LCA methodological choices and environmental impacts performance of an integrated seawater desalination and brine treatment system
R. Ktori (TU Delft - BT/Bioprocess Engineering)
John A. Posada (TU Delft - BT/Biotechnology and Society)
Mark C.M. van Loosdrecht (TU Delft - BT/Environmental Biotechnology)
Dimitris Xevgenos (TU Delft - Energy and Industry)
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Abstract
As water research and industry shift towards resource recovery plants, comprehensive assessment methods are needed to capture environmental trade-offs. Existing life cycle assessments (LCA) on desalination often neglect key methodological challenges in multi-product zero-liquid-discharge (ZLD) systems, risking misleading conclusions. This study applies LCA to conventional desalination and with three resource recovery scenarios (integrated desalination and brine treatment) in Cyprus: Sc1) maximum water recovery using waste heat (WH), Sc2) integrated desalination plant with brine treatment using WH, Sc3) electricity-based desalination with chemicals recovery, to assess how key methodological decisions influence the results and decisions. Five impact categories were analysed: climate change, human toxicity, marine ecotoxicity, water depletion, and fossil depletion. Without product substitution, multi-product ZLD systems show higher absolute impacts than SWRO due to increased energy and chemical demands. However, when credits for recovered salts and chemicals are considered, Scenarios 2 and 3 achieve large net reductions compared to conventional production, highlighting the sustainability potential of resource recovery. Results proved highly sensitive to methodological choices: functional unit selection (increase up to 59 %), allocation methods (variation from 54 % to 90 %), while excluding WH altered impacts by up to 89 %, emphasizing the need for transparent reporting to support robust decision-making in desalination design. Sensitivity analysis showed that integrating renewable energy could cut climate change and fossil depletion impacts by up to 99 %, though with trade-offs in marine ecotoxicity and water depletion. Rather than proposing new methods, this work provides critical guidance on applying standardized LCA options to complex systems, offering directly relevant insights for practitioners and policy-makers in sustainable desalination design.