Polymeric healing agents have proven their efficiency to heal cracks in concrete in an autonomous way. However, the bottleneck for valorisation of self-healing concrete with polymeric healing agents is their encapsulation. In the present work, the suitability of polymeric materials such as poly(methyl methacrylate) (PMMA), polystyrene (PS) and poly(lactic acid) (PLA) as carriers for healing agents in self-healing concrete has been evaluated. The durability of the polymeric capsules in different environments (demineralized water, salt water and simulated concrete pore solution) and their compatibility with various healing agents have been assessed. Next, a numerical model was used to simulate capsule rupture when intersected by a crack in concrete and validated experimentally. Finally, two real-scale self-healing concrete beams were made, containing the selected polymeric capsules (with the best properties regarding resistance to concrete mixing and breakage upon crack formation) or glass capsules and a reference beam without capsules. The self-healing efficiency was determined after crack creation by 3-point-bending tests.

Within the European FP7 project HEALCON, Non-Destructive Testing (NDT) and monitoring techniques are developed and combined to characterize the effects of self-healing mechanisms in small and full-size specimens. In the first stage, healing mechanisms were evaluated at lab-scale. Specimens containing encapsulated polymer precursors were cracked and reloaded after the healing period. During loading, healing and reloading, NDT techniques (acoustic emission analysis, vibration analysis and ultrasonic measurement) were applied to help understanding the cracking behavior, capsule breakage and healing efficiency. Moreover, the effect of the flexibility of the polymeric healing agent on the crack re-opening during reloading was investigated on cracked and healed mortar specimens, using acoustic emission and digital image correlation techniques. The results show the applicability of NDT methods to evaluate the self-healing efficiency for small specimens. Comparing the NDT techniques, some of them (e.g. ultrasound) seem to be good candidates for in situ monitoring of the healing efficiency.