The early age expansion of cement paste/concrete due to expansive additives (EA) has a significant impact on the microstructure and early-age mechanical properties of cement paste and concrete. Moreover, external restraints owing to reinforcement and supports play a crucial role in reducing concrete expansion and may also affect the microstructure. In this study, a measurement technique to monitor the development of early age elastic modulus of paste (from casting to hardened stage) focusing on the effect of external restraints was established. The influence of external restraint on the microstructure and elastic modulus was examined using the Elastic Modulus Measurement Ambient Response Method (EMM-ARM) and mercury intrusion porosimetry (MIP). This study also focuses on the effect of water-to-binder (w/b) ratios and amount of EA on the early-age mechanical properties of cement paste. The experimental results revealed that under unrestrained conditions, the addition of EA caused the microstructure of the paste to become porous, resulting in a decrease in mechanical properties. Conversely, under restrained conditions, the elastic modulus of the paste with EA and the level of porosity were comparable to the paste without EA. These findings have significant implications for the utilisation of EA in concrete construction and provide potential avenues for enhancing the durability and performance of concrete structures.

The current work provides an integrated analysis of autogenous shrinkage, isothermal calorimetry, and modulus of elasticity measurement through ambient response method (EMM-ARM), to characterise the hardening behaviour of a non-proprietary and more eco-friendly ultra-high performance fibre reinforced cementitious composite (UHPFRC). Isothermal calorimetry revealed that induction period ends at 3 h, and the rapid evolution of hydration heat occurs up to 9 h. Then, the hydration reaction still undergoes but at a very slow rate. The autogenous shrinkage exhibited a strong increase, particularly in the first 6 h, after which a dramatic reduction in the slope of the curves occurred, corroborating with the heat of hydration measurements. The modulus of elasticity evolution pattern revealed a typical cementitious material S-shaped curve, with a strong evolution in the first 8 h and reached 37 GPa at 7 days. As the current study perceives, UHPC/UHPFRC-3 % MOE evolution mainly occurs at very early ages. Thus, using EMM-ARM method for evaluating stiffness-related properties since casting age of UHPC/UHPFRC is of utmost importance to take advantage of the remarkable properties of such advanced material with no waste of time and resources. Furthermore, the UHPFRC developed with a lower amount of cement and silica fume decreases the heat of hydration, shrinkage, and reduced costs and ecological footprint without significantly impairing the MOE, compared to other non-proprietary blended UHPC/UHPFRC mixtures.

This study investigates the influences of internal curing on reducing the autogenous shrinkage of alkali-activated slag/fly ash (AASF) paste. The influences of internal curing with superabsorbent polymers (SAPs) on the reactions and microstructure of AASF paste are investigated. It is found that the SAPs absorb liquid mainly before the initial setting time of the paste. Afterwards, the liquid is gradually released, keeping the internal relative humidity of the paste close to 100%. The internal curing with SAPs can significantly mitigate the autogenous shrinkage of AASF paste, especially after the acceleration period of the reaction. The mitigating effect of internal curing is due to the mitigated self-desiccation in the paste, rather than the formation of a denser microstructure or expansive crystals. The cracking potential of AASF under restrained condition is also greatly mitigated by internal curing. Despite the slight reductions in the elastic modulus and the compressive strength, great improvement is obverted in the flexural strength of the paste. This work confirms the effectiveness of internal curing of AASF with SAPs and further provides a promising way to reduce the autogenous shrinkage of AASF without compromising its mechanical properties.

In this study, internal curing by superabsorbent polymers (SAP) is utilized to mitigate self-desiccation and autogenous shrinkage of alkali-activated slag (AAS) pastes. Absorption and desorption kinetics of SAP incorporated in AAS pastes were studied with X-ray tomography. Internal curing delayed the peak of the rate of heat liberation but increased the total reaction degree of AAS pastes. Internal curing by SAP mitigated effectively the drop of internal relative humidity and the self-desiccation-induced autogenous shrinkage of AAS pastes. The cracking tendency of AAS pastes undergoing shrinkage in restrained conditions was also significantly reduced with SAP. Nonetheless, adding SAP, regardless of their content, cannot eliminate the autogenous shrinkage of AAS pastes, suggesting the existence of other autogenous shrinkage mechanism(s) besides self-desiccation.

The development of the elastic properties of a hardening cement paste results from the microstructural evolution due to cement hydration. The elastic behaviour of cement paste can be predicted by a combination of the hydration model and micromechanical analysis, which originates from a microstructural representative volume where the elastic behaviour of different hydrating cement products can be recognised. In this paper, the formation of the microstructural volume is simulated with the computational code HYMOSTRUC3D for cement hydration. The obtained microstructure is an input for a micromechanical modelling. A 3D regular lattice model is proposed to predict the elastic modulus of the microstructure, considering a water-to-cement (w/c) ratio within the range [0.30-0.50]. In addition, the Finite Element Method (FEM) is used to compare and validate the results from the lattice model. Predictions from these two modelling approaches are then compared to the experimental results provided by the EMM-ARM (Elasticity Modulus Measurement through Ambient Response Method) testing technique, the latter allowing measurement of the elastic modulus of hydrating cement pastes. Finally, the above-referred numerical models are used to evaluate the influence of the following features: the particle size distribution of the cement grains, the microstructure discretisation refinement and the elastic modulus of the C-S-H cement hydration product.