Analysis of naturally-generated corrosion products due to chlorides in 20-year old reinforced concrete

An elastic modulus-mineralogy characterization

Journal Article (2021)
Authors

Emanuele Rossi (TU Delft - Materials and Environment)

Hongzhi Zhang (Shandong University)

S.J. Garcia (Novel Aerospace Materials)

Johan Bijleveld (Novel Aerospace Materials)

Timo Nijland (TNO)

O Copuroglu (TU Delft - Materials and Environment)

R.B. Polder (RPCP, TU Delft - Materials and Environment, TNO)

Branko Šavija (TU Delft - Materials and Environment)

Research Group
Materials and Environment
Copyright
© 2021 E. Rossi, Hongzhi Zhang, Santiago J. Garcia, J.C. Bijleveld, Timo G. Nijland, Oguzhan Copuroglu, R.B. Polder, B. Šavija
To reference this document use:
https://doi.org/10.1016/j.corsci.2021.109356
More Info
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Publication Year
2021
Language
English
Copyright
© 2021 E. Rossi, Hongzhi Zhang, Santiago J. Garcia, J.C. Bijleveld, Timo G. Nijland, Oguzhan Copuroglu, R.B. Polder, B. Šavija
Research Group
Materials and Environment
Volume number
184
Pages (from-to)
1-13
DOI:
https://doi.org/10.1016/j.corsci.2021.109356
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Abstract

The elastic modulus of corrosion product (Ecp) has been reported with significant variations in the literature. This study aims to investigate the Ecp of naturally-generated chloride-induced corrosion products formed in different concrete mixes. Microstructural characterization was conducted through nano-indentation, electron microscopy and Raman spectroscopy. The corrosion products were mainly composed of a goethite matrix with portions of maghemite, independently of the concrete composition. Microscopic analysis suggest that layers of corrosion products grow at different times and under different physico-chemical conditions. Our measurements showed that Ecp varied between 80−100 GPa, which can be suggested for numerical models of corrosion induced cracking.