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S.K. Ammu

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The inherent directionality of piezoelectric materials is constrained by the symmetry of their crystal structure, which limits the property space in natural piezoelectric materials. To alleviate this limitation, one could leverage geometry or architecture at the mesoscale. Here, we present a framework for designing and 3D-printing piezoelectric truss metamaterials with customizable anisotropic responses. We employ generative machine learning to design truss metamaterials and achieve unconventional behaviors, including auxetic, unidirectional, and omnidirectional piezoelectricity. Then, we develop an in-gel-3D printing method to fabricate these structures using a composite slurry of photo-curable resin and lead-free piezoelectric particles. We achieve an improvement of over 48% in the specific hydrostatic piezoelectric coefficient in optimized metamaterials over bulk lead zirconate titanate (PZT), and the rare phenomenon of higher transverse piezoelectric coefficients than the longitudinal coefficient. Our approach enables customizable piezoelectric responses and paves the way towards the development of a new generation of electro-active animate materials. ...

3D-Printing of Piezoelectric and Living Materials

Doctoral thesis (2025) - S.K. Ammu, K. Masania, C.A. Dransfeld
Multi-material direct ink writing (DIW) of smart materials opens new possibilities for manufacturing complex-shaped structures with embedded sensing and actuation capabilities. In this study, DIW of UV-curable piezoelectric actuators is developed, which do not require high-temperature sintering, allowing direct integration with structural materials. Through particle size and ink rheology optimization, the highest d33*g33 piezoelectric constant compared to other DIW fabricated piezo composites is achieved, enabling tunable actuation performance. This is used to fabricate ultrasound transducers by printing piezoelectric vibrating membranes along with their support structures made from a structural ink. The impact of transducer design and scaling up transducer dimensions on the resonance behavior to design millimeter-scale ultrasound transducers with desired out-of-plane displacement is explored. A significant increase in output pressure with increasing membrane dimensions is observed. Finally, a practical application is demonstrated by using the printed transducer for accurate proximity sensing using time of flight measurements. The scalability and flexibility of the reported DIW of piezo composites can open up new advancements in biomedical, human-computer interaction, and aerospace fields. ...
Engineered living materials (ELMs) are a novel class of functional materials that typically feature spatial confinement of living components within an inert polymer matrix to recreate biological functions. Understanding the growth and spatial configuration of cellular populations within a matrix is crucial to predicting and improving their responsive potential and functionality. Here, this work investigates the growth, spatial distribution, and photosynthetic productivity of eukaryotic microalga Chlamydomonas reinhardtii (C. reinhardtii) in three-dimensionally shaped hydrogels in dependence of geometry and size. The embedded C. reinhardtii cells photosynthesize and form confined cell clusters, which grow faster when located close to the ELM periphery due to favorable gas exchange and light conditions. Taking advantage of location-specific growth patterns, this work successfully designs and prints photosynthetic ELMs with increased CO2 capturing rate, featuring high surface to volume ratio. This strategy to control cell growth for higher productivity of ELMs resembles the already established adaptations found in multicellular plant leaves. ...
Levitation offers extreme isolation of mechanical systems from their environment, while enabling unconstrained high-precision translation and rotation of objects. Diamagnetic levitation is one of the most attractive levitation schemes because it allows stable levitation at room temperature without the need for a continuous power supply. However, dissipation by eddy currents in conventional diamagnetic materials significantly limits the application potential of diamagnetically levitating systems. Here, a route toward high-Q macroscopic levitating resonators by substantially reducing eddy current damping using graphite particle based diamagnetic composites is presented. Resonators that feature quality factors Q above 450 000 and vibration lifetimes beyond one hour are demonstrated, while levitating above permanent magnets in high vacuum at room temperature. The composite resonators have a Q that is >400 times higher than that of diamagnetic graphite plates. By tuning the composite particle size and density, the dissipation reduction mechanism is investigated, and the Q of the levitating resonators is enhanced. Since their estimated acceleration noise is as low as some of the best superconducting levitating accelerometers at cryogenic temperatures, the high Q and large mass of the presented composite resonators positions them as one of the most promising technologies for next generation ultra-sensitive room temperature accelerometers. ...
Conference paper (2019) - T. R. Mahon, V. L. Stuber, S. K. Ammu, S. Van Der Zwaag, P. Groen, T. Hoeks, S. Guhathakurtha
While most of the work on piezoelectric composites focuses on methods to reduce the dielectric constant of the composite (for better sensor and energy harvesting performance), for haptic feedback and actuator applications the opposite is desirable. We present here a study of the effect of adding a second ceramic phase (BaTiO3 nanoparticles) to composites of (K0.5N0.5)1-xLixNbO3 (x = 0.03) in PVDF-TrFE-CFE in order to increase the dielectric constant of the composite. Adding small amounts of these nanoparticles to the composites results in an increase in the dielectric constant and, at high total ceramic loadings, an increase in the density of the composite. Furthermore, while adding larger amounts of nanoparticles leads to agglomeration and reduced densities, it also allows access to higher loadings of ceramic than normally attainable. ...