the use of polymers for biomedical applications. The global medical polymer market size was valued at USD 19.92 billion in 2022 and is expected to grow at a CAGR of 8.0% from 2023 to 2030 despite some limitations, such as cost (financial limitation), strength compared to metal plates for bone fracture, design optimization and incorporation of reinforcement. Recently, this increase has been more pronounced due to important advances in synthesis and modification techniques for the design of novel biomaterials and their behavior in vitro and in vivo. Also, modern medicine allows the use of less invasive surgeries and faster surgical sutures. Besides their use in the human body, polymer biomedical materials must have desired physical, chemical, biological, biomechanical, and degradation properties. This review summarizes the use of polymers for biomedical applications, mainly focusing on hard and soft tissues, prosthetic limbs, dental applications, and bone fracture repair. The main properties, gaps, and trends are discussed.@en

Different amounts of graphene quantum dots (CQDs) (0, 1, 2.5, and 5 wt%) were incorporated into an epoxy matrix. The thermal conductivity, density, morphology, and dynamic mechanical thermal (DMTA) properties were reused from the study of Seibert et al.. The Pearson plot showed a high correlation between mass loading, thermal conductivity, and thermal diffusivity. A poorer correlation with density and heat capacity was observed. At lower CQD concentrations (0.1 wt%), the fracture surface showed to be more heterogeneous, while at higher amounts (2.5 and 5 wt%), a more homogeneous surface was observed. The storage modulus values did not change with the CQD amount. But the extension of the glassy plateau increased with higher CQD contents, with an increase of ~40 °C for the 5 wt% compared to the 2.5 wt% and almost twice compared to the neat epoxy. This result is attributed to the intrinsic characteristics of the filler. Additionally, lower energy dissipation and a higher glass transition temperature were observed with the CQD amount. The novelty and importance are related to the fact that for more rigid matrices (corroborated with the literature), the mechanical properties did not change, because the polymer bridging mechanism was not present, in spite of the excellent CQD dispersion as well as the filler amount. On the other hand, thermal conductivity is directly related to particle size and dispersion.@en

Carbon fiber reinforced polymer (CFRP) composites are widely used to produce structural components. However, their low interlaminar strength makes them susceptible to delamination, limiting structural applications. Aiming to solve this problem, this work proposes adding carbon nanotubes buckypaper (BP) into CFR thermoplastic composites as an interlayer to enhance the interlaminar strength through the BP bridging effect. Despite this objective, the carbon nanotube BP changed the delamination behavior in mode-I, creating an easy pathway for crack growth (smooth fracture surface) and reducing the interlaminar strength. An opposite behavior was observed for mode-II, in which BP acted as an obstacle for crack growth through the shear direction due BP bridging effect, which slightly improved interlaminar strength, resulting in a rougher surface. The experiments demonstrated through the energy involved in crack growth, the roughness of the fracture surface, and the amount of fracture mechanisms when BP was incorporated that in mode-I the delamination strength decreased, while it increased under the shear mode. This evidences that the BP bridging effect is influenced by the loading mode. Finally, this work highlights the need to study individual modes I and II in composites with buckypaper as an interlayer, since it influences the interlaminar toughness differently.

@en