Future energy and transport scenarios will still rely on gas turbines for energy conversion and propulsion. Gas turbines will play a major role in energy transition and therefore gas turbine performance should be improved, and their pollutant emissions decreased. Consequently, designers must have accurate performance and emission prediction tools. Usually, pollutant emission prediction is limited to the combustion chamber as the composition at its outlet is considered to be “chemically frozen”. However, this assumption is not necessarily valid, especially with the increasing turbine inlet temperatures and operating pressures that benefit engine performance. In this work, Computational Fluid Dynamics (CFD) and Chemical Reactor Network (CRN) simulations were performed to analyse the progress ofNOx and CO species through the high-pressure turbine stator. Simulations considering turbulence-chemistry interaction were performed and compared with the finite-rate chemistry approach. The results show that progression of some relevant reactions continues to take place within the turbine stator. For an estimated cruise condition, both NO and CO concentrations are predicted to increase along the stator, while for the take-off condition, NO increases and CO decreases within the stator vanes. Reaction rates and concentrations are correlated with the flow structure for the cruise condition, especially in the near-wall flow field and the blade wakes. However, at the higher operating pressure and temperature encountered during take-off, reactions seem to be dependent on the residence time rather than on the flow structures. The inclusion of turbulencechemistry interaction significantly changes the results, while heat transfer on the blade walls is shown to have minor effects.

One of the main challenges of future aircraft engines is to achieve low pollutant emissions while maintaining high combustion efficiencies and operability. The Flameless Combustion (FC) regime is pointed as one of the promising solutions due to its well-distributed reaction zones that yield low NOx emissions and oscillations. A dual-combustor configuration potentially facilitates the attainment of FC in the Inter-Turbine Burner (ITB). The development of such burner is dependent on knowledge regarding NOx formation and the parameters affecting it. It is known from the literature that the NOx formation mechanisms are different in FC. Therefore, in an attempt to clarify some of the mechanisms involved in NOx formation at relevant conditions, a chemical reactor network model developed to represent the ITB is explored. The role of prompt NOx was previously shown to be dominant at relatively low inlet temperatures and atmospheric pressure. In order to check these findings, five chemical reaction mechanisms were employed. All of them overpredicted NOx emissions and the overprediction is likely to be caused by the prompt NOx subset implemented in these mechanisms. Higher reactants temperatures and operational pressures were also investigated. Overall NOx emissions increased with temperature and the NOx peak moved to lower equivalence ratios. Operational pressure changed the emissions trend with global equivalence ratio. Leaner conditions had behaviour similar to that of conventional combustors (increase in NOx), while NOx dropped with further increase in equivalence ratio due to suppression of the prompt NOx production, as well as an increase in NO reburning. These trends highlight the differences between the emission behaviour of the ITB with those of a conventional combustion system.

Since its discovery, the flameless combustion (FC) regime has been a promising alternative to reduce pollutant emissions of gas turbine engines. This combustion mode is characterized by well-distributed reaction zones, which potentially decreases temperature gradients, acoustic oscillations, and NO_x emissions. Its attainment within gas turbine engines has proved to be challenging because previous design attempts faced limitations related to operational range and combustion efficiency. Along with an aircraft conceptual design, the AHEAD project proposed a novel hybrid engine. One of the key features of the proposed hybrid engine is the use of two combustion chambers, with the second combustor operating in the FC mode. This novel configuration would allow the facilitation of the attainment of the FC regime. The conceptual design was adapted to a laboratory scale combustor that was tested at elevated temperature and atmospheric pressure. In the current work, the emission behavior of this scaled combustor is analyzed using computational fluid dynamics (CFD) and chemical reactor network (CRN). The CFD was able to provide information with the flow field in the combustor, while the CRN was used to model and predict emissions. The CRN approach allowed the analysis of the NO_x formation pathways, indicating that the prompt NO_x was the dominant pathway in the combustor. The combustor design can be improved by modifying the mixing between fuel and oxidizer as well as the split between combustion and dilution air.

Since its discovery, the Flameless Combustion (FC) regime has been seen as a promising alternative combustion technique to reduce pollutant emissions of gas turbine engines. This combustion mode is often characterized by well-distributed reaction zones, which can potentially decrease temperature gradients, acoustic oscillations and, consequently NOx emission. However, the application of FC to gas turbines is still not a reality due to the inherent difficulties faced in attaining the regime while meeting all the engine requirements. Over the past years, investigations related to FC have been focused on understanding the fundamentals of this combustion regime, the regime boundaries, its computational modelling, and combustor design attempts. This article reviews the progress achieved so far, discusses the various definitions of the FC regime, and attempts to point the directions for future research. The review suggests that modelling of the FC regime is still not capable of predicting intermediate species and pollutant emissions. Comprehensive experimental databases with conditions relevant to gas turbine combustors are not available, and moreover, many of the current experiments do not necessarily represent the FC regime. By analysing the latest developments in computational modelling, the review points to the most promising approaches for the prediction of reaction zones and pollutant emissions in FC. The lessons learned from previous design attempts provide valuable insights into the design of a successful gas turbine engine operating under the FC regime. The review concludes with some examples where the gas turbine architecture has been exploited to advance the possibilities of FC in gas turbines.

The Flameless Combustion (FC) regime is promising to the attainment of lower emissions in gas turbine engines. The well-distributed reactions, with low peak temperatures present in the regime result in lower emissions and acoustic oscillations. However, the attainment of the FC regime on gas turbine engines has not been successful, as most of the previous design attempts failed with respect to combustion efficiency, operational range, or difficulty to integrate in an engine. Along with a novel aircraft concept, a conceptual design of a gas turbine engine with two sequential combustion chambers was presented.1 As the aircraft would allow the use of cryogenic fuels, the first (and main) combustion chamber envisages the use of hydrogen or natural gas. The inter-turbine burner (ITB) is the subsequent chamber, and would operate under the FC regime with conventional fuels.