Analysis of naturally-generated corrosion products due to chlorides in 20-year old reinforced concrete
An elastic modulus-mineralogy characterization
Emanuele Rossi (TU Delft - Materials and Environment)
Hongzhi Zhang (Shandong University)
S.J. Garcia (Novel Aerospace Materials)
Johan Bijleveld (Novel Aerospace Materials)
Timo Nijland (TNO)
O Copuroglu (TU Delft - Materials and Environment)
R.B. Polder (RPCP, TU Delft - Materials and Environment, TNO)
Branko Šavija (TU Delft - Materials and Environment)
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Abstract
The elastic modulus of corrosion product (Ecp) has been reported with significant variations in the literature. This study aims to investigate the Ecp of naturally-generated chloride-induced corrosion products formed in different concrete mixes. Microstructural characterization was conducted through nano-indentation, electron microscopy and Raman spectroscopy. The corrosion products were mainly composed of a goethite matrix with portions of maghemite, independently of the concrete composition. Microscopic analysis suggest that layers of corrosion products grow at different times and under different physico-chemical conditions. Our measurements showed that Ecp varied between 80−100 GPa, which can be suggested for numerical models of corrosion induced cracking.