document

Impact of F and S doping on (Mn,Fe)₂(P,Si) giant magnetocaloric materials

Zhang, F. (author), Batashev, I. (author), Shen, Q. (author), Wu, Z. (author), Smith, Ronald I. (author), de Wijs, Gilles A. (author), van Dijk, N.H. (author), Brück, E.H. (author)

The quarternary (Mn,Fe)₂(P,Si)-based materials with a giant magnetocaloric effect (GMCE) at the ferromagnetic transition T_C are promising bulk materials for solid-state magnetic refrigeration. In the present study we demonstrate that doping with the light elements fluorine and sulfur can be used to adjust T_C...

journal article 2022

document

Correction: Ocádiz Flores et al. Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems: Thermodynamic Description of the ACl-ThCl4 (A = Li, Na, K) Systems (Thermo, (2021), 1, 2, (122-133), 10.3390/thermo1020009)

Ocadiz flores, J.A. (author), Rooijakkers, B.A.S. (author), Konings, R. (author), Smith, A.L. (author)

Corrected excess Gibbs energies of the liquid solutions in the ACl-ThCl4 (A = Li, Na, K), as well as revised standard enthalpies of formation and standard entropies of the intermediate phases occurring in the binary systems, are presented. The phase diagrams are reproduced to a similar level of accuracy as in the original publication, and the...

journal article 2022

document

Improved clinical investigation and evaluation of high-risk medical devices: the rationale and objectives of CORE-MD (Coordinating Research and Evidence for Medical Devices)

Fraser, Alan (author), Nelissen, R.G.H.H. (author), Kjærsgaard-Andersen, P. (author), Szymański, P. (author), Melvin, T. (author), Piscoi, P. (author), Fraser, Alan (author), Szymański, Piotr (author), Gale, Chris (author), Maggioni, Aldo (author), Zanon, Elisabetta (author), Dimopoulou, Christina (author), Ceccarelli, Cinzia (author), Vairami, Polyxeni (author), Ruszanov, Anett (author), Kjærsgaard-Andersen, Per (author), Nelissen, Rob (author), Ott, Adrian (author), Macintyre, Elizabeth (author), Simulescu, Loredana (author), Meijer, Marieke (author), Koletzko, Berthold (author), Wieczorek, Sarah (author), Hadjipanayis, Adamos (author), Del Torso, Stefano (author), Marang-van de Mheen, P.J. (author), Hoogervorst, L. (author), Steyerberg, Ewout W. (author), de Vries, B. (author), McCulloch, Peter (author), Landray, Martin (author), Alhambra, Daniel Prieto (author), Smith, James (author), Lubbeke-Wolf, Anne (author), James, Stefan (author), Buccheri, Sergio (author), Byrne, Robert (author), McGovern, Laurna (author), Windecker, Stephan (author), Frenk, Andre (author), Siontis, Georgios (author), Stettler, Christoph (author), Bano, Arjola (author), Bally, Lia (author), Rademakers, Frank E. (author), D'hooge, Jan (author), Vedder, Anton (author), Biasin, Elisabetta (author), Kamenjasevic, Erik (author), Schnell-Inderst, Petra (author)

In the European Union (EU) the delivery of health services is a national responsibility but there are concerted actions between member states to protect public health. Approval of pharmaceutical products is the responsibility of the European Medicines Agency, whereas authorizing the placing on the market of medical devices is decentralized to...

journal article 2022

document

Global correction of optical distortions in multicolor single-molecule microscopy using Zernike polynomial gradients

Mc Cluskey, K.A. (author), van Veen, E.N.W. (author), Cnossen, J.P. (author), Wesselink, W.J. (author), Asscher, F.M. (author), Smith, C.S. (author), Dekker, N.H. (author)

Accurate image alignment is critical in multicolor single-molecule fluorescence microscopy. Global alignment using affine transformations leaves residual errors due to the nonlinearity of the distortions, which decreases the effective field of view. Subsequent local refinement demands either large amounts of reference data and processing time...

journal article 2021

document

The ethical application of biometric facial recognition technology

Smith, Marcus (author), Miller, S.R.M. (author)

Biometric facial recognition is an artificial intelligence technology involving the automated comparison of facial features, used by law enforcement to identify unknown suspects from photographs and closed circuit television. Its capability is expanding rapidly in association with artificial intelligence and has great potential to solve crime...

journal article 2021

document

Assessing Silver Palladium Alloys for Electrochemical CO₂ Reduction in Membrane Electrode Assemblies

Chandrashekar, S. (author), Geerlings, J.J.C. (author), Smith, W.A. (author)

The field of electrochemical CO₂ reduction has been transitioning to industrially relevant scales by changing the architecture of the electrochemical cells and moving away from the traditional aqueous H-cells to membrane electrode assemblies (MEA). The reaction environments in MEAs vary drastically from that of aqueous H-cells,...

journal article 2021

document

Cation-Driven Increases of CO₂Utilization in a Bipolar Membrane Electrode Assembly for CO₂Electrolysis

Yang, K. (author), Li, Mengran (author), Subramanian, S.S. (author), Blommaert, M.A. (author), Smith, W.A. (author), Burdyny, T.E. (author)

Advancing reaction rates for electrochemical CO2 reduction in membrane electrode assemblies (MEAs) have boosted the promise of the technology while exposing new shortcomings. Among these is the maximum utilization of CO2, which is capped at 50% (CO as targeted product) due to unwanted homogeneous reactions. Using bipolar membranes in an MEA ...

journal article 2021

document

Role of the Carbon-Based Gas Diffusion Layer on Flooding in a Gas Diffusion Electrode Cell for Electrochemical CO₂ Reduction

Yang, K. (author), Kas, Recep (author), Smith, W.A. (author), Burdyny, T.E. (author)

The deployment of gas diffusion electrodes (GDEs) for the electrochemical CO2 reduction reaction (CO2RR) has enabled current densities an order of magnitude greater than those of aqueous H cells. The gains in production, however, have come with stability challenges due to rapid flooding of GDEs, which frustrate both laboratory experiments and...

journal article 2021

document

Orientation of a bipolar membrane determines the dominant ion and carbonic species transport in membrane electrode assemblies for CO₂reduction

Blommaert, M.A. (author), sharifian, rezvan (author), Shah, N. (author), Nesbitt, N.T. (author), Smith, W.A. (author), Vermaas, D.A. (author)

A bipolar membrane (BPM), consisting of a cation and an anion exchange layer (CEL and AEL), can be used in an electrochemical cell in two orientations: reverse bias and forward bias. A reverse bias is traditionally used to facilitate water dissociation and control the pH at either side. A forward bias has been proposed for several...

journal article 2021

document

Thermodynamic Assessment of the AF–CrF3 (A = Li, Na, K) and CrF2–CrF3 Systems

Dumaire, T. (author), Konings, R. (author), Smith, A.L. (author)

Understanding the corrosion mechanisms and the effect of corrosion products on the basic properties of the salt (e.g., melting point, heat capacity) is fundamental for the safety assessment and durability of molten salt reactor technology. This work focused on the thermodynamic assessment of the CrF2−CrF3 system and the binary systems of...

journal article 2021

document

Biometric Identification, Law and Ethics

Smith, Marcus (author), Miller, S.R.M. (author)

This book undertakes a multifaceted and integrated examination of biometric identification, including the current state of the technology, how it is being used, the key ethical issues, and the implications for law and regulation. The five chapters examine the main forms of contemporary biometrics–fingerprint recognition, facial recognition and...

book 2021

document

New insights into the Cs-Mo-O system: Experimental studies of the Cs₂MoO₄-MoO₃ pseudo-binary system

Smith, A.L. (author), Vlieland, J. (author), Pignié, M. C. (author), Abbink, M. (author), Mikaelian, G. (author), Benigni, P. (author)

The ternary cesium molybdates Cs₂Mo₂O₇, Cs₂Mo₃O₁₀, Cs₂Mo₅O₁₆ and Cs₂Mo₇O₂₂ have been synthesized in this work using a solid state route and their structures have been characterized using X-ray diffraction. The...

journal article 2021

document

Experimental studies and thermodynamic assessment of the Ba-Mo-O system by the CALPHAD method

Smith, A.L. (author), Rutten, M. (author), Herrmann, L. (author), Epifano, E. (author), Konings, R. (author), Colineau, E. (author), Griveau, J. C. (author), Guéneau, C. (author), Dupin, N. (author)

Thermodynamic measurements on BaMoO₄, BaMoO₃ and BaMo₃O₁₀ are reported, that served as input for the development of a thermodynamic model of the Ba-Mo-O system using the CALPHAD methodology. The valence states of molybdenum in BaMoO₄ and BaMoO₃ were confirmed to be VI and IV,...

journal article 2021

document

Along the Channel Gradients Impact on the Spatioactivity of Gas Diffusion Electrodes at High Conversions during CO₂Electroreduction

Kas, Recep (author), Star, Andrew G. (author), Yang, K. (author), Van Cleve, Tim (author), Neyerlin, Kenneth C. (author), Smith, W.A. (author)

Results of a 2-D transport model for a gas diffusion electrode performing CO2 reduction to CO with a flowing catholyte are presented, including the concentration gradients along the flow cell, spatial distribution of the current density and local pH in the catalyst layer. The model predicts that both the concentration of CO2 and the buffer...

journal article 2021

document

A principled approach to cross-sector genomic data access

Smith, Marcus (author), Miller, S.R.M. (author)

Genomic data is growing in importance as scientific knowledge and technology develop, and in availability, as direct-to-consumer genomic health testing and recreational genealogy services become more widely utilized. Access to genomic data needs to be considered in light of individual privacy. Cross-sector use of genomic health and ancestry data...

journal article 2021

document

Thermodynamic modelling assessment of the ternary system Cs-Mo-O

Smith, A.L. (author), Pham Thi, T. N. (author), Guéneau, C. (author), Dumas, J. (author), Epifano, E. (author), van Burik, W. (author), Dupin, N. (author)

This work reports the thermodynamic modelling assessment of the rather complex Cs-Mo-O system, which is key for the understanding of fission products chemistry in oxide fuelled Light Water Reactors (LWRs) and next generation Sodium-cooled and Lead-cooled Fast Reactors (SFRs and LFRs). The model accounts for the existence of the ternary...

journal article 2021

document

Geomorphological mapping in urban areas

Brandolini, Pierluigi (author), Del Monte, Maurizio (author), Faccini, Francesco (author), Cattoor, B. (author), Zwoliński, Zbigniew (author), Smith, Mike (author)

contribution to periodical 2021

document

Introducing special issue on photocatalysis and photoelectrochemistry

Batista, Victor (author), Li, Can (author), Smith, W.A. (author), Wang, Dunwei (author)

contribution to periodical 2021

document

Risk blindness in local perspectives about the Alberta oil sands hinders Canada's decarbonization

Virla, Luis D. (author), van de Ven, Dirk Jan (author), Sampedro, Jon (author), van Vliet, Oscar (author), Smith, Alistair (author), Pollitt, Hector (author), Della Santina, C. (author)

Local perspectives can conflict with national and international climate targets. This study explores three stakeholder (community, provincial, and federal) perspectives on the Alberta oil sands as risks for a sustainability transition in Canada. In an ex-post analysis, we compared outputs from stakeholder consultations and energy-economy...

journal article 2021

document

Operando Infrared Spectroscopy Reveals the Dynamic Nature of Semiconductor-Electrolyte Interface in Multinary Metal Oxide Photoelectrodes

Venugopal, A. (author), Kas, Recep (author), Hau, Kayeu (author), Smith, W.A. (author)

Detailed knowledge about the semiconductor/electrolyte interface in photoelectrochemical (PEC) systems has been lacking because of the inherent difficulty of studying such interfaces, especially during operation. Current understandings of these interfaces are mostly from the extrapolation of ex situ data or from modeling approaches. Hence,...

journal article 2021